Surface complexation modeling of Cu(II) adsorption on mixtures of hydrous ferric oxide and kaolinite

Background  

The application of surface complexation models (SCMs) to natural sediments and soils is hindered by a lack of consistent models and data for large suites of metals and minerals of interest. Furthermore, the surface complexation approach has mostly been developed and tested for single solid systems. Few studies have extended the SCM approach to systems containing multiple solids.     

Iterative selective spatial variance reduction of MYD11A2 LST data

The aim of this research effort is to develop a method that will allow to map and evaluate thermal anomalies in SW USA from the MYD11A2 night land surface temperature (LST) imagery being available for the year 2014, that present higher spatial (1 km) and temporal (46 images per year) resolution than the MYD11C3 LST data (12 images per year at 5.6 km spatial resolution). The fact that is MYD11A2 LST imagery is projected to a rectangular grid did not affect the X, Y and elevation (H) spatial decorrelation stretch. Principal component analysis and linear regression models isolated and removed the X, Y, H (spatial) dependent variance included in the data while metrics devised verified the selective spatial variance reduction. The reconstructed 46 LST images represent the amount the LST deviates from the X, Y and H predicted for the year 2014. The thematic information content of the reconstructed LST images is verified by cluster analysis and mapped the spatial extend and the temporal variability of thermal anomalies within the study area. The positive thermal anomaly clusters are spatially arranged mainly west of Sierra Nevada in Great Basin Section where extensional tectonics create a series of titled elongated mountain blocks along the N to S direction in between basins bounded by normal faults, while the negative thermal anomaly clusters are spatially arranged along the coastal region, further north and in the western region far from the tilted mountain tectonic blocks of the Great Basin Section. The spatial maps that define regions with (positive or negative) thermal anomalies and distinct mean land response could assist landcover studies and support urban and rural planning in the context of emerging climatic change.     

Nature of serpentinization and carbonation of ophiolitic peridotites (Eastern Desert,Egypt): constrains from stable isotopes and whole-rock geochemistry

Serpentinites are widespread in the Arabian-Nubian Shield (ANS) of the Eastern Desert of Egypt and usually enclose a tremendous carbonate alteration. Combined investigation of the stable isotope compositions of both O-H in serpentines and O-C in the whole-rock and the chemistry of the fluid-mobile elements (FMEs) in whole-rock serpentinites from Wadi (W.) Alam, Gabal (G.) El-Maiyit, and W. Atalla (Eastern Desert of Egypt) allowed to better understand the subsequent fluid sources of serpentinization and carbonation, as well as impact of these processes on the geochemistry of protolith ultramafic rocks. δ ¹⁸O values of W. Alam and W. Atalla serpentine minerals are close to the unaltered mantle and propose a lower temperature serpentinization if compared with those of G. El-Maiyit rocks. Moreover, δD values of W. Alam and W. Atalla serpentines (? 94 to ? 65‰) correspond to an igneous source that might be hydrothermal solutions mixed with the seawater in the mid-ocean ridge-arc transition setting. On the other hand, G. El-Maiyit serpentine is more depleted in ¹⁸O (with lower δ ¹⁸O values = 4.08–4.85‰), and its δD values (? 73 to 56 ‰) are most probably caused by an interaction with metamorphic fluids, acquired during on-land emplacement of oceanic peridotites or during burial in fore-arc setting. In addition, the oceanic oxygen isotope composition of most studied ophiolitic serpentinites points to the preservation of the pre-obduction δ ¹⁸O signatures and thus local-scale fluid flow at low water/rock ratios. Serpentinization fluids were CO₂-poor and the carbonation of the serpentinites resulted from infiltration of externally derived fluids. δ ¹⁸O_VSMOW values of carbonates in the studied serpentinites vary between heavier oxygen isotope composition in G. El-Maiyit samples (av. = 25.32‰) to lighter composition in W. Alam samples (av. = 19.43‰). However, δ ¹³C values of all serpentinites point mantle source of carbon. This source might have been evolved in mid-ocean ridge (W. Atalla) and subduction zone (W. Alam and G. El-Maiyit) settings. The studied serpentinites are usually enriched in FMEs, particularly Pb, Sr, Cs, and U. These enrichments were most probably the result of serpentinization and/or carbonation.     

Hydrochemical assessment of groundwater from shallow aquifers in parts of Wadi Al Hamad,Madinah, Saudi Arabia

The present study was carried out in the Mulaylih area which forms a part of Wadi Al Hamad in the Madinah Province of Saudi Arabia. Thirty groundwater samples from agricultural farms were collected and analyzed for various physio-chemical parameters including trace elements. The area is occupied by the Quaternary alluvium deposits which form shallow unconfined aquifers. Evaporation and ion exchange are the major processes which control the major ion chemistry of the area. The extreme aridity has results in high total dissolved solid values (average of 9793.47 mg/l). Trace element concentrations are low and are mainly attributed to geogenic sources (silicate weathering). Na-Cl groundwater type is the main hydrochemical facies found in the area. The waters are found to be oversaturated with calcite/aragonite and dolomite. The average nitrate concentration was found to be 134.10 mg/l and is much higher than the WHO recommended limit of 50 mg/l in drinking water. Their high values are mainly associated with the application of N-fertilizers on the agricultural farms. The average fluoride concentration in the study was found to be 1.54 mg/l. The relation between F and Cl and Cl and Na reveals that the fluoride concentrations are mainly attributed to geogenic sources. A comparison of the groundwater quality with the Saudi drinking water standards shows that the water is unfit for drinking. The high salinity and sodicity of the groundwater make it unfit for irrigation. Principal component analysis resulted in extraction of four principal components accounting for 79.5% of the total data variability and supports the fact that the natural hydrochemical processes (evaporation and ion exchange) control the overall groundwater chemistry.     

Geochemistry and origin of Dehoo manganese deposit,south Zahedan,southeastern Iran

Dehoo manganese deposit is located 52 km to the south of Zahedan in Sistan and Baluchestan Province, southeastern Iran. This deposit that lies in the central part of the Iranian Flysch Zone is lenticular in shape and lies above the micritic limestone-radiolarite cherts of the upper Cretaceous ophiolite unit. It is hosted within the reddish to brown radiolarite cherts and in places interlinks with them, so that the radiolarite chert packages play a key role for Mn mineralization in the region. Investigated ore-paragenetic successions and the geochemical characteristics of the Dehoo deposit were studied by means of major oxide, trace, and rare earth element (REE) contents that provide information as to the mineral origin. Strong positive correlations were found between major oxides and trace elements (Al₂O₃-TiO₂, r = 0.95; TiO₂-MgO, r = 0.94; Fe₂O₃-Al₂O₃, r = 0.90; MgO-Al₂O₃, r = 0.84; MgO-Fe₂O₃, r = 0.88; Fe₂O₃-TiO₂, r = 0.91; Fe₂O₃-K₂O, r = 0.74; Al₂O₃-K₂O, r = 0.69; Al₂O₃-V, r = 0.72; TiO₂-V, r = 0.73, and MgO-V, r = 0.69) that testify to the contribution of mafic terrigenous detrital material to the deposit. Chondrite-normalized REE patterns of all ore samples are characterized by negative Ce (0.06–0.15, average 0.10) and slightly positive Eu (0.29–0.45, average 0.36) anomalies. Based on ratios of Mn/Fe (average 56.23), Co/Ni (average 0.33), Co/Zn (average 0.38), U/Th (average 3.40), La/Ce (average 1.45), La_n/Nd_n (average 2.16), Dy_n/Yb_n (average 0.33), and light REE/heavy REE (average 8.40; LREE > HREE), as well as Ba (average 920 ppm) and total REE contents (average 6.96 ppm) negative Ce and positive Eu anomalies, Dehoo could be considered a predominantly submarine hydrothermal Mn deposit complemented by terrigenous detrital mafic material.     

Assessment of uranium in correlation with physico-chemical properties of drinking water of Northern Rajasthan

In the present study, analysis of 238U concentration in 40 drinking water samples collected from different locations of Jodhpur, Nagaur, Bikaner and Jhunjhunu districts of Rajasthan, India has been carried out by using high resolution inductively coupled plasma mass spectroscopy (HR-ICP-MS) technique. The water samples were taken from hand pumps and tube wells having depths ranging from 50 to 800 feet. The measured uranium concentration lies in the range from 0.89 to 166.89 μg l^-1 with the mean value of 31.72 μg l^-1. The measured uranium content in twelve water samples was found to be higher than the safe limit of 30 μg l^-1 as recommended by World Health Organization (WHO, 2011) and US Environmental Protection Agency (USEPA, 2011). Radiological risk calculated in the form of annual effective dose estimated from annual uranium intake ranges from 0.66 to 138.63 μSv y^-1 with the mean value of 26.28 μSv y^-1. The annual effective dose in two drinking water samples was found to be greater than WHO (2004) recommended level of 100 μSv y^-1. Chemical risk calculated in the form of lifetime average daily dose (LAAD) estimated from the water samples varies from 0.02 to 4.57 μg kg^-1 d^-1 with the mean value of 0.87 μg kg^-1 d^-1. The lifetime average daily dose (LAAD) of ten drinking water samples was found to be greater than WHO (2011) recommended level of 1 μg kg^-1 d^-1. The corresponding values of hazard quotient of 48% water samples were found to be greater than unity.A good positive correlation of uranium concentration with total dissolved solids (TDS) and conductance has been observed. However no correlation of uranium concentration with pH was observed. The results revels that uranium concentration in drinking water samples of the study area can cause radiological and chemical threat to the inhabitants.     

Simulating climate change impact on soil carbon sequestration in agro-ecosystem of mid-Himalayan landscape using CENTURY model

Soils play significant roles in global carbon cycle. The increase in atmospheric CO₂ due to climate change may have a significant impact on both soil organic carbon storage and management practices to sequester organic carbon in agricultural areas. The aim of the study was to simulate climate change impact on soil carbon sequestration using CENTURY model. The statistical downscaling model (SDSM) was used to downscale the climate variables (temperature and rainfall) under two scenarios A2 and B2 for three periods: 2020 (2011–2040), 2050 (2041–2070) and 2080 (2071–2099). Downscaling was better in case of temperature than precipitation, which was evident from coefficient of correlation for temperature (r ² = 0.91–0.99) and precipitation (r ² = 0.71–0.80). Downscaling of climate data revealed that the temperature may increase for the years 2020, 2050 and 2080 periods, whereas precipitation may increase till 2020 and then it may reduce in 2050 and 2080 as compared to 2020 in the study area. For CENTURY model, the input parameters were obtained through soil sampling and interviewing the farmers as well, whereas the climatic variables (maximum temperature, minimum temperature and precipitation) were taken from the SDSM output. The historical data of soils were collected from the literature, and six agricultural sites were selected for estimating soil carbon sequestration. After soil sampling of the same sites, it was found that the organic carbon had increased two times than historical data might be due to the addition of high organic matter in the form of farm yard manure. Therefore, the model was calibrated, considering more organic carbon in the area, and was validated using random points in the study area. Determination coefficient (r ² = 0.95) and RMSE (538 g c/m²) were computed to assess the accuracy of the model. The organic carbon was predicted from 2011 to 2099 and was compared with the 2011 predicted data. The study revealed that the amount of soil organic carbon in Bhaitan, Kanatal, Kotdwar, Malas, Pata and Thangdhar sites may reduce by 11.6, 15.8, 17.19, 13.54, 19.2 and 12.7%, respectively, for A2 scenario and by 9.62, 15.6, 15.72, 11.45, 16.96 and 13.36% for B2 scenario up to 2099. The study provides comprehensive possible future scenarios of soil carbon sequestration in the mid-Himalaya for scientists and policy makers.     

The use of selected research methods to describe the pore space of dolomite from copper ore mine,Poland

Basic knowledge of the characteristics of copper-bearing rock such as dolomite is essential to locate those areas of the deposit which have different structural and textural properties. Those regions can be important in terms of the assessment of the possibilities of gas accumulating in them as well as in terms of gasogeodynamic hazard. To better understand those threats, it is necessary to locate, monitor and analyse those areas in detail. This article characterises the structural and textural parameters of dolomite from the Polkowice–Sieroszowice copper mine in Poland. The study involved five samples from various areas of the mine. A number of research methods were selected. Reflected and transmitted light microscopy (MS), computer microtomography (Micro-CT), gas adsorption porosimetry (LPNA), mercury porosimetry (MIP), helium and quasi-fluid pycnometry (Pycno. He, DryFlo). Each of the methods examined a different scope of the pore size, which enabled to achieve a full view of the porous nature of those rocks. We determined their porosity (open, closed, total), surface area as well as mean size and volume of the pores. Also, we studied the character and the pore size distribution from a few nm to a few mm. Comprehensive dolomite properties analyses showed that these rocks are characterised by high structural variability. They have mesopores and macropores but few micropores. The analyses presented in this paper are determined by a large petrographic diversity of the deposits containing dolomite. This article is an example of a comprehensive approach to the rock analysis in copper ore mines.     

Groundwater depth prediction in a shallow aquifer in north China by a quantile regression model

There is a close relationship between groundwater level in a shallow aquifer and the surface ecological environment; hence, it is important to accurately simulate and predict the groundwater level in eco-environmental construction projects. The multiple linear regression (MLR) model is one of the most useful methods to predict groundwater level (depth); however, the predicted values by this model only reflect the mean distribution of the observations and cannot effectively fit the extreme distribution data (outliers). The study reported here builds a prediction model of groundwater-depth dynamics in a shallow aquifer using the quantile regression (QR) method on the basis of the observed data of groundwater depth and related factors. The proposed approach was applied to five sites in Tianjin city, north China, and the groundwater depth was calculated in different quantiles, from which the optimal quantile was screened out according to the box plot method and compared to the values predicted by the MLR model. The results showed that the related factors in the five sites did not follow the standard normal distribution and that there were outliers in the precipitation and last-month (initial state) groundwater-depth factors because the basic assumptions of the MLR model could not be achieved, thereby causing errors. Nevertheless, these conditions had no effect on the QR model, as it could more effectively describe the distribution of original data and had a higher precision in fitting the outliers.     

Mapping of groundwater prospective zones integrating remote sensing,geographic information systems and geophysical techniques in El-Qaà Plain area,Egypt

The geospatial mapping of groundwater prospective zones is essential to support the needs of local inhabitants and agricultural activities in arid regions such as El-Qaà area, Sinai Peninsula, Egypt. The study aims to locate new wells that can serve to cope with water scarcity. The integration of remote sensing, geographic information systems (GIS) and geophysical techniques is a breakthrough for groundwater prospecting. Based on these techniques, several factors contributing to groundwater potential in El-Qaà Plain were determined. Geophysical data were supported by information derived from a digital elevation model, and from geologic, geomorphologic and hydrologic data, to reveal the promising sites. All the spatial data that represent the contributing factors were integrated and analyzed in a GIS framework to develop a groundwater prospective model. An appropriate weightage was specified to each factor based on its relative contribution towards groundwater potential, and the resulting map delineates the study area into five classes, from very poor to very good potential. The very good potential zones are located in the Quaternary deposits, with flat to gentle topography, dense lineaments and structurally controlled drainage channels. The groundwater potential map was tested against the distribution of groundwater wells and cultivated land. The integrated methodology provides a powerful tool to design a suitable groundwater management plan in arid regions.