Total Mercury Distribution and Volatilization in Microcosms with and Without the Aquatic Macrophyte Eichhornia Crassipes

Mercury (Hg) is one of the most toxic pollutants and spreads in the environment according to its affinity to several compartments. Aquatic macrophytes, such as Eichhornia crassipes, are known as sites for accumulation of Hg and methylmercury formation. The objective of this research was to observe Hg distribution among air, water and whole plants of the macrophyte E. crassipes for 17?days. The distribution of a single ²⁰³Hg spike was evaluated by gamma spectrometry. Two experiments, with and without macrophytes, were made, and the compartments analyzed for the presence of Hg were air, 0.2-μm filtered water, suspended and settled particles, roots, leafs, petioles and adsorption on the desiccators walls. ²⁰³Hg was detected in all analyzed compartments, and the highest total Hg concentrations were found in the roots and particles of the incubations with and without macrophytes that retained in average 68 and 34?% of added Hg, respectively. On the other hand, the lowest concentrations were found in air for both incubations, with higher volatilization (up to 2.5?% of added Hg) in the absence of macrophytes. The lower Hg values in leafs and petioles suggest this plant has mechanisms of Hg retention in the roots. Results suggest this macrophyte promotes changes in the Hg cycle since it attracts most Hg present in water and particulate to its roots and settled particles underneath and also reduces Hg volatilization.     

Spatiotemporal heterogeneity of actual and potential respiration in two contrasting floodplains

Floodplains are vital components of river ecosystems and play an important role in carbon cycling and storage at catchment and global scales. For efficient river management and conservation, it is critical to understand the functional role of spatiotemporally complex and dynamic habitat mosaics of river floodplains. Unfortunately, the fundamental understanding of mineralization and carbon flux patterns across complex floodplains is still fragmentary. In this study, respiratory potential (i.e., electron transport system activity [ETSA]) was quantified seasonally across different aquatic and terrestrial habitats (wetted channels, gravel bars, islands, riparian forests, and grasslands) of 2 Alpine floodplains differing in climate, altitude, discharge, flow alteration intensity, and land use (So?a [natural flow regime, 12% grassland area] and Urbach [mean annual discharge reduction by 30% due to water abstraction, 69% grassland area]). In situ respiration (R) was measured, and ETSA–R ratios were calculated to examine differences in exploitation intensity of the overall respiratory capacity among floodplain habitats and seasons. ETSA and R provided potential and actual estimates, respectively, of organic matter mineralization in the different floodplain habitats. Hierarchical linear regression across habitat types showed that organic matter, grain sizes <0.063 mm, and water content were the most important predictors of ETSA in both floodplains, and grain sizes 2–0.063 and >8 mm were also highly important for the So?a floodplain. The combination of ETSA and R measurements conducted in contrasting floodplains increased our understanding of the relationships between floodplain habitat heterogeneity, organic matter mineralization and human impacts, that is, structural–functional linkages in floodplains. These data are integral towards predicting changes in floodplain function in response to environmental alterations from increasing human pressures and environmental change.     

Nebular emission-line profiles of Type Ib/c supernovae – probing the ejecta asphericity

In order to assess qualitatively the ejecta geometry of stripped-envelope core-collapse supernovae (SNe), we investigate 98 late-time spectra of 39 objects, many of them previously unpublished. We perform a Gauss-fitting of the [O  i ]  λλ6300, 6364  feature in all spectra, with the position, full width at half maximum and intensity of the  λ6300  Gaussian as free parameters, and the  λ6364  Gaussian added appropriately to account for the doublet nature of the [O  i ] feature. On the basis of the best-fitting parameters, the objects are organized into morphological classes, and we conclude that at least half of all Type Ib/c SNe must be aspherical. Bipolar jet models do not seem to be universally applicable, as we find too few symmetric double-peaked [O  i ] profiles. In some objects, the [O  i ] line exhibits a variety of shifted secondary peaks or shoulders, interpreted as blobs of matter ejected at high velocity and possibly accompanied by neutron-star kicks to assure momentum conservation. At phases earlier than ∼200 d, a systematic blueshift of the [O  i ]  λλ6300, 6364  line centroids can be discerned. Residual opacity provides the most convincing explanation of this phenomenon, photons emitted on the rear side of the SN being scattered or absorbed on their way through the ejecta. Once modified to account for the doublet nature of the oxygen feature, the profile of Mg  i ]  λ4571  at sufficiently late phases generally resembles that of [O  i ]  λλ6300, 6364  , suggesting negligible contamination from other lines and confirming that O and Mg are similarly distributed within the ejecta.     

Intra- and inter-specific variability in total and methylmercury bioaccumulation by eight marine fish species from the Azores

We relate fish biological and ecological characteristics to total and organic mercury concentrations to determine whether accumulation is influenced by trophic level, Hg concentration in the diet, and vertical distribution. Levels of total mercury and methylmercury were determined in the muscle tissue of eight species of fish: Pagellus acarne, Trachurus picturatus, Phycis phycis, P. blennoides, Polyprion americanus, Conger conger, Lepidopus caudatus and Mora moro, caught in the Azores. All such fishes are commercially valuable and were selected to include species from a wide range of vertical distributions from epipelagic (<200 m) to mesopelagic (>300 m) environments. Methylmercury was the major form accumulated in all species, comprising an average of 88.1% of total mercury. Concentrations of mercury (total and methylmercury) increased with age, length and weight. Based on data from other studies, mercury concentrations in fish diet were estimated. Mercury levels in food ranged from 0.08 to 0.32 ppm, dry weight. Hg concentrations in the food and in muscle tissue from different species were positively correlated. Total Hg levels in the muscles were approximately nine times those estimated in food. Total mercury concentrations in muscle were positively correlated with both trophic level and median depth. Such enhanced mercury bioaccumulation in relation to depth appears to be determined primarily by concentrations in food and ultimately by water chemistry, which controls mercury speciation and uptake at the base of the food chain.     

Biomarkers in croakers Micropogonias furnieri (Teleostei: Sciaenidae) from polluted and non-polluted areas from the Patos Lagoon estuary (Southern Brazil): evidences of genotoxic and immunological effects

Biomarkers of exposure and effect of pollutants were analyzed in croakers Micropogonias furnieri (Teleostei: Sciaenidae) captured in winter and summer in a polluted and in a non-polluted site at the Patos Lagoon estuary (Southern Brazil). Catalase and glutathione S-transferase activities (exposure biomarkers) and lipid peroxidation (effect biomarker) were analyzed in liver samples. Other two effect biomarkers were also studied: blood cells DNA damage (through comet assay and micronucleus test) and respiratory burst measurements. In a broad view, results point to an important seasonal variation of the biochemical biomarkers analyzed. However, data obtained clearly indicate that croakers collected in winter at the polluted site were subjected to a level of clastogenic agents sufficient to generate irreversible genetic damages (mutations) and impair the fish immune system.     

The Dramas of the Marine Extractive Reserve Managers in Brazil: Navigating through Multiple Institutions

Abstract

In this paper, we describe and analyze the co-management institutional framework at 21 Brazilian Marine Extractive Reserves (MERs) and present the dramas of its implementation from the local manager’s perspective. We categorized the governance instruments of MERs into (i) instruments for land/sea tenure and beneficiaries’ recognition, (ii) territorial use planning, (iii) institutional arenas for discussion and deliberation, as well as (iv) public policies. Although the legal arrangements of these protected areas address fundamental dimensions of governance, we present the challenges of its implementation based on the voice of local managers. The managers are the bridge between the central government and communities, dealing with the implementation of the institutional framework in a reality of multi-level and multi-scale drama: from local to national dilemmas, from organizational to structural ones. We explore these dramas and highlight the institutional dilemmas based on the paradoxes between legalism and social emancipation.     

Correction to: Spatiotemporal variability of vegetation due to drought dynamics (2012–2017): a case study of the Upper Paraíba River basin,Brazil

Natural Hazards - This correction stands to support the updating of the original article for changing the name Glauciene Justino Ferreira to Glauciene Justino Ferreira da Silva. The author group...     

Quantification of vertical water fluxes in the vadose zone using particle‐size distribution and pedology‐based approaches to model soil heterogeneities

One‐dimensional flow simulations were conducted at four locations of the shallow alluvial aquifer of the upper Rhine River (at the Erstein polder) to quantify the time‐dependent moisture distribution, the water flux and the water volume infiltrated in the unsaturated zone as a function of soil heterogeneities during a five‐day‐long flooding event. Three methods of estimating the hydraulic parameters of soil in the vadose zone were tested. They are based on the following: (1) experimental data, (2) soil particle‐size distribution and (3) pedology information on soils. Water fluxes calculated from modelling approaches 2 and 3 were compared with those of the experiment‐based values and the effect of these differences on the arrival time and velocity of water at the water table were analysed. Major differences in water fluxes were found among the methods of estimating the hydrodynamic parameters. At the Terrace location, the groundwater recharge predicted using soil data from methods 1 and 2 are approximately 4500 and 2400 mm, respectively. Flow simulations using soil data and the experiment‐based method show the highest velocities of infiltrating water at the soil surface and largest volume of groundwater infiltration but result in the lowest centres of the moisture content mass. The results obtained using soil data based on the pedological method are similar to those calculated using soil parameters based on the particle‐size distribution of extracted soil samples. Water pressure profiles calculated on Terrace and Channel location, 3 and 7 days after the inundation event agreed reasonably well with those observed when using hydrodynamic parameters from the experiment‐based method. However, the flow model using the pedology‐based parameters largely underestimates the time needed to achieve hydrostatic conditions of the soil water profile once water flooding at the soil surface stops. This can be mainly attributed to the low values of estimated van Genuchten parameter α. Copyright © 2012 John Wiley & Sons, Ltd.     

Photon path-length distribution function (I)

The determination of the photon path-length distribution function (PLDF) for the case of linearly anisotropic (Rocard) scattering in a semi-infinite plane-parallel homogeneous atmosphere using the Piessens-Huysmans method is described in detail. It has been shown that in this case the PLDF may have a minimum at small path-lengths — a feature which is never encountered in isotropic scattering. The respective regions with minima in the (µ, )-plane have been sorted out. As a rule, the average path-length in the case of the forward/backward Rocard scattering is larger/smaller than that in the isotropic case. The precise average path-lengths for a number of parameters are shown in Table I.