Natural baseline quality of Madrid Tertiary Detrital Aquifer groundwater (Spain): a basis for aquifer management

The Madrid Tertiary Detrital Aquifer is one of the largest and most important aquifers of Spain. This paper assesses the most relevant controls on the natural baseline quality and the dominant chemical processes within the aquifer. The hydrochemistry of the groundwater is variable despite the relative uniformity of the detrital sediments. The natural baseline is expressed as a range of values that are controlled by lithological and hydrological factors; spatial variations of groundwater chemistry are related to changes in rock type, water-rock interaction and the residence time of groundwater. The fundamental chemical processes within the Arkosic aquifer are hydrolysis of silicates, dissolution of carbonates, dissolution of evaporites (only in the vicinity of the transitional facies), ion exchange, neoformation of clays, precipitation of silica as cement, and precipitation of carbonates due to increasing temperature along the downward pathways. Some chemical and physico-chemical parameters like pH, dissolved oxygen, and hardness, and several elements like calcium, sodium, magnesium, silica, and arsenic show an evolutionary trend according to groundwater flow path. A gradual increase in arsenic concentration from recharge areas to discharge areas is observed; it is the main natural water constituent that deteriorates the quality of the fresh Madrid groundwater as a drinking water supply. The occasionally elevated arsenic concentrations originate from natural sources. The concentration and mobility of arsenic seems to be controlled by pH-dependent anion exchange processes resulting from the evolution to Na-HCO₃ water.     

Distribution of arsenic and other minor trace elements in the groundwater of Ischia Island (southern Italy)

The island of Ischia belongs to the active volcanic area of Naples. It is formed from Quaternary volcanic rocks and exhibits intense hydrothermal activity, which is manifested through numerous springs, fumaroles and sporadic geysers. The content of minor and trace elements in groundwater has been analyzed, including some elements that are considered toxic for humans. Mean concentrations of As, B, Fe, Mn, Sb, and Se in samples from 43 aquifer points exceed the WHO recommended values and the limits set by European and Italian legislation (98/83/CE and DM 471, respectively). In general, the spatial distribution of the elements follows a common pattern: it is governed by a marked structural control, which favors hydrochemical processes that liberate the elements into the water.     

Neotectonics and morphotectonics of the southern Almería region (Betic Cordillera-Spain) kinematic implications

Most previous studies related to the recent tectonic development of southeastern Betic Cordillera, and in particular the south of Almería, agree with the kinematic variety that can be observed in the post-Miocene structures at different scales. This variety is difficult to explain if we consider only the regional stress field related to the convergence of the Eurasian and African plates that remained relatively steady over the last 9 Ma. This work proposes a block tectonics with horizontal and vertical relative movements driven by strike-slip movements of major faults to explain the variety of kinematics observed in the area from Middle Miocene to present. The combined activity of the Alpujarras fault zone (dextral strike-slip) and the Carboneras fault zone (sinistral strike-slip) induces, within the major block bounded by them, the squeezing of minor pre-existing fault bounded crustal blocks. This process generates traction areas inside the escaping block, which are linked with the existence of gradients of westward movement rate. This tectonics can explain some of the structures related with the extensional tectonics predominant in the south of Almería province and the development of the minor and major morphostructures driven by faults with different kinematics. The tectonics of blocks proposed is useful to give a coherent interpretation of apparently incoherent local structural data into a regional and homogeneous compressional stress field.Sadly, Professor José L. Hernández Enrile died in April 2003, and thus this paper represents his last thoughts on the topic. Reviews were addressed by the first author; however, some of the suggested changes were discussed to preserve Professor Hernández Enriless thoughts.     

The X- Y-, and H-matrices for molecular scattering

A method is described to calculate theX-,Y-, andH-matrices for molecular scattering in a homogeneous plane-parallel atmosphere. This method is based on the method of discrete ordinates by Chandrasekhar. A sample of results in 7 decimals is given and the accuracy of the method presented is discussed.     

Non integrability of theJ 2 problem

We consider the motion of a massless particle around an oblate planet, keeping only in the expression of the perturbing potential the second degree zonal harmonic. We prove the analytical non integrability of this problem, by using Ziglin's theorem and the Yoshida criterion for homogeneous potentials.     

A Holocene pollen and diatom record from Vanderlin Island, Gulf of Carpentaria, lowland tropical Australia

Sedimentary, palynological and diatom data from a dunefield lake deposit in the interior of Vanderlin Island in the Gulf of Carpentaria are presented. Prior to the formation of present perennial lake conditions, the intensified Australian monsoon associated with the early Holocene marine transgression allowed Cyperaceae sedges to colonise the alluvial margins of an expansive salt flat surrounded by an open Eucalyptus woodland. As sea level stabilised between 7500 and 4500 cal yr B.P. coastal dunes ceased to develop allowing dense Melaleuca forest to establish in a Restionaceae swamp. Dune-sand input into the swamp was diminished further as the increasingly dense vegetation prevented fluvial and aeolian transported sand arriving from coastal sources. This same process impounded the drainage basin allowing a perennial lake to form between 5500 and 4000 cal yr B.P. Myriophyllum and other aquatic taxa colonised the lake periphery under the most extensive woodland recorded for the Holocene. The palynological data support an effective precipitation model proposed for northern Australia that suggests more variable conditions in the late Holocene. A more precise measure of effective precipitation change is provided by diatom-based inferences that indicate few changes in lake hydrology. Such interpretations are explained in terms of palynological sensitivity to adjustments in local fire regimes where regional precipitation change may only be recorded indirectly through fire promoting mechanisms, including intensified ENSO periodicity and human impact.     

Metal Complexation with Different types of Soluble and Adsorbed Freshwater Ligands Followed by DPASV

In order to understand metal speciation in a polluted river (Este River, Northern Portugal) filtrate, freeze dried particles and organics desorbed from surfaces were titrated with Cd(II) and Zn(II), followed by differential pulse anodic stripping voltammetry (DPASV). The obtained results are compared with those previously published for Pb(II) and Cu(II). Due to the heterogeneity of the system, a continuous and a discrete ligand model were used to interpret the titration data. Two types of ligands could be detected and quantified by the discrete ligand model: small molecules with high affinities for cations such as Cd(II), Cu(I), and Zn(II) and macromolecules with higher affinities for Pb(II) and Cu(II). Small ligands were strongly adsorbed onto the particles, as inferred from the desorption of Zn(II) during titration with Pb(II) and Cd(II). The total concentrations of the different ligands and the complex formation constants with the different metals are reported.     

Recent deformations and hydrothermal fields in the northern part of Paramushir Island

This paper discusses application of a structural-morphologic method for interpreting covered territories; in the present case, covered by lava flows. The study resulted in recognizing a network of recent faults and in determining their strike-slip kinematics. The relation of volcanoes and thermal springs to these faults is discussed.     

Microbial methane turnover at mud volcanoes of the Gulf of Cadiz

The Gulf of Cadiz is a tectonically active area of the European continental margin and characterised by a high abundance of mud volcanoes, diapirs, pockmarks and carbonate chimneys. During the R/V SONNE expedition “GAP-Gibraltar Arc Processes (SO-175)” in December 2003, several mud volcanoes were surveyed for gas seepage and associated microbial methane turnover. Pore water analyses and methane oxidation measurements on sediment cores recovered from the centres of the mud volcanoes Captain Arutyunov, Bonjardim, Ginsburg, Gemini and a newly discovered, mud volcano-like structure called “No Name” show that thermogenic methane and associated higher hydrocarbons rising from deeper sediment strata are completely consumed within the seabed. The presence of a distinct sulphate-methane transition zone (SMT) overlapping with high sulphide concentrations suggests that methane oxidation is mediated under anaerobic conditions with sulphate as the electron acceptor. Anaerobic oxidation of methane (AOM) and sulphate reduction (SR) rates show maxima at the SMT, which was found between 20 and 200 cm below seafloor at the different mud volcanoes. In comparison to other methane seeps, AOM activity (<383 mmol m⁻² year⁻¹) and diffusive methane fluxes (<321 mmol m⁻² year⁻¹) in mud volcano sediments of the Gulf of Cadiz are low to mid range. Corresponding lipid biomarker and 16S rDNA clone library analysis give evidence that AOM is mediated by a mixed community of anaerobic methanotrophic archaea and associated sulphate reducing bacteria (SRB) in the studied mud volcanoes. Little is known about the variability of methane fluxes in this environment. Carbonate crusts littering the seafloor of mud volcanoes in the northern part of the Gulf of Cadiz had strongly ¹³C-depleted lipid signatures indicative of higher seepage activities in the past. However, actual seafloor video observations showed only scarce traces of methane seepage and associated biological processes at the seafloor. No active fluid or free gas escape to the hydrosphere was observed visually at any of the surveyed mud volcanoes, and biogeochemical measurements indicate a complete methane consumption in the seafloor. Our observations suggest that the emission of methane to the hydrosphere from the mud volcano structures studied here may be insignificant at present.     

Rate constants of dissolution derived from the measurements of mass balance in hydrological catchments

The experimental rate constant of dissolution of oligoclase, 1.7 × 10 ^{? 2} mol · m^?2 · s^?1 (Busenberg and Clemency, 1976), is compared with rate constants, 5.2 × 10^?15 to 6.8 × 10^?13 mol · m^?2· s^?1, derived from mass-balance measurements of sodium in hydrological catchments. The wide range of the field-based rate constants mainly reflects the uncertainty in the evaluation of the specific wetted surface of rock in aquifer. The most probable order of magnitude of the field rate constant is 10^?14 mol · m^?2· s^?1. The difference between the experimental and field rate constant is only partly caused by lower temperature and lowerP_CO2 in the aquifer. The main reason for the discrepancy is the diverse history of the mineral surfaces undergoing reaction.It is suggested that the feldspar surfaces in an aquifer are old, compared to those of feldspars utilized in laboratory experiments. They have fewer defects and are smooth. The fresh surfaces of feldspars studied in the laboratory consist of many kinks and ledges and small-area terraces which dissolve faster.The differences in rate constants derived from field data on several specific catchments indicate that the anthropogenic processes which have operated during this century in Central Europe speed up the rate of dissolution by a factor of three. Modern agricultural practices speed up the rate by a factor of five.