A potentially new type of nonchondritic interplanetary dust particle with hematite,organic carbon,amorphous Na,Ca‐aluminosilicate,and FeO‐spheres

Abstract– We used a combination of different analytical techniques to study particle W7190‐D12 using microinfrared spectroscopy, micro‐Raman spectroscopy, and field emission scanning electron microscopy (FESEM) energy dispersive X‐ray spectroscopy (EDS). The particle consists mainly of hematite (α‐Fe₂O₃) with considerable variations in structural disorder. It further contains amorphous (Na,K)‐bearing Ca,Al‐silicate and organic carbon. Iron‐bearing spherules (<150 nm in diameter) cover the surface of this particle. At local sites of structural disorder at the hematite surface, the hematite spheres were reduced to FeO in the presence of organic carbons forming FeO‐spheres. However, metallic Fe spheres cannot be excluded based on the available data. To the best of our knowledge, this particle is the first detection of such spherules at the surface of a stratospheric dust particle. Although there is no definitive evidence for an extraterrestrial origin of particle W7190‐D12, we suggest that it could be an IDP that had moved away from the asteroid‐forming region of the early solar system into the outer solar system of the accreting Kuiper Belt objects. After it was released from a Jupiter family comet, this particle became part of the zodiacal cloud. Atmospheric entry flash‐heating caused (1) the formation of microenvironments of reduced iron oxide when indigenous carbon materials reacted with hematite covering its surface resulting in the formation of FeO‐spheres and (2) Na‐loss from Na,Al‐plagioclase. The particle of this study, and other similar particles on this collector, may represent a potentially new type of nonchondritic IDPs associated with Jupiter family comets, although an origin in the asteroid belt cannot be ignored.     

When do rock glacier fronts fail? Insights from two case studies in South Tyrol (Italian Alps)

The fronts of two rock glaciers located in South Tyrol (Italian Alps) failed on 13 August 2014, initiating debris flows in their downslope channels. A multimethod approach including climate, meteorological, and ground temperature data analysis, aerial image correlation, as well as geotechnical testing and modeling, led to the reconstruction of the two events. An integrated investigation of static predisposing factors, slowly changing preparatory factors, and potential triggering events shed light on the most likely reasons for such failures. Our results suggest that the occurrence of front destabilization at the two rock glaciers can only partly be explained by the occurrence of heavy rainfall events. Indeed, antecedent hydrological and thermal ground conditions were characterized by a saturated active layer favored by a snow-rich winter and extensive precipitation in late spring and summer. Also, the rising trend of air temperature during spring and summer months since 1950s might explain the concurrent marked displacement of the two rock glaciers. Indeed, geotechnical investigations have provided strong indications that one of the investigated rock glacier fronts was at a marginally stable state prior to 2014. As rainfall events more intense than the one that occurred in August 2014 were previously recorded in the same area without resulting failures at the studied rock glaciers, we propose that both predisposing and preparatory destabilizing factors have played a key role in the 2014 rock glacier front failures.     

High-Nb hawaiite–mugearite and high-Mg calc-alkaline lavas from northeastern Iran: Oligo-Miocene melts from modified mantle wedge

Tertiary volcanic rocks in northwestern Firoozeh, Iran (the Meshkan triangular structural unit), constitute vast outcrops (up to 250 km²) of high-Mg basaltic andesites to dacites that are associated with high-Nb hawaiites and mugearites. Whole-rock ⁴⁰Ar/³⁹Ar ages show a restricted range of 24.1 ± 0.4–22.9 ± 0.5 Ma for the volcanic rocks. The initial ratios of ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd vary from 0.703800 to 0.704256 and 0.512681 to 0.512877, respectively, in the high-Mg basaltic andesites–dacites. High-Th contents (up to 11 ppm) and Sr/Y values (27–100) and the isotopic composition of the subalkaline high-Mg basaltic andesites–dacites indicate derivation from a mantle modified by slab and sediment partial melts. Evidence such as reverse zoning and resorbed textures and high Ni and Cr contents in the evolved samples indicate that magma mixing with mafic melts and concurrent fractional crystallization lead to the compositional evolution of this series. The high-Nb hawaiites and mugearites, by contrast, have a sodic alkaline affinity and are silica undersaturated; they are also enriched in Nb (up to 47 ppm) and a wide range of incompatible trace elements, including LILE, LREE, and HFSE. Geochemistry and Sr–Nd isotopic compositions of the high-Nb hawaiites and mugearites suggest derivation from a mantle source affected by lower degrees of slab melts. Post-orogenic slab break-off is suggested to have prompted the asthenospheric upwelling that triggered partial melting in mantle metasomatized by slab-derived melts.     

Metals in eggs and hatchlings of Dermochelys coriacea (testudines) in Espírito Santo,Brazil and their relation to hatching and emergence success

Certain concentration of metal may influence survival in embryonic stages, reducing the birthrate and hatching emergence. This study aimed to evaluate concentration of metal in eggs and hatchlings of Dermochelys coriacea and correlate metal concentrations in eggs with hatching and emergence success. The samples were collected at Biological Reserve Station, ES, Brazil. At the nests' opening, unhatched eggs and stillborn hatchlings were collected to survey the successful hatching and emergence of D. coriacea. The eggs shell, egg content, and dead hatchlings metal concentrations were compared to hatching and emergence success. A positive correlation was found between the concentration of copper (Cu) in the hatchlings and the success of the emergence (r² = .28, p < .05), and a moderate positive correlation between the concentrations of iron (Fe) and barium (Ba; r² = .44, p < .05) and success hatching. The concentrations of metals in eggs and hatchlings of D. coriacea in the Espírito Santo are below the levels that could be considered harmful to the species. In summary, there is a positive correlation between metals levels and hatching and emergence success.     

Did the “Autochthonous” European foreland of Corsica Island (France) experience Alpine subduction?

Despite the important role played by the Sardinia‐Corsica block in the reconstruction of the Western Mediterranean geodynamics, the extent of involvement of the “Autochthonous” European margin exposed in Corsica (France) (i.e., Hercynian Corsica) in the Alpine orogeny remains uncertain. Stratigraphic and sedimentological studies in the post‐Variscan deposits on the Hercynian Corsica are scarce and even scarcer are the structural and metamorphic constraints. To face these uncertainties, we present new stratigraphic, structural and metamorphic data from the area of Razzo Bianco, Central Corsica, where a complete sequence belonging to the European continental margin is exposed. Field and structural investigations demonstrate that the sequence represents the easternmost edge of the downgoing European plate. Metamorphic studies on the Eocene deposits indicate that the margin was buried at depth up to blueschist facies conditions and, subsequently, it was progressively exhumed mainly through the activation of oblique top‐to‐the NW shear zones.     

Cotton canopy reflectance under variable solar zenith angles: Implications of use in evapotranspiration models

Evapotranspiration (ET) is an important parameter in hydrologic processes and modelling. In agricultural watersheds with competing uses of fresh water including irrigated agriculture, estimating crop evapotranspiration (ET_c) accurately is critical for improving irrigation system and basin water management. The use of remote sensing-based basal crop coefficients is becoming a common method for estimating crop evapotranspiration for multiple crops over large areas. The Normalized Difference Vegetation Index (NDVI) and the Soil Adjusted Vegetation Index (SAVI), based on reflectance in the red and near-infrared bands, are commonly used for this purpose. In this paper, we examine the effects of row crop orientation and soil background darkening due to shading and soil surface wetness on these two vegetation indices through modelling, coupled with a field experiment where canopy reflectance of a cotton crop at different solar zenith angles, was measured with a portable radiometer. The results show that the NDVI is significantly more affected than the SAVI by background shading and soil surface wetness, especially in north–south oriented rows at higher latitudes and could lead to a potential overestimation of crop evapotranspiration and irrigation water demand if used for basal crop coefficient estimation. Relationships between the analysed vegetation indices and canopy biophysical parameters such as crop height, fraction of cover and leaf area index also were developed for both indices.     

Do static stress changes of a moderate‐magnitude earthquake significantly modify the regional seismic hazard? Hints from the L'Aquila 2009 normal‐faulting earthquake (Mw 6.3, central Italy)

We investigated the Coulomb stress changes in the active faults surrounding a moderate‐magnitude normal‐faulting earthquake (2009 L'Aquila, Mw 6.3) and the associated variations in the expected ground motion on regional probabilistic seismic hazard maps. We show that the static stress variations can locally increase the seismic hazard by modifying the expected mean recurrence time on neighbouring faults by up to ~290 years, with associated variations in the probability of occurrence of the maximum expected earthquake of up to ~2%. Our findings suggest that the increase in seismic hazard on neighbouring faults following moderate‐magnitude earthquakes is probably not sufficient to necessitate systematic upgrades of regional probabilistic seismic hazard maps, but must be considered to better address and schedule strategies for local‐scale mitigation of seismic risk.     

Late Pleistocene stratigraphy and sedimentary environments of the Severnaya Dvina‐Vychegda region in northwestern Russia

The Late Pleistocene stratigraphy from the Severnaya Dvina‐Vychegda region of northwestern Russia is revised based on investigations of new localities, revisiting earlier localities, introduction of about 110 new OSL dates and burial depth corrections of earlier published OSL dates, in addition to six new radiocarbon dates. Most of the OSL samples studied here are from fluvial and subaquaeous sediments, which we found to be well bleached. Six chronostratigraphical units and their sedimentary environment are described, with the oldest unit consisting of pre‐Eemian glacial beds. For the first time, Early Weichselian sediments are documented from the region and a fluvial environment with some vegetation and permafrost conditions is suggested to have persisted from the end of the Eemian until at least about 92 ka ago. The period in which a Middle Weichselian White Sea Lake could have existed is constrained to 67?62 ka, but as the lake level never reached the thresholds of the drainage basin, the lake probably existed only for a short interval within this time‐span. Blocking and reversal of fluvial drainage started again around 21?20 ka ago when the Fennoscandian Ice Sheet advanced into the area, reaching its maximum 17?15 ka ago. At that time, an ice‐dammed lake reached its maximum water level, which was around 135 m above present sea level. Drainage of the lake started shortly after 15 ka ago, and the lake was emptied within 700 years. Severe periglacial conditions, with permafrost and aeolian activity, prevailed in the area until about 10.7 ka.     

Extensional tectonics during the Tyrrhenian back‐arc basin formation and a new morpho‐tectonic map

We present a new tectonic map focused upon the extensional style accompanying the formation of the Tyrrhenian back‐arc basin. Our basin‐wide analysis synthetizes the interpretation of vintage multichannel and single‐channel seismic profiles, integrated with modern seismic images, P‐wave velocity models, and high‐resolution morpho‐bathymetric data. Four distinct evolutionary phases of the Tyrrhenian back‐arc basin opening are further constrained, redefining the initial opening to Langhian/Serravallian time. Listric and planar normal faults and their conjugates bound a series of horst and graben, half‐graben and triangular basins. Distribution of extensional faults, active throughout the basin since Middle Miocene, allows us to define an arrangement of faults in the northern/central Tyrrhenian mainly related to a pure shear which evolved to a simple shear opening. At depth, faults accommodate over a Ductile‐Brittle Transitional zone cut by a low‐angle detachment fault. In the southern Tyrrhenian, normal, inverse and transcurrent faults appear to be related to a large shear zone located along the continental margin of the northern Sicily. Extensional style variation throughout the back‐arc basin combined with wide‐angle seismic velocity models allows to explore the relationships between shallow deformation, faults distribution throughout the basin, and crustal‐scale processes as thinning and exhumation.     

The extension of the parametrization of the radio source coordinates in geodetic VLBI and its impact on the time series analysis

The radio sources within the most recent celestial reference frame (CRF) catalog ICRF2 are represented by a single, time-invariant coordinate pair. The datum sources were chosen mainly according to certain statistical properties of their position time series. Yet, such statistics are not applicable unconditionally, and also ambiguous. However, ignoring systematics in the source positions of the datum sources inevitably leads to a degradation of the quality of the frame and, therefore, also of the derived quantities such as the Earth orientation parameters. One possible approach to overcome these deficiencies is to extend the parametrization of the source positions, similarly to what is done for the station positions. We decided to use the multivariate adaptive regression splines algorithm to parametrize the source coordinates. It allows a great deal of automation, by combining recursive partitioning and spline fitting in an optimal way. The algorithm finds the ideal knot positions for the splines and, thus, the best number of polynomial pieces to fit the data autonomously. With that we can correct the ICRF2 a priori coordinates for our analysis and eliminate the systematics in the position estimates. This allows us to introduce also special handling sources into the datum definition, leading to on average 30 % more sources in the datum. We find that not only the CPO can be improved by more than 10 % due to the improved geometry, but also the station positions, especially in the early years of VLBI, can benefit greatly.