Sedimentary carbon forms in relation to climate and phytoplankton biomass in a large,shallow, hard-water boreal lake

Carbon storage in lakes can have huge implications for the global carbon cycle, as lakes annually accumulate up to one half the amount of organic carbon buried in marine sediments. Yet little is known of the effect of recent climate change on carbon storage in lakes. We analyzed century-scale time series of climate variables (precipitation, temperature, NAO winter index) and profiles of sediment characteristics in a dated sediment core from shallow, eutrophic Lake Võrtsjärv, south Estonia. We used path analysis to evaluate the effect of climate conditions on phytoplankton biomass in the lake and accumulation of organic and inorganic carbon in the sediment. Changes in winter and spring climate influenced the lake’s phytoplankton growth significantly. Carbon pathways in hard-water Lake Võrtsjärv were influenced by both hydrological (most significant in colder periods) and biogeochemical processes. Increased nutrient and water input to Lake Võrtsjärv, anticipated with projected climate warming, favours greater in-lake productivity, larger accumulation of inorganic carbon in sediments, and an increase in organic carbon mineralisation, which fuels atmospheric greenhouse gas emissions from the lake.     

Variations in annual snowline and area of an ice-covered stratovolcano in the Cordillera Ampato,Peru, using remote sensing data (1986–2014)

This research focuses on the recent variations in the annual snowline and the total glaciated area of the Nevado Coropuna in the Cordillera Ampato, Peru. Maximum snowline altitude towards the end of dry season is taken as a representative of the equilibrium line altitude of the year, which is an indirect measurement of the annual mass balance. We used Landsat and IRS LISS3 images during the last 30 years due to its better temporal coverage of the study site. It is found that there was a decrease of 26.92% of the glaciated area during 1986–2014. We calculated the anomalies in precipitation and temperature in this region and also tried to correlate the changes in glacier parameters with the combined influence of El Niño – Southern Oscillation (ENSO) and pacific decadal oscillation (PDO). It is concluded that the snowline of Nevado Coropuna has been fluctuated during ENSO, and maximum fluctuations were observed when ENSO and PDO were in phase.     

Multi-model climate projections of the main cyclogenesis hot-spots and associated winds over the eastern coast of South America

Climate Dynamics - In this study, multi-model ensembles are used to understand regional features of future climate trends of cyclones and associated winds in eastern South America. For this, we...     

Dating recent floodplain sediments in the Hawkesbury‐Nepean River system,eastern Australia using single‐grain quartz OSL

Two fluvial sediment cores taken from a floodplain of the Hawkesbury‐Nepean River system in the Sydney region, eastern Australia are dated using Optically Stimulated Luminescence (OSL) to provide a reliable chronology essential for the management and planning of water resources. Nine charcoal ¹⁴C (AMS) dates constrain these OSL ages. Quartz extracted from seven OSL samples from each of the cores was measured using both single‐grain and multi‐grain OSL techniques. Three of the single‐grain natural dose distributions appear to be well bleached, but the others appear to be incompletely bleached to various degrees. Three minimum‐age models (MAM, MAM_UL and IEU) are applied to the single‐grain dose distributions. We conclude that these models give consistent age estimates. For one of the cores it appears to be necessary to use a minimum‐age model to obtain accurate ages, but in the other core incomplete bleaching is probably less important than postdepositional mixing and mixing during sampling. As a result, the burial age is probably best estimated using the weighted average of the individual single‐grain dose estimates. The application of multi‐grain OSL techniques to these samples results in an average apparent age overestimation of ～200 years, which is significant for these samples, but negligible for sediments older than a few thousand years. The intention is that the chronology obtained in this study will be used in conjunction with a proxy flood record, derived from floodplain sediments, to gain an understanding of the long‐term variability in periods of high and low rainfall in eastern Australia.     

Intra- and inter-specific variability in total and methylmercury bioaccumulation by eight marine fish species from the Azores

We relate fish biological and ecological characteristics to total and organic mercury concentrations to determine whether accumulation is influenced by trophic level, Hg concentration in the diet, and vertical distribution. Levels of total mercury and methylmercury were determined in the muscle tissue of eight species of fish: Pagellus acarne, Trachurus picturatus, Phycis phycis, P. blennoides, Polyprion americanus, Conger conger, Lepidopus caudatus and Mora moro, caught in the Azores. All such fishes are commercially valuable and were selected to include species from a wide range of vertical distributions from epipelagic (<200 m) to mesopelagic (>300 m) environments. Methylmercury was the major form accumulated in all species, comprising an average of 88.1% of total mercury. Concentrations of mercury (total and methylmercury) increased with age, length and weight. Based on data from other studies, mercury concentrations in fish diet were estimated. Mercury levels in food ranged from 0.08 to 0.32 ppm, dry weight. Hg concentrations in the food and in muscle tissue from different species were positively correlated. Total Hg levels in the muscles were approximately nine times those estimated in food. Total mercury concentrations in muscle were positively correlated with both trophic level and median depth. Such enhanced mercury bioaccumulation in relation to depth appears to be determined primarily by concentrations in food and ultimately by water chemistry, which controls mercury speciation and uptake at the base of the food chain.     

Fault tectonics,neotectonic stresses,and hidden uranium mineralization in the area adjacent to the Strel’tsovka Caldera

The scheme of recent fault tectonics and neotectonic stresses of the area adjacent to the Strel’tsovka Caldera in the southeastern Transbaikal region has been compiled for the first time on the basis of structural and geomorphic study. The faults were ranked by criteria of slip direction stability along separate segments and their expression in topography. Neotectonic stresses of corresponding ranks were ascertained as well. The heterogeneity of neotectonic stress field is related to the mosaic development of compression, extension, and the three-axial stress state. Comparison of morphogenetic features of recent and older faults shows the different character of the deformation mechanism and orientation of tectonic displacements. It has been established that the Strel’tsovka Caldera and its northwestern segment, in particular, developed as an echeloned system of pull-apart grabens, but the caldera itself is situated in a recent rise, whereas the northwestern segment is located in a neotectonic depression corresponding to the Dry Urulyungui Basin filled with volcanic and sedimentary rocks. Such a structure markedly expands the outlook for discovery of hidden uranium mineralization in the studied area. The elaborated scheme of neotectonic faults and stresses reflects the postore geodynamic setting and completes the reconstruction of geodynamic conditions pertaining to the periods of preore preparation and ore-forming tectonomagmatic reactivation.     

Presence of fluoroquinolones and sulfonamides in urban sewage sludge and their degradation as a result of composting

The concentrations of some widely used pharmaceuticals, namely fluoroquinolones (ciprofloxacin C₁₇ H₁₈FN₃O₃, norfloxacin C₁₇ H₁₈FN₃O₃ and ofloxacin C₁₈ H₂₀FN₃O₄ and sulfonamides (sulfadimethoxine C₁₂ H₁₄N₄O₄s and sulfamethoxazole C₁₀ H₁₁N₃O₃S were determined in urban sewage sludge utilized for making compost. The levels of degradation of these pharmaceuticals resulting from sludge treatment were assessed. The concentrations of the studied pharmaceuticals sufficiently varied both in sewage sludge and in compost and due to this phenomenon the possible danger resulting from the presence of pharmaceuticals in sewage sludge, used for composting, can not be ignored. The concentrations of the studied pharmaceuticals were lower in compost, if compared to the relevant concentrations in sewage sludge. The highest pharmaceutical concentration in sewage sludge — 426 μg/kg — was detected in the case of ciprofloxacin. The highest concentrations present in compost were 22 μg/kg of norfloxacin and 20 μg/kg of ciprofloxacin. Results show that before using the sewage sludge for making compost or before using the compost a fertilizer for food plants, they should be carefully tested against the content of commonly used pharmaceuticals.     

Nebular emission-line profiles of Type Ib/c supernovae – probing the ejecta asphericity

In order to assess qualitatively the ejecta geometry of stripped-envelope core-collapse supernovae (SNe), we investigate 98 late-time spectra of 39 objects, many of them previously unpublished. We perform a Gauss-fitting of the [O  i ]  λλ6300, 6364  feature in all spectra, with the position, full width at half maximum and intensity of the  λ6300  Gaussian as free parameters, and the  λ6364  Gaussian added appropriately to account for the doublet nature of the [O  i ] feature. On the basis of the best-fitting parameters, the objects are organized into morphological classes, and we conclude that at least half of all Type Ib/c SNe must be aspherical. Bipolar jet models do not seem to be universally applicable, as we find too few symmetric double-peaked [O  i ] profiles. In some objects, the [O  i ] line exhibits a variety of shifted secondary peaks or shoulders, interpreted as blobs of matter ejected at high velocity and possibly accompanied by neutron-star kicks to assure momentum conservation. At phases earlier than ∼200 d, a systematic blueshift of the [O  i ]  λλ6300, 6364  line centroids can be discerned. Residual opacity provides the most convincing explanation of this phenomenon, photons emitted on the rear side of the SN being scattered or absorbed on their way through the ejecta. Once modified to account for the doublet nature of the oxygen feature, the profile of Mg  i ]  λ4571  at sufficiently late phases generally resembles that of [O  i ]  λλ6300, 6364  , suggesting negligible contamination from other lines and confirming that O and Mg are similarly distributed within the ejecta.     

Study of the transfer from the Earth to a halo orbit around the equilibrium pointL 1

The purpose of this paper is to study a transfer strategy from the vicinity of the Earth to a halo orbit around the equilibrium pointL ₁ of the Earth-Sun system. The study is done in the real solar system (we use the DE-118 JPL ephemeris in the simulations of motion) although some simplified models, such as the restricted three body problem (RTBP) and the bicircular problem, have been also used in order to clarify the geometrical aspects of the problem. The approach used in the paper makes use of the hyperbolic character of the halo orbits under consideration. The invariant stable manifold of these orbits enables the transfer to be achieved with, theoretically, only one manoeuvre: the one of insertion into the stable manifold. For the total v required, the figures obtained are similar to the ones given by the standard procedures of optimization.