Soluble organic compounds in fog and cloud droplets: what have we learned over the past few years?

We have recently set up a new procedure for characterising the water soluble organic compounds (WSOC) in fog water, for which information is still rather limited. Fog samples collected during the 1998–1999 fall–winter season in the Po Valley (Italy) were analysed following this procedure, which allows a quantitative determination of three main classes of organic compounds (neutral species, mono- and di-carboxylic acids, polycarboxylic acids), together accounting for ca. 85% of the total WSOC. This procedure also provides information on the main chemical characteristics of these three classes of compounds (functional groups, aliphatic vs. aromatic character, etc.). The enhanced chemical knowledge on fog/cloud chemical composition opens new scenarios as far as chemical and microphysical processes in clouds and fogs are concerned.     

Milan: The city of constant renewal

Traditional models of urban development are no longer adequate to describe current metropolitan transformations. These are now at the centre of a debate concerning management and administration. In Italy, delays in resolving problems of urban and metropolitan government, despite the legal framework provided by Law 142/90, have weighed heavily on the larger urban areas of the country: Rome, Naples, Milan, which have not been able to tackle the issue of metropolitan government. Recent legislation, while not providing a pre-defined institutional solution, allows separate administrative districts to collectively establish metropolitan institutions of `variable geometry'. The Milan urban area is not one city, but a system of mutually-dependent cities, linked to each other and the rest of the world by a transport network still requiring much investment. The vitality of its economic structure (especially its small firms) is held back by seriously inadequate infrastructure and low external economic efficiency. The provincial capital may boast `historic centrality' but the most interesting potential for development is to be found on the periphery and in the administrative districts immediately surrounding it, in the recovery of derelict industrial areas and dormitory towns established in the 1950s and 1960s, especially to the north. Recovery of derelict areas, green areas, and better transport links within the urban area and with the outside world are the key elements in the reorganization of `Greater Milan'. In this situation of rapid transformation the most appropriate political strategies involve negotiated planning. This revised version was published online in August 2006 with corrections to the Cover Date.     

Modeling of Rayleigh waves dispersion in the Sannio region (Southern Italy) from seismic active refraction data

Short period surface waves, recorded during a seismic refractionsurvey in the Sannio region (Southern Italy), have been modeled to infera shallow velocity model for the area. Based on the decrease of resolutionwith depth, due to the bias on group velocity estimates arising frominterference of the Rayleigh waves with higher modes, we carried out aprocedure of fitting, with synthetic seismograms, of selected filtered traceswith a gaussian filter, having a width at half height equal to 1 Hz and acentral frequency lying in the range [1,4] Hz. We estimated the likelihoodbetween synthetic and observed seismograms by measuring their semblance.In this way we were able to infer a more refined local velocity modelcharacterized by a high Vp and Vs vertical gradient in the sedimentarycover. Two ad hoc resolution studies, based on group velocity andamplitude data respectively, indicate that the local velocity model is a goodvelocity model also for the entire studied area. The increase in the numberof available data when using amplitude information allows us to make amore selective choice in the model parameter space (Vp and Vs of eachlayer) and to solve for the Vp/Vs ratio. The inferred Vp velocity in thehalf-space is equal to 2.8 km/s. This value is in excellent agreement withthat inferred by other authors (3 km/s) by modeling P-wave travel timevs. distance. The best-fit model furnish low Vp/Vs for the sedimentarycover so indicating a high degree of the sediment's compaction in thestudied area. The inferred shallow high-velocity gradient indicates thatthe shallow sedimentary layer in the area could trap and focus the energytraveling into it.     

Parameters affecting maximum fluid transport in large aperture fractures

We present results of laboratory experiments to study the behavior of liquids moving in unsaturated wide-aperture fractures. A 5-mm-thick glass plate cut with a 1.7-mm aperture was used as a fractured rock analog to study behavior of film and capillary droplet flow modes. Flow rates ranged between 0.6 and 6.0 ml/min. Variability in the ambient barometric pressure, resulting from weather conditions, seemed to play a role in the natural selection of flow mode. For droplet mode, constant input conditions resulted in highly variable transport properties within the fracture. The advancing meniscus exhibited a dynamic contact angle that was a function of the droplet speed and much larger than the static contact angle. Flow rate was reduced due to the larger contact angle. Analytical expressions for droplet velocity and flow capacity are presented as a function of the dynamic rather than the static contact angle.