<Superscript>10</Superscript>Be surface exposure dating of the last deglaciation in the Aare Valley,Switzerland

The combined Rhone and Aare Glaciers presumably reached their last glacial maximum (LGM) extent on the Swiss Plateau prior to 24 ka. Two well-preserved, less extensive moraine stades, the Gurten and Bern Stade, document the last deglaciation of the Aare Valley, yet age constraints are very scarce. In order to establish a more robust chronology for the glacial/deglacial history of the Aare Valley, we applied ¹⁰Be surface exposure dating on eleven boulders from the Gurten and Bern Stade. Several exposure ages are of Holocene age and likely document post-depositional processes, including boulder toppling and quarrying. The remaining exposure ages, however yield oldest ages of 20.7 ± 2.2 ka for the Gurten Stade and 19.0 ± 2.0 ka for the Bern Stade. Our results are in good agreement with published chronologies from other sites in the Alps.     

Seasonal controls on sediment transport and deposition in Lake Ohau,South Island,New Zealand: Implications for a high‐resolution Holocene palaeoclimate reconstruction

Laminated sediments in Lake Ohau, Mackenzie Basin, New Zealand, offer a potential high‐resolution climate record for the past 17 kyr. Such records are particularly important due to the relative paucity of detailed palaeoclimate data from the Southern Hemisphere mid‐latitudes. This paper presents outcomes of a study of the sedimentation processes of this temperate lake setting. Hydrometeorological, limnological and sedimentological data were collected over a 14 month period between 2011 and 2013. These data indicate that seasonality in the hydrometeorological system in combination with internal lake dynamics drives a distinct seasonal pattern of sediment dispersal and deposition on a basin‐wide scale. Sedimentary layers that accumulate proximal to the lake inflow at the northern end of the lake form in response to discrete inflow events throughout the year and display an event stratigraphy. In contrast, seasonal change in the lake system controls accumulation of light (winter) and dark (summer) laminations at the distal end of the lake, resulting in the preservation of varves. This study documents the key processes influencing sediment deposition throughout Lake Ohau and provides fundamental data for generating a high‐resolution palaeoclimate record from this temperate lake.     

The volumes of He+ and H+ inHII regions: The Orion Nebula

We obtain ratios of volumes of He⁺ to H⁺ zones forHII regions ionized by associations following a Salpeter IMF using Kurucz's (1979) model atmospheres. It is concluded that the temperature of hottest star in the association is the dominant factor determining the He ionization structure. The selective dust absorption seems to play a secondary role as well as density gradients and spatial distribution of ionizing stars. The results are compared with observations, in particular with the Orion Nebula. A density gradient is found in M42. Filling factors in the range ??5–16 for M43 are obtained.     

Application of Correspondence Analysis in the Assessment of Groundwater Chemistry

Correspondence Analysis (CA) was used to determine the sources and processes that may explain the variation observed in datasets of groundwater analyses. The following method was adopted: (1) based on the observation of sympathies and antipathies between loadings signs, correspondence factors were represented by parameters with some pertinent geochemical meaning: (2) the relation between factors and parameters then was checked by Multiple Linear Regression (MLR) where factors acted as independent variables and parameters as dependent variables. Sample scores of the selected parameters gave the ability to separate polluted from nonpolluted waters, identify areas where pollution is dominated by agriculture and areas where contamination is controlled by domestic effluents, and describe weathering and agricultural activities in the sampled area. The practical example presented here anticipates the impact of agriculture and urban pollution on the chemistry of 160 water samples collected in a granitoid area at central Portugal (Fundão).     

Widespread Occurrence of Ephemeral Funnel Hoarfrost and Related Air Ventilation in Coarse‐Grained Sediments of a Relict Rock Glacier in the Seckauer Tauern Range,Austria

This paper examines the occurrence of ephemeral hoarfrost crystals at funnel openings (funnel hoarfrost) detected between large blocks at the surface of the presumably relict Schöneben Rock Glacier. Field mapping on 25 November 2011 identified 51 individual funnel openings with notable hoarfrost crystals distributed over the entire rock glacier. Hoarfrost was no longer detectable a few days after the initial mapping campaign. At least in the period 20–25 November 2011 temperature conditions at the rock glacier surface were favourable for hoarfrost formation and preservation as indicated by different types of measurements. A period of 24–48 h of hoarfrost‐suitable weather conditions would have been sufficient to form the observed hoarfrost if crystal growth rates of 2–4 mm h^?1 are assumed. The void systems with funnel hoarfrost seem to be rather localised and limited in horizontal (10s of metres) and vertical (some metres) extent. Presumably the observed funnel hoarfrost was caused by the so‐called chimney effect, although no larger reversible air circulation systems with warm air exhalation were identified. Continuous ground temperature data from several sites at the rock glacier surface (period November 2011–December 2012) showed that hoarfrost sites are cooler and thermally buffered compared with non‐hoarfrost sites at similar elevations. This seems to be related to the decoupling of the air above the rock glacier and the pore air during periods of atmospheric warming. Only the combination of specific micro‐climatic (temperature/humidity), geometric (open void systems) and sedimentological (grain size/sediment structure) conditions allow the formation of the ephemeral funnel hoarfrost at this rock glacier.     

Natural speciation of Mn, Ni, and Zn at the micrometer scale in a clayey paddy soil using X-ray fluorescence, absorption, and diffraction

The natural speciation of Mn (0.19 g/kg), Ni (46 mg/kg), and Zn (42 mg/kg) in the argillic horizon (120 cm depth, pH = 5.6) of an Ultisol from a paddy soil in northern Taiwan was investigated by advanced X-ray synchrotron techniques. Microchemical associations were imaged by synchrotron-based X-ray microfluorescence, host minerals were identified by standard and micrometer-resolved X-ray diffraction, and the local coordination environment of Mn, Ni, and Zn was probed using extended X-ray absorption fine structure (EXAFS) spectroscopy on a powdered sample and a soil thin section, and polarized EXAFS spectroscopy on a highly textured self-supporting clay film from the <2 μm fraction of the soil. Manganese was concentrated in Fe-Mn soft mottles (44.4 g/kg) as turbostratic hexagonal birnessite and lithiophorite having Mn³⁺/Mn⁴⁺ atomic ratios of ∼20% and 50%, respectively. Quantitative analysis of high-order scattering paths of the EXAFS spectrum for natural and synthetic lithiophorite revealed that Mn³⁺ and Mn⁴⁺ are ordered in the layer. A structural model is proposed, in which Mn⁴⁺ and Mn³⁺ are ordered similarly to Al and Li in the layer, with Mn³⁺ cations being surrounded by six Mn⁴⁺, and Mn⁴⁺ cations by three Mn³⁺ and three Mn⁴⁺. Similar cation ordering in the manganese and aluminum layers likely provides a more homogeneous local balance of the excess and deficit of charges in each layer and increases the stability of lithiophorite. Ni (r = 0.70 Å) substitutes for Mn (r(Mn⁴⁺) = 0.54 Å, r(Mn³⁺) = 0.65 Å) in the manganese layer in the natural lithiophorite. In contrast, Zn (r = 0.74 Å) fills vacant sites in the gibbsitic layer of natural lithiophorite, in a similar manner as lithium (r = 0.74 Å) in synthetic lithiophorite. The partitioning of Ni and Zn between the two layers is a result of the general preference of Ni, whose size is intermediate between those of Mn³⁺ and Li⁺, for slightly smaller sites. In contrast with nickel, which is detected only where there is lithiophorite, the Zn-lithiophorite association found in Fe-Mn mottles is not representative of the bulk soil. The combined use of X-ray diffraction, and powder and polarized EXAFS spectroscopy revealed that Zn is predominantly bound to hydroxy-Al interlayers sandwiched between 2:1 vermiculite layers in the fine soil matrix. The incorporation of Zn in the gibbsitic layer of both lithiophorite and vermiculite helps increase the stability of these minerals by providing positive charge to balance the negative charge from the 2:1 phyllosilicate layer and the layer of lithiophorite. This binding environment for zinc is probably the main mechanism by which zinc is sequestered in acidic to near-neutral aluminum-rich clayey soils.     

A Bayesian method for the estimation of return values of wave heights

Bayesian statistics offer a novel means of estimating return values of wave heights and hence of establishing design criteria for offshore structures. The Bayesian method has significant advantages over the classical method since it enables all types of uncertainty (physical, parameter, distribution) associated with the design wave prediction to be handled in a consistent manner in the same analysis.The basic principles of the Bayesian method for drawing inferences are outlined step-by-step. It is shown how Bayesian estimators of return values for wave heights are established by taking an expectation over all parameters and contending distributions. When the Bayesian procedure is applied to large data sets, such as wave data sets, computational difficulties could be encountered, making a “remedial” procedure necessary. However, the Bayesian procedure has been used successfully with wave data sets from the northern North Sea. Furthermore, the associated remedial procedure is such that the program can be made suitable for many existing computers, e.g. desk computers.     

The massive winds of luminous peculiar B-type stars

The wind characteristics of a small group of luminous B-type stars are investigated. They present a momentum problem, similar to but not as obvious as that seen in Wolf-Rayet stars. However, there is no violation of a fundamental limit since the energy to be extracted from the radiation field is small. Moreover, their mass loss rates can be roughly reproduced in the context of a radiation-driven wind provided we make use of larger values for the radiative parameterk.     

High-resolution regional ocean dynamics simulation in the southwestern tropical Atlantic

The southwestern tropical Atlantic (05°S–25°S/20°W–47°W), where part of the South Equatorial Current (SEC) enters at its eastern border, is of particular interest as it is fed by many western boundary currents along the eastern Brazilian continental shelf. However, the long-term variability of the dynamics in this region, which are also important as they contribute to the climate over northeastern Brazil, is largely unknown. We use the Regional Ocean Model System (ROMS) here for the first time in this area to simulate the ocean circulation with an isotropic horizontal grid resolution of 1/12° and 40 terrain-following layers. As a primary evaluation of the ROMS configuration, we explore surface and vertical thermal structures, the surface mixed layer, and mass transports within the upper levels. Interannual variability results are compared with the first two-year series of observed thermal profiles derived from the three PIRATA-SWE moorings. The simulated thermal structure in the upper ocean layers agrees well with in-situ data. ROMS simulations point out a broad and relatively weak SEC flow composed of a sequence of more or less defined near-surface cores. The westward SEC transport for the upper 400 m along the PIRATA-SWE section, calculated from the ROMS simulation for 2005–2007, shows an average volume transport of 14.9 Sv, with a maximum observed in JFM (15.7 Sv), and a minimum during MJJ (13.8 Sv). ROMS results indicate that the 2005–2007 seasonal near-surface westward SEC transport is modulated by the zonal wind variability. Three zonal sections extending from the American continent to the PIRATA buoy sites confirm that stronger northward NBUC transport and decreasing BC transport were achieved during May 2006 and May 2007, i.e. at the time the sSEC bifurcation reaches its southernmost position. On the other hand, the maximum southward BC flow was verified during January 2006, January 2007 and March 2007, with a minimum northward NBUC flow in December 2005 and October/December 2006, corresponding to the period when the sSEC bifurcation reaches its lowest latitude (OND). Sea Surface Height (SSH) and the surface Eddy Kinetic Energy (EKE) derived from simulations and AVISO Rio05 product point out the highest surface meso-scale activity (EKE  50 cm² s⁻²) along the cSEC and NBUC/BC patches. Preliminary results provide additional ingredients in the complexity of the SEC divergence region and encourage us to conduct a more detailed exploration of the dynamics of this region using the ROMS. This also shows the need to continue, extend, and vertically upgrade the observational PIRATA-SWE array system, especially with more levels of salinity measurements and the installation of current measurements.     

Evolution of X-ray cavities

A wide range of recent observations have shown that active galactic nuclei (AGN) driven cavities may provide the energy source that balances the cooling observed in the centres of 'cool-core' galaxy clusters. One tool for better understanding the physics of these cavities is their observed morphological evolution, which is dependent on such poorly understood properties as the turbulent density field and the impact of magnetic fields. Here, we combine numerical simulations that include subgrid turbulence and software that produces synthetic X-ray observations to examine the evolution of X-ray cavities in the absence of magnetic fields. Our results reveal an anisotropic size evolution of the cavities that is dramatically different from simplified, analytical predictions. These differences highlight some of the key issues that must be accurately quantified when studying AGN-driven cavities, and help to explain why the inferred pV energy in these regions appears to be correlated with their distance from the cluster centre. Interpreting that X-ray observations will require detailed modelling of effects, including mass entrainment, distortion by drag forces and projection. Current limitations do not allow a discrimination between purely hydrodynamic and magnetically dominated models for X-ray cavities.