Options for the Treatment and Management of Municipal Landfill Leachate: Common and Specific Issues

This paper aims to explore information from the literature for emphasizing the state‐of‐the art and progress in landfill leachate generation, fate and migration, and treatment. Leachate composition is discussed in terms of types of waste disposed and the processes occurring within landfill. The focus is also on potential pathways of environmental contamination by leachate, which may increase environmental and human health risk. The analysis addresses the opportunity and support for decision making concerning alternatives for leachate management and treatment. Advantages and limitations of treatment methods and processes are discussed considering leachate transfer, physico‐chemical methods, biodegradation, and combined methods.     

A Method for Conducting Simultaneous Convergent Tracer Tests in Multilayered Aquifers

Forced gradient tracer tests between two boreholes can be used to study contaminant transport processes at the small field scale or investigate the transport properties of an aquifer. Full depth tests, in which tracer samples are collected just from the discharge of the abstraction borehole, often give rise to breakthrough curves with multiple peaks that are usually attributed to different flow paths through the aquifer that can rarely be identified from the test results alone. Tests in selected levels of the aquifer, such as those between packer‐isolated sections of the boreholes, are time consuming, expensive; and the identification of major transport pathways is not guaranteed. We present a method for simultaneously conducting multiple tracer tests covering the full depth of the boreholes, in which tracer sampling and monitoring is carried out by a novel multilevel sampling system allowing high frequency and cumulative sampling options. The method is applied to a tracer test using fluorescein conducted in the multilayered sandstone aquifer beneath the city of Birmingham, UK, producing six well‐defined tracer breakthrough curves.     

Nonparametric estimation of wave dispersion in high‐rise buildings by seismic interferometry

Interferometric identification and health monitoring of high‐rise buildings has been gaining increasing interest in recent years. The wave dispersion in the structure has been largely ignored in these efforts but needs to be considered to further develop these methods. In this paper, (i) the goodness of estimation of vertical wave velocity in buildings, as function of frequency, by two nonparametric interferometric techniques is examined, using realistic fixed‐base Timoshenko beam benchmark models. Such models are convenient because the variation of phase and group velocities with frequency can be derived theoretically. The models are those of the NS and EW responses of Millikan Library. One of the techniques, deconvolution interferometry, estimates the phase velocity on a frequency band from phase difference between motions at two locations in the structure, while the other one estimates it approximately at the resonant frequencies based on standing wave patterns. The paper also (ii) examines the modeling error in wave velocity profiles identified by fitting layered shear beam in broader band impulse response functions of buildings with significant bending flexibility. This error may affect inferences on the spatial distribution of damage from detected changes in such velocity profiles. Copyright © 2014 John Wiley & Sons, Ltd.     

The role of snow melting upon landslides in the central Argentinean Andes

This paper focuses on the historical range of variability of landslide activity and its relation to climate in the Aconcagua Park, Argentina. Landslide frequency data are obtained through historic compilation, including the review of more than 85 data sources and personal interviews with members of the local community. Based on these records, the study analyzes major landslide triggering mechanisms and evaluates the role of climate. Slope instability in Aconcagua Park appears to be mainly forced by the melting of snow accumulated during the winter season, which in turn promotes soil saturation and landslide occurrence the following spring–summer (December–February). This finding is supported by a strong correlation between landslides and stream flows of Andean rivers. These peaks occur during warmer seasons, fed by snow and ice‐glacier melting. In contrast, the correlation between landslide frequency and precipitation (diary/accumulative/monthly/annual) is less certain; and the relationship of landslide to temperature records (mean annual temperature/mean temperature during November–February period) is weak. Copyright © 2012 John Wiley & Sons, Ltd.     

High-temperature vesuvianite: crystal chemistry and surface considerations

A multi-methodical approach has been applied for characterizing the bulk and surface crystal chemical features of a high-temperature vesuvianite crystal from skarns of Mount Somma-Vesuvius Volcano (Naples, Italy). Vesuvianite belongs to the space group P4/nnc with unit cell parameters a = 15.633(1) Å, c = 11.834(1) Å and chemical formula (Ca_18.858 Na_0.028 Ba_0.004 K_0.006 Sr_0.005 □_0.098)_19.000 (Al_8.813 Ti_0.037 Mg_2.954 Mn_0.008 Fe_0.114²⁺ Fe_1.375³⁺ Cr_0.008 B_0.202)_13.511 Si_18.000(O_0.261 F_0.940 OH_7.799)_9.000. Structure refinement, which converges at R = 0.0328, demonstrates a strong positional disorder down the fourfold axes, indicating that the Y1 site is split into two positions (Y1A and Y1B) alternatively occupied. However, because of X4 proximity to Y1B and Y1A, X4 cannot be occupied if Y1B or Y1A are. Overall Y1 occupancy (Y1A + Y1B) reaches approximately 0.5, as common in vesuvianite and occupancy of Y1B site is extremely limited. Moreover, T1 position, limitedly occupied, accommodates the excess of cations generally related to Y position. A small quantity (0.202 apfu) of boron is sited at the T2 site that, like T1, is poorly occupied. The determination of the amount of each element on the (100) vesuvianite surface, obtained through X-ray photoelectron spectroscopy high-resolution spectra in the region of the Si_2p, Al_2p, Mg_1s, and Ca_2p core levels, evidences that a greater amount of aluminum and a smaller amount of calcium characterize the surface with respect to the bulk. Although both of these features require further investigation, we may consider the Al increase can be related to preferential orientation of Al-rich sites on the (100) plane. Furthermore, the surface structure of vesuvianite suggests that Al, Ca, and Mg cations maintain coordination features at the surface similar to the bulk. Silica, however, while presenting fourfold coordination, shows also a [1]-fold small coordinated component at binding energy 99.85 eV, due to broken Si–O bonds at the surface. The presence of eight- and nine-coordinated Ca cations is suggested by a large XPS feature resulting from the merging of Ca_2p3/2 and Ca_2p1/2 peaks at 348.45 and 352.05 eV, respectively.     

Nutrient inputs from submarine groundwater discharge on the Santiago reef flat, Bolinao, Northwestern Philippines

Submarine groundwater discharge (SGD) on the reef flat of Bolinao, Pangasinan (Philippines) was mapped using electrical resistivity, 222Rn, and nutrient concentration measurements. Nitrate levels as high as 126 μM, or 1-2 orders of magnitude higher than ambient concentrations, were measured in some areas of the reef flat. Nutrient fluxes were higher during the wet season (May-October) than the dry season (November-April). Dissolved inorganic nitrogen (DIN=NO3+NO2+NH4) and soluble reactive phosphorus (SRP) fluxes during the wet season were 4.4 and 0.2 mmoles m(-2) d(-1), respectively. With the increase population size and anthropogenic activities in Bolinao, an enhancement of SGD-derived nitrogen levels is likely. This could lead to eutrophic conditions in the otherwise oligotrophic waters surrounding the Santiago reef flat.     

Hypoxia in Manila Bay, Philippines during the northeast monsoon

Herein we present results from one of the first extensive bay-wide oceanographic surveys of Manila Bay, wherein 31 stations were sampled during the northeast monsoon (cold and dry season). A band of hypoxic bottom water (dissolved oxygen<2.8 mg/L) spanned the midsection of the bay from east to west. Bottom nitrate concentrations (5.7-16.8 μM; avg. 11.1 μM) and total organic carbon values in sediments (1.7-3.1%; avg. 2.4%) were high in the midsection, which coincided with the band of hypoxic bottom water. Physical processes and site-specific accumulation of organic material likely lead to hypoxic conditions in Manila Bay, even during the northeast monsoon period when the water column is relatively well mixed. The results of this study complement the previously reported widespread hypoxia that occurs during the rainy season. Thus, hypoxia may be pervasive in the bay throughout the year, although it varies in intensity and spatial extent.     

Explanatory analysis of the relationship between atmospheric circulation and occurrence of flood‐generating events in a coastal city

The aim of this study is to enhance the understanding of the occurrence of flood‐generating events in urban areas by analysing the relationship between large‐scale atmospheric circulation and extreme precipitation events, extreme sea water level events and their simultaneous occurrence, respectively. To describe the atmospheric circulation, we used the Lamb circulation type (LCT) classification and re‐grouped it into Lamb circulation classes (LCC). The daily LCCs/LCTs were connected with rare precipitation and water‐level events in Aarhus, a Danish coastal city. Westerly and cyclonic LCCs (W, C, SW and NW) showed a significantly high occurrence of extreme precipitation. Similarly, for extreme water‐level events westerly LCCs (W and SW) showed a significantly high occurrence. Significantly low occurrence of extreme precipitation and water‐level events was obtained in easterly LCCs (NE, E and SE). For concurrent events, significantly high occurrence was obtained in LCC W. We assessed the change in LCC occurrence frequency in the future based on two regional climate models (RCMs). The projections indicate that the westerly directions in LCCs are expected to increase in the future. Consequently, simultaneous occurrence of extreme water level and precipitation events is expected to increase in the future as a result of change in LCC frequencies. The RCM projections for LCC frequencies are uncertain because the representation of current LCCs is poor; a large number of days cannot be classified and the frequencies of the days that can be classified differ from the observed time series. Copyright © 2015 John Wiley & Sons, Ltd.     

Use of shallow groundwater temperature profiles to infer climate and land use change: interpretation and measurement challenges

Temperature is often used to infer the effect of land use and climate conditions on aquifers. Reliable data are needed to examine the temperature behaviour in the subsurface; thus, the use of robust acquisition techniques is unavoidable. Three temperature measurement techniques were applied to assess the sources of bias that could occur during temperature logging in a shallow Quaternary coastal aquifer in Ferrara (Northern Italy). Open borehole temperature logging, multilevel sampling straddle packers isolated temperature measurements within a flow cell above ground and multilevel sampling straddle packers isolated temperature measurements via an in‐well level logger (MLS‐IW) were compared for several coastal monitoring wells to gain insights on the limitations of each technique. Results show that the source of bias between the three applied techniques are different: (i) the open borehole temperature logging method tends to record heat convection through the open borehole and is not representative of the aquifer temperature distribution; (ii) the multilevel sampling straddle packers isolated temperature measurements within a flow cell above ground method is swayed by the air temperature and the heating of the submersible pump used to lift groundwater above ground; and (iii) the MLS‐IW provides the most reliable vertical thermal profiling both in summer and winter, because groundwater temperature is directly measured at the selected monitoring depth. The implementation of a 1D flow model demonstrates that if precise temperature profiles are needed to infer the influence that land use and climate changes have on groundwater, the MLS‐IW method is a reliable method that could be applied to existing monitoring wells. Copyright © 2016 John Wiley & Sons, Ltd.