Progressive deformation of an evaporite-bearing accretionary complex: SeaMARC I,SeaBeam and piston-core observations from the Mediterranean Ridge

The Mediterranean Ridge is an arcuate ridge of deformed sediment caught up in the convergent plate margin between the African plate and the Aegean. An intensive campaign of SeaMARC I and SeaBeam surveys followed by piston coring has been conducted along the contact between undeformed turbidites of the Sirte Abyssal Plain and folded and faulted sediments of the Mediterranean Ridge. Along the outer edge of the Ridge, surficial sediments have been deformed into sinusoidal ridges and troughs (wavelengths 0.5–2 km, amplitude 20–150 m), which we interpret as folds. In plan view, the ridge and the trough fabric parallels the NW-SE trending regional contours, suggesting that the folds formed in response to compression orthogonal to the Mediterranean Ridge. The outermost ridge is shedding a debris apron out onto the abyssal plain, implying that uplift and deformation are ongoing. We show that the geometry of the outermost folds can be produced by elastic bending of a packet of 5–10 relatively strong layers, each 10–20 m thick, interbedded between weaker layers; we equate the strong layers with gypsum beds in the Messinian upper evaporites. Folding the seafloor from a flat layer into the observed ridge and trough topography would shorten the layer by less than 2%. Two percent shortening (equals two percent thickening) is insufficient to create the observed relief of the Mediterranean Ridge even if the entire sediment column down to basement were involved; we infer that additional shortening/thickening is accommodated by thrust faulting above a decollement at the top of the Messinian salt layer. At distances > 15 km from the deformation front and more than 500 m from the abyssal plain, sharp-edged, fine-grained side-scan lineations with very little vertical relief cut across the kilometer-scale ridge and trough topography. These fine-grained lineations fall in two groups trending N/S to NNE/SSW and ~ENE. We interpret these lineaments as traces of conjugate strike-slip faults formed in the same compressional regime which formed the NW/SE trending folds. The onset of strike-slip faulting may coincide with the cessation of imbricate thrust fan development above the initial salt-controlled decollement surface. The following characteristics of the Mediterranean Ridge are attributed to the presence of evaporites in the incoming sedimentary section: (1) initial deformation by folding rather than thrust faulting; (2) narrow taper; (3) rapid rate of outward growth; (4) karstification.     

Multi-level assessment of chronic toxicity of estuarine sediments with the amphipod Gammarus locusta: I. Biochemical endpoints

We report on biomarker responses conducted as part of a multi-level assessment of the chronic toxicity of estuarine sediments to the amphipod Gammarus locusta. A companion article accounts for organism and population-level effects. Five moderately contaminated sediments from two Portuguese estuaries, Sado and Tagus, were assessed. Three of them were muddy and two were sandy sediments. The objective was to assess sediments that were not acutely toxic. Three of the sediments met this criterion, the other two were diluted (50% and 75%) with clean sediment until acute toxicity was absent. Following 28-d exposures, the amphipods were analysed for whole-body metal bioaccumulation, metallothionein induction (MT), DNA strand breakage (SB) and lipid peroxidation (LP). Two of the muddy sediments did not cause chronic toxicity. These findings were consistent with responses at organism and population levels that showed higher growth rates and improvement of reproductive traits for amphipods exposed to these two sediments. Two other sediments, one muddy and one sandy, exhibited pronounced chronic toxicity, affecting SB, MT induction (in muddy sediment), survival and reproduction. Potential toxicants involved in these effects were identified. The last sandy sediment exhibited some loss of DNA integrity, however growth was also enhanced. Present results, together with the organism/population-level data, and also benthic communities information, were analysed under a weight-of-evidence approach. By providing evidence of exposure (or lack of it) to contaminants in sediments, the biomarkers here applied assisted in distinguishing toxicants' impacts in test organisms from the confounding influence of other geochemical features of the sediments.     

A less disastrous disaster: Managing response to climate-driven hazards in the Cayman Islands and NE Brazil

This paper explores the relationship between disaster risk reduction and long-term adaptive capacity building in two climate vulnerable areas—the Cayman Islands in the Caribbean and Ceará, in NE Brazil. Drawing on past applications of the disaster risk reduction framework, we identify four critical factors that have led to reductions in risk: flexible, learning-based, responsive governance; committed, reform-minded and politically active actors; disaster risk reduction integrated into other social and economic policy processes; and a long-term commitment to managing risk. We find that while the presence of these factors has reduced overall risk in both regions, in Ceará, disaster response as it is currently practiced, has fallen short of addressing the fundamental causes of vulnerability that leave those prone to hazards able to cope in the short term, yet enmeshed in poverty and at risk from the longer-term changes associated with climate change. Although calls for integration of disaster risk management with poverty eradication are not new, there has been insufficient attention paid in the literature on how to foster such integration. Based on the two case studies, we argue that the adoption of good governance mechanisms (such as stakeholder participation, access to knowledge, accountability and transparency) in disaster risk reduction policy may create the policy environment that is conducive to the kind of structural reform needed to build long-term adaptive capacity to climate-driven impacts. We conclude that without a synergistic two-tiered approach that includes both disaster risk reduction and structural reform, disaster risk reduction, in the face of climate changes, will prove to be an expensive and ineffective palliative treatment of changing risks.     

Atmospheric forcing of Fram Strait sea ice export: a closer look

Fram Strait is the primary region of sea ice export from the Arctic and therefore plays an important role in regulating the amount of sea ice and freshwater within the Arctic. We investigate the variability of Fram Strait sea ice motion and the role of atmospheric circulation forcing using daily data during the period 1979–2006. The most prominent atmospheric driver of anomalous sea ice motion across Fram Strait is an east–west dipole pattern of Sea Level Pressure (SLP) anomalies with centers of action located over the Barents Sea and Greenland. This pattern, also observed in synoptic studies, is associated with anomalous meridional winds across Fram Strait and is thus physically consistent with forcing changes in sea ice motion. The association between the SLP dipole pattern and Fram Strait ice motion is maximized at 0-lag, persists year-round, and is strongest on time scales of 10–60 days. The SLP dipole pattern is the second empirical orthogonal function (EOF) of daily SLP anomalies in both winter and summer. When the analysis is repeated with monthly data, only the Barents center of the SLP dipole remains significantly correlated with Fram Strait sea ice motion. However, after removing the leading EOF of monthly SLP variability (e.g., the North Atlantic Oscillation), the full east–west dipole pattern is recovered. No significant SLP forcing of Fram Strait ice motion is found in summer using monthly data, even when the leading EOF is removed. Our results highlight the importance of high frequency atmospheric variability in forcing Fram Strait sea ice motion.     

Climate signal in varve thickness: Lake La Cruz (Spain), a case study

Lake La Cruz is a meromictic, karstic lake with annually laminated sediment formed by summer pulses of calcite deposition. The aim of this study was to explore the potential use of the laminated sediment from Lake La Cruz as a quantitative climate proxy, by calibrating lamina thickness against instrumental climate data. Statistical analysis of the relation between lamina thickness and the meteorological dataset indicated a high correlation between calcium carbonate lamina thickness and rainfall from December to March (r  = 0.725, P < 0.01, n = 35). Winter rainfall anomalies in the area are, in turn, highly negatively correlated with the North Atlantic Oscillation index (NAO, r = −0.832; P < 0.01; n = 53). We propose a regression model to infer past winter rainfall from calcium carbonate laminae thickness. These results highlight new possibilities for paleoenvironmental research using calcite laminated sediment records as climate proxies, especially to study past rainfall variability.     

Inferred Indium Resources of the Bolivian Tin‐Polymetallic Deposits

Tin‐polymetallic base metal deposits of Miocene age in the Eastern Cordillera in Bolivia were studied by ICP/MS and EPMA for major and minor elements, paying an attention to indium concentration of the ore deposits. The highest indium content and 1000 In/Zn ratio of individual ore deposits are 5,740 ppm and 22.2 for the Potosi deposits, 2,730 ppm and 7.4 for Bolivar deposit, 2,510 ppm and 17.5 for Siete Suyos–Animas deposits, and 1,290 ppm and 3.3 for San Vicente deposit. The same content and ratio of composite samples of the studied deposits are up to 292 ppm and 4.0 for Potosi deposits, 3,080 ppm and 11.3 for Huari Huari deposit, 100 ppm and 0.3 for Tuntoco deposit, 152 ppm and 1.8 for Porco deposit, 103 ppm and 59.2 for Animas deposit, and 1,160 ppm and 3.7 for Pirquitas deposit. Those of zinc concentrates are as follows: 1,080 ppm and 2.1 at San Lorenzo; 584 ppm and 1.7 at Bolivar; 499 ppm and 1.23 at Porco; 449 ppm and 1.21 at Reserva, and 213 ppm and 0.61 at Colquiri deposit. Indium occurs mostly in dark colored sphalerite and that of the Potosi deposit was found to have one of the highest concentrations, containing up to 1.27 wt% In. Petrukite was discovered in the Potosi deposit, and indium minerals are expected to occur in the Huari Huari deposit and others with the high 1000 In/Zn ratios. The indium contents of the zinc concentrates and composite samples were applied to the produced and remaining ores, then the total amounts of indium in the Bolivian tin‐polymetallic base metal deposits are speculated to be more than 12,000 tons In, which is bigger than that of South China (11,000 tons) and the Japanese Islands (9,000 tons). Sphalerites of the Potosi deposit have one of the highest ranges of indium, similarly to those of the San Vicente deposit. Both the San Vicente and Potosi deposits are rich in silver, implying significance of both silver‐polymetallic and tin‐polymetallic environments for the concentration of trace amounts of indium.     

美国内华达Goldstrike矿区卡林型贝茨金矿同变形的富矿分带(续)

(接第 1期第 1 6页 )3　富矿分带与控制因素贝茨金矿中不同矿石矿物组合和蚀变类型的分布与构造背景、围岩岩石及在矿体中的位置有关。根据形态、矿物组成和地质背景可分出几种空间形式截然不同的矿石类型 ,彼此之间由废石或低含金量的岩石所分隔。富矿体的地球化学、矿物学、地质及冶金方面的分带在三维空间上是连续的。富矿体的形状和定位与 Peters向斜构造的特征 ,沉积岩的岩石组成以及闪长岩接触带的几何形态和厚度有关 (图 6 A,B)。根据对不同的矿石类型和围岩类型的研究结果 ,对不同的富矿体进行了分类和判别。 Pe-ters( 1 996 ,1 9…     

Controls of facies and sediment composition on the diagenetic pathway of shallow-water Heterozoan carbonates: the Oligocene of the Maltese Islands

Relatively few studies have so far addressed diagenetic processes in Heterozoan carbonates and the role that sediment composition and depositional facies exert over diagenetic pathways. This paper presents a study of Oligocene shallow-water, Heterozoan carbonates from the Maltese Islands. We investigate stratigraphic distribution, abundance and timing of diagenetic features and their relationship to sediment composition and depositional facies. The studied carbonate rocks comprise rud- to packstones of the Heterozoan association predominantly containing coralline red algae, bryozoans, echinoids and benthic foraminifers. XRD analyses show that all high-Mg calcite has been transformed to low-Mg calcite and that no aragonite is preserved. Diagenetic processes include dissolution of aragonitic biota, neomorphism of high-Mg calcitic biota to low-Mg calcite and cementation by fibrous, bladed, epitaxial and blocky cements. Stable isotopes on bulk rock integrated with petrographic data suggest that the study interval was not exposed to significant meteoric diagenesis. We interpret early cementation to have taken place in the marine and marine burial environment. The distribution and abundance of early diagenetic features, determining the diagenetic pathway, can be related to the primary sediment composition and depositional texture. Sorting and micrite content are important controls over the abundance of diagenetic features.     

Multi-methodological investigation of kunzite, hiddenite, alexandrite, elbaite and topaz, based on laser-induced breakdown spectroscopy and conventional analytical techniques for supporting mineralogical characterization

Gem-quality alexandrite, hiddenite and kunzite, elbaite and topaz minerals were characterized through a multi-methodological investigation based on EMPA-WDS, LA-ICP-MS, and laser-induced breakdown spectroscopy (LIBS). With respect to the others, the latter technique enables a simultaneous multi-elemental composition without any sample preparation and the detection of light elements, such as Li, Be and B. The criteria for the choice of minerals were: (a) the presence of chromophore elements in minor contents and/or as traces; (b) the presence of light lithophile elements (Li, Be and B); (c) different crystal chemistry complexity. The results show that LIBS can be employed in mineralogical studies for the identification and characterization of minerals, and as a fast screening method to determine the chemical composition, including the chromophore and light lithophile elements.