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991.
George G. Waldbusser Erin P. Voigt Heather Bergschneider Mark A. Green Roger I. E. Newell 《Estuaries and Coasts》2011,34(2):221-231
Anthropogenic carbon dioxide (CO2) emissions reduce pH of marine waters due to the absorption of atmospheric CO2 and formation of carbonic acid. Estuarine waters are more susceptible to acidification because they are subject to multiple
acid sources and are less buffered than marine waters. Consequently, estuarine shell forming species may experience acidification
sooner than marine species although the tolerance of estuarine calcifiers to pH changes is poorly understood. We analyzed
23 years of Chesapeake Bay water quality monitoring data and found that daytime average pH significantly decreased across
polyhaline waters although pH has not significantly changed across mesohaline waters. In some tributaries that once supported
large oyster populations, pH is increasing. Current average conditions within some tributaries however correspond to values
that we found in laboratory studies to reduce oyster biocalcification rates or resulted in net shell dissolution. Calcification
rates of juvenile eastern oysters, Crassostrea virginica, were measured in laboratory studies in a three-way factorial design with 3 pH levels, two salinities, and two temperatures.
Biocalcification declined significantly with a reduction of ∼0.5 pH units and higher temperature and salinity mitigated the
decrease in biocalcification. 相似文献
992.
Basalts interbedded with oil source rocks are discovered frequently in rift basins of eastern China, where CO2 is found in reservoirs around or within basalts, for example in the Binnan reservoir of the Dongying Depression. In the reservoirs, CO2 with heavy carbon isotopic composition (δ13C>-10‰ PDB) is in most cases accounts for 40% of the total gas reserve, and is believed to have resulted from degassing of basaltic magma from the mantle. In their investigations of the Binnan reservoir, the authors suggested that the CO2 would result from interactions between the source rocks and basalts. As the source rocks around basalts are rich in carbonate minerals, volcanic minerals, transition metals and organic matter, during their burial history some of the transition metals were catalyzed on the thermal degradation of organic matter into hydrocarbons and on the decomposition of carbonate minerals into CO2, which was reproduced in thermal simulations of the source rocks with the transition metals (Ni and Co). This kind of CO2 accounts for 55%-85% of the total gas reserve generated in the process of thermal simulation, and its δ13C values range from -11‰- -7.2‰ PDB, which are very similar to those of CO2 found in the Binnan reservoir. The co-generation of CO2 and hydrocarbon gases makes it possible their accumulation together in one trap. In other words, if the CO2 resulted directly from degassing of basaltic magma or was derived from the mantle, it could not be accumulated with hydrocarbon gases because it came into the basin much earlier than hydrocarbon generation and much earlier than trap formation. Therefore, the source rocks around basalts generated hydrocarbons and CO2 simultaneously through catalysis of Co and Ni transition metals, which is useful for the explanation of co-accumulation of hydrocarbon gases and CO2 in rift basins in eastern China. 相似文献
993.
A model for estimating the value of sampling programs and the optimal number of samples for contaminated soil 总被引:1,自引:0,他引:1
Pär-Erik Back 《Environmental Geology》2007,52(3):573-585
A model is presented for estimating the value of information of sampling programs for contaminated soil. The purpose is to calculate the optimal number of samples when the objective is to estimate the mean concentration. A Bayesian risk–cost–benefit decision analysis framework is applied and the approach is design-based. The model explicitly includes sample uncertainty at a complexity level that can be applied to practical contaminated land problems with limited amount of data. Prior information about the contamination level is modelled by probability density functions. The value of information is expressed in monetary terms. The most cost-effective sampling program is the one with the highest expected net value. The model was applied to a contaminated scrap yard in Göteborg, Sweden, contaminated by metals. The optimal number of samples was determined to be in the range of 16–18 for a remediation unit of 100 m2. Sensitivity analysis indicates that the perspective of the decision-maker is important, and that the cost of failure and the future land use are the most important factors to consider. The model can also be applied for other sampling problems, for example, sampling and testing of wastes to meet landfill waste acceptance procedures. 相似文献
994.
Jiangrong Xiao Tianyou Peng Dingning Ke Ling Zan Zhenghe Peng 《Physics and Chemistry of Minerals》2007,34(4):275-285
CdS/rectorite nanocomposite was synthesized via a cation-exchange reaction followed by a sulfurization process. The obtained
samples were characterized by using X-ray diffraction (XRD), fourier transform infrared spectra (FTIR), transmission electron
microscope (TEM), UV-Vis diffuse reflectance spectra (DRS), and thermal analysis. The measured results indicate that CdS species
in the composites exist in the form of pillars and nanoparticles, the crystallized CdS particles are in the hexagonal symmetry.
The photocatalytic activities of the pillared nanocomposite were enhanced significantly comparing with the bare rectorite
and the pure CdS. Moreover, the photostabilities of the obtained nanocomposites are also better than that of the pure CdS
due to the hosts retard the photocorrosion of the CdS. 相似文献
995.
Hanifi Canakci 《Environmental Geology》2007,53(4):915-922
This paper focuses on an investigation of the possible causes for the collapse of limestone caves in Gaziantep, Turkey. The
city contains a lot of man-made caves, at a shallow depth, of various width and length. These caves were mainly excavated
to provide work or storage space. As the city has been growing fast with increased population, many structures were constructed
over these caves. Recently, two caves collapsed and five houses were damaged. These caves are all made of limestone and it
was observed after the collapse that the limestone was saturated with water due to sewer pipe leakage and surface water. Tests
were carried out on the limestone and it was determined that the compressive strength of limestone decreases by about 50%
and the tensile strength decreased by about 80% when saturated with water. It was concluded that the reduced strength of the
limestone combined with additional loads due to the factors mentioned above seem to be the main reason for these collapses. 相似文献
996.
Dieter F. Mertz Paul R. Renne Michael Wuttke Clemens Mödden 《International Journal of Earth Sciences》2007,96(2):353-361
The fauna of the Enspel (Westerwald) and the neighbouring Kärlich (Neuwied basin) fossil deposits correspond to the Upper Oligocene Mammal Paleogene (MP) reference level 28 and 28–30, respectively. Basaltic flows and a trachyte tuff terminating and predating the fossil deposit sedimentation allow to numerically calibrate the MP reference levels by radioisotope dating. Laser fusion 40Ar/39Ar step heating on volcanic feldspars yield a time interval of 24.9–24.5 Ma for reference level MP28 at Enspel and a maximum age of 25.5 Ma for the time interval MP28–MP30 at Kärlich. Interpolation between the time intervals determined for the Enspel reference level MP28 and the age of the global Oligocene/Miocene boundary of 24.0 ± 0.1 Ma taken from literature results in time intervals of 24.5–24.2 Ma and 24.2–23.9 Ma for the younger reference levels MP29 and MP30, respectively. These intervals of ≤ 0.4 m.y. for MP reference levels of the latest Oligocene are short relative to older Oligocene MP reference levels 21–27 between 34 and 25 Ma. Since subdivision into MP reference levels essentially is based on assemblages of mammal taxa and on evolutionary changes in tooth morphology of mammals short MP time intervals during the latest Oligocene indicate a rapid evolutionary change relative to the early Oligocene. 相似文献
997.
Hugues Raimbourg Bruno Goffé Laurent Jolivet 《Contributions to Mineralogy and Petrology》2007,153(1):1-28
Caledonian eclogite-facies metamorphism partially reworking Grenvillian granulite-facies anorthosite allows us to study the processes of garnet reequilibration at high pressure and to reconstruct the evolution of the unit near metamorphic peak conditions. Our results indicate that eclogite-facies metamorphism happened in two successive phases: first, inherited granulitic garnet was fractured and reequilibrated from their boundaries (crystal or fracture rims); then eclogite-facies minerals were crystallised in the fractures as overgrowths on inherited garnets. The reequilibration of inherited garnets is achieved through Fe2+Mg−1 exchange, whereas eclogite-facies garnets crystallised during the subsequent phase are notably richer in Ca than un- and re-equilibrated granulitic garnet. Pseudosection construction shows that this lack in Ca reequilibration cannot be related to variations in thermodynamic conditions (a
H2O, reacting system composition) between the two phases. From the compilation of the available data, the reequilibration of granulitic garnet seems to be controlled by the inefficient intra- and inter-granular transport properties of Ca compared to Fe2+ and Mg. While these kinetic factors confine garnet reequilibration to Fe2+Mg−1 exchange, the extent of reequilibration along this exchange vector is controlled by partitioning with adjacent omphacite. On the contrary to the diffusional reequilibration of granulitic garnet that lasted for several My according to our modelling of the diffusional relaxation, the strong compositional gradients between eclogite-facies and reequilibrated garnets, which are almost unaffected by diffusional reequilibration, provide evidence that rapid exhumation followed the crystallisation of eclogite-facies minerals. We propose that the movement reversal itself, from burial to exhumation, and associated deformation and fluid flow, triggered this crystallisation event. The resulting evolution near metamorphic peak conditions is therefore strongly asymmetrical: on the one hand, the prograde diffusional relaxation profiles indicate slow movement during the last stages of burial, whereas the unaffected retrograde overgrowth indicates fast exhumation rates. 相似文献
998.
Fukun Chen Xiang-Hui Li Xiu-Li Wang Qiu-Li Li Wolfgang Siebel 《International Journal of Earth Sciences》2007,96(6):1179-1194
The Baoshan block of the Tethyan Yunnan, southwestern China, is considered as northern part of the Sibumasu microcontinent.
Basement of this block that comprises presumably greenschist-facies Neoproterozoic metamorphic rocks is covered by Paleozoic
to Mesozoic low-grade metamorphic sedimentary rocks. This study presents zircon ages and Nd–Hf isotopic composition of granites
generated from crustal reworking to reveal geochemical feature of the underlying basement. Dating results obtained using the
single zircon U–Pb isotopic dilution method show that granites exposed in the study area formed in early Paleozoic (about
470 Ma; Pingdajie granite) and in late Yanshanian (about 78–61 Ma, Late Cretaceous to Early Tertiary; Huataolin granite).
The early Paleozoic granite contains Archean to Mesoproterozoic inherited zircons and the late Yanshanian granite contains
late Proterozoic to early Paleozoic zircon cores. Both granites have similar geochemical and Nd–Hf isotopic charateristics,
indicating similar magma sources. They have whole-rock T
DM(Nd) values of around 2,000 Ma and zircon T
DM(Hf) values clustering around 1,900–1,800 and 1,600–1,400 Ma. The Nd–Hf isotopic data imply Paleoproterozoic to Mesoproterozoic
crustal material as the major components of the underlying basement, being consistent with a derivation from Archean and Paleoproterozoic
terrains of India or NW Australia. Both granites formed in two different tectonic events similarly originated from intra-crustal
reworking. Temporally, the late Yanshanian magmatism is probably related to the closure of the Neotethys ocean. The early
Paleozoic magmatism traced in the Baoshan block indicates a comparable history of the basements during early Paleozoic between
the SE Asia and the western Tethyan belt, such as the basement outcrops in the Alpine belt and probably in the European Variscides
that are considered as continental blocks drifting from Gondwana prior to or simultaneously with those of the SE Asia. 相似文献
999.
1000.
Coupling of oceanic and continental crust during Eocene eclogite-facies metamorphism: evidence from the Monte Rosa nappe,western Alps 总被引:1,自引:0,他引:1
Thomas J. Lapen Clark M. Johnson Lukas P. Baumgartner Giorgio V. Dal Piaz Susanne Skora Brian L. Beard 《Contributions to Mineralogy and Petrology》2007,153(2):139-157
High precision U–Pb geochronology of rutile from quartz–carbonate–white mica–rutile veins that are hosted within eclogite
and schist of the Monte Rosa nappe, western Alps, Italy, indicate that the Monte Rosa nappe was at eclogite-facies metamorphic
conditions at 42.6 ± 0.6 Ma. The sample area [Indren glacier, Furgg zone; Dal Piaz (2001) Geology of the Monte Rosa massif: historical review and personal comments. SMPM] consists of eclogite boudins that are exposed
inside a south-plunging overturned synform within micaceous schist. Associated with the eclogite and schist are quartz–carbonate–white
mica–rutile veins that formed in tension cracks in the eclogite and along the contact between eclogite and surrounding schist.
Intrusion of the veins at about 42.6 Ma occurred at eclogite-facies metamorphic conditions (480–570°C, >1.3–1.4 GPa) based
on textural relations, oxygen isotope thermometry, and geothermobarometry. The timing of eclogite-facies metamorphism in the
Monte Rosa nappe determined in this study is identical to that of the Gran Paradiso nappe [Meffan-Main et al. (2004) J Metamorphic Geol 22:261–281], confirming that these two units have shared the same Alpine metamorphic history. Furthermore,
the Gran Paradiso and Monte Rosa nappes underwent eclogite-facies metamorphism within the same time interval as the structurally
overlying Zermatt-Saas ophiolite [∼50–40 Ma; e.g., Amato et al. (1999) Earth Planet Sci Lett 171:425–438; Mayer et al. (1999) Eur Union Geosci 10:809 (abstract); Lapen et al. (2003) Earth Planet Sci Lett 215:57–72]. The nearly identical P–T–t histories of the Gran Paradiso, Monte Rosa, and Zermatt-Saas units suggest that these units shared a common Alpine tectonic
and metamorphic history. The close spatial and temporal associations between high pressure (HP) ophiolite and continental
crust during Alpine orogeny indicates that the HP internal basement nappes in the western Alps may have played a key role
in exhumation and preservation of the ophiolitic rocks through buoyancy-driven uplift. Coupling of oceanic and continental
crust may therefore be critical in preventing permanent loss of oceanic crust to the mantle. 相似文献