Plankton copper requirements and uptake in the subarctic Northeast Pacific Ocean

We undertook the first measurements of metabolic Cu requirements (net Cu:C assimilation ratios) and steady-state Cu uptake rates (ρCu_ss) of natural plankton assemblages in the northeast subarctic Pacific using the short-lived radioisotope ⁶⁷Cu. Size-fractionated net Cu:C assimilation ratios varied ～3 fold (1.35–4.21 μmol Cu mol C^?1) among the stations along Line P, from high Fe coastal waters to the Fe-limited open ocean. The variability in Cu:C was comparable to biogenic Fe:C ratios in this region. As previously observed for Fe uptake, the bacterial size class accounted for half of the total particulate ρCu_ss. Interestingly, carbon biomass-normalized rates of Fe uptake from the siderophore desferrioxamine B (DFB) (ρFe_DFB; a physiological proxy for Fe-limitation) by the >20 μm size class were positively correlated with the intracellular net Cu:C assimilation ratios in this size class, suggesting that intracellular Cu requirements for large phytoplankton respond to increased Fe-limitation. At Fe-limited Ocean Station Papa (OSP), we performed short-term Cu uptake (ρCu_L) assays to determine the relative bioavailability of Cu bound to natural and synthetic ligands. Like the volumetric ρCu_ss measured along Line P, the bacterial size class was responsible for at least 50% of the total ρCu_L. Uptake rates of Cu from the various organic complexes suggest that Cu uptake was controlled by the oxidation state of the metal and by the metal:ligand concentration ratio, rather than the concentration of inorganic species of Cu in solution. Collectively, these data suggest that Cu likely plays an important role in the physiology of natural plankton communities beyond the toxicological effects studied previously.     

Quaternary palaeoenvironments and multi-storey valley fill architecture along the Mezen and Severnaya Dvina river valleys,Arkhangelsk region,NW Russia

The modern Severnaya Dvina and Mezen river systems in the Arkhangelsk region, NW Russia, are located within extensive palaeovalley systems. The palaeovalleys form depressions in bedrock and have controlled the drainage systems in the area at least since the Last Interglacial. Vertically stacked marine to fluvial sediments reflect deposition during fluctuating climate and sea levels.A compilation of lithostratigraphical data collected during the last decade has been coupled with bedrock topography and geomorphology from satellite images in order to describe the valley fill architecture for the two valley systems. Each system has been divided into a number of depositional units (storeys) separated by incision/non-deposition and used to investigate the timing of aggradational versus incisional phases. Time constraints for each phase are provided by optically stimulated luminescence (OSL) ages, and aggradation and incision are linked to independent records of climate and sea level change.The pattern of aggradation and erosion is regional and primarily driven by episodes of increasing and decreasing sediment supply. Aggradation is correlated to times of deglaciation with high sediment supply from the ice margin, release of sediment from ice-dammed lakes and low vegetation and degradation of permafrost on the flood plain. Incision is related to cold intervals with low sediment supply, delayed incision due to isostatic uplift and drainage of ice-dammed lakes. Relative sea level change controls the distribution of marine deposits, which show significant regional variations due to variable isostatic response across the region. Sea level change plays a limited role for fluvial aggradation/incision in the study area.     

Three‐dimensional modeling of problems in poro‐elasticity via a mixed least‐squares method using linear tetrahedral elements

In a previous publication we developed a new mixed least‐squares method for poro‐elasticity. The approximate solution was obtained via a minimization of a least‐squares functional, based upon the equations of equilibrium, the equations of continuity and weak forms of the constitutive relationships for elasticity and Darcy flow. The formulation involved four independent types of variables: displacements, stresses, pore pressures and velocities. All of them were approximated by linear continuous triangles. Encouraged by the computational results, obtained from the two‐dimensional implementation of the method, we extended our formulation to three dimensions. In this paper we present numerical examples for the performance of continuous linear tetrahedra within the context of the mixed least‐squares method. The initial results suggest that the method works well in the nearly and entirely incompressible limits for elasticity. For poro‐elasticity, the obtained pore pressures are stable without exhibiting the oscillations, which are observed when the standard Galerkin formulation is used. Copyright © 2010 John Wiley & Sons, Ltd.     

Coversand and Pleistocene palaeosols in the Landes region,southwestern France

New sections in the coversand of the Landes region, southwestern France, show at least two main depositional phases corresponding to the Upper Pleniglacial and the Lateglacial, which are separated by palaeosols. The lower palaeosol, a gleyic to histic cryosol overlying a net of sand wedges and dated to ca. 23 ¹⁴C ka BP, testifies to a short occurrence of permafrost. Impeded drainage due to the frozen subsoil is assumed to be the main factor involved in lowered aeolian transport and soil formation. Pollen analysis indicates a shrub tundra‐type environment. The overlying coversand unit is associated with small transverse ridges or sheet‐like deposits, and corresponds to the maximal extension of the sands, Upper Pleniglacial in age. An incipient podzol developed on the dunes under a boreal pine forest, and has been dated to 11.5–12 ¹⁴C ka BP, i.e. to the Allerød period. This has been buried by the second coversand unit during the Younger Dryas, typified by abundant denivation features and root imprints. Although preliminary, the chronology of sand deposition in the Landes region appears thus to be roughly similar to that found for the other European coversands, showing that all were the result of similar western European climatic changes, i.e. repeated episodes of increasing aridity related to the Upper Pleniglacial and the Younger Dryas episode. Copyright © 2008 John Wiley & Sons, Ltd.     

Variable sequence of events during the past seven terminations in two deep-sea cores from the Southern Ocean

The relationships among internally consistent records of summer sea-surface temperature (SSST), winter sea ice (WSI), and diatomaceous stable isotopes were studied across seven terminations over the last 660 ka in sedimentary cores from ODP sites 1093 and 1094. The sequence of events at both sites indicates that SSST and WSI changes led the carbon and nitrogen isotopic changes in three Terminations (TI, TII and TVI) and followed them in the other four Terminations (TIII, TIV, TV and TVII). In both TIII and TIV, the leads and lags between the proxies were related to weak glacial mode, while in TV and TVII they were due to the influence of the mid-Pleistocene transition. We show that the sequence of events is not unique and does not follow the same pattern across terminations, implying that the processes that initiated climate change in the Southern Ocean has varied through time.     

Characterization of a karstic aquifer using magnetic resonance sounding and electrical resistivity tomography: a case-study of Esta?a Lakes (northern Spain)

The geophysical characterization of a previously unstudied endorheic karstic system is presented. The studied area, known as the Esta?a Lakes, is located in the Pyrenean Marginal Sierras, northern Spain. The Esta?a Lakes are a set of natural water ponds on a bedrock of Triassic evaporites, lutites and carbonates. This wetland is included in the Natura 2000 European network of nature protection areas as a “Site of Community Importance”. Two geophysical techniques were used, magnetic resonance sounding (MRS) and electrical resistivity tomography (ERT), to map the subsurface geology and characterize the aquifer layers and the hydraulic links between the aquifers and lakes. The geophysical data were integrated with the surface geology and data from six boreholes. Ten electrical profiles were performed to identify the thickness of the units and lithological changes, whereas the MRS was used to determine the top of the saturated zone. As result, the aquifer in the Esta?a Lakes system and surrounding area has been identified as Middle Triassic carbonates, which does not correspond with the regional aquifer in the area (Upper Cretaceous and Eocene). This work shows the power of geophysical methods in poorly understood and tectonically complex areas in addition to the standard aquifer tests to evaluate hydraulic properties.     

New data on the Vrancea Nappe (Moldavidian Basin, Outer Carpathian Domain, Romania): paleogeographic and geodynamic reconstructions

A study has been performed on the Cretaceous to Early Miocene succession of the Vrancea Nappe (Outer Carpathians, Romania), based on field reconstruction of the stratigraphic record, mineralogical-petrographic and geochemical analyses. Extra-basinal clastic supply and intra-basinal autochthonous deposits have been differentiated, appearing laterally inter-fingered and/or interbedded. The main clastic petrofacies consist of calcarenites, sub-litharenites, quartzarenites, sub-arkoses, and polygenic conglomerates derived from extra-basinal margins. An alternate internal and external provenance of the different supplies is the result of the paleogeographic re-organization of the basin/margins system due to tectonic activation and exhumation of rising areas. The intra-basinal deposits consist of black shales and siliceous sediments (silexites and cherty beds), evidencing major environmental changes in the Moldavidian Basin. Organic-matter-rich black shales were deposited during anoxic episodes related to sediment starvation and high nutrient influx due to paleogeographic isolation of the basin caused by plate drifting. The black shales display relatively high contents in sub-mature to mature, Type II lipidic organic matter (good oil and gas-prone source rocks) constituting a potentially active petroleum system. The intra-basinal siliceous sediments are related to oxic pelagic or hemipelagic environments under tectonic quiescence conditions although its increase in the Oligocene part of the succession can be correlated with volcanic supplies. The integration of all the data in the “progressive reorientation of convergence direction” Carpathian model, and their consideration in the framework of a foreland basin, led to propose some constrains on the paleogeographic-geodynamic evolutionary model of the Moldavidian Basin from the Late Cretaceous to the Burdigalian.