Coexisting tectonic settings: the example of the southern Tyrrhenian Sea

We performed geodetic strain rate analyses in southern Italy, using new GPS velocities. Two-dimensional strain and rotation rate fields were estimated and results show that most of the shortening is distributed in the northern Sicily offshore. Extension becomes more evident and comparable with shortening on the eastern side of the same margin, and greater in the eastern Sicily offshore. Principal shortening and extension rate axes are consistent with long-term geological features: seismic reflection profiles show both active compressive and extensional faults affecting Pleistocene strata. We show evidence for contemporaneous extension and transtension in the Cefalù Basin. Combining geodetic data and geological features point to the coexistence of independent geodynamic processes, i.e., the active E–W backarc spreading in the hangingwall of the Apennines subduction zone and shortening along the southern margin of the Tyrrhenian backarc basin operated by the NNW-motion of Africa relative to Eurasia.     

Design Aspects of Grazing Angle Multilayer Mirrors for Soft γ-Rays

If sensitive enough, future missions for nuclear astrophysics will be a great help in understanding supernovae explosions. In contrast to coded-mask instruments, both crystal diffraction lenses and grazing angle mirrors offer a possibility to construct a sensitive instrument to detect γ-ray lines in supernovae. We report on possible implementations of grazing angle mirrors and simulations carried out to determine their performance.     

Correlation between damage distribution and ambient noise H/V spectral ratio: the SESAME project results

In the framework of the SESAME project one of the tasks was the compilation of all available ambient noise measurements within urban environments affected by historical or/and recent strong earthquakes in Europe. The aim of such a task was to give an answer to the question; “How does horizontal-to-vertical ambient noise spectral ratio compare with damage in modern cities?”. For this purpose five European urban areas, namely, Angra do Heroismo (Portugal), Fabriano and Palermo (Italy), Thessaloniki and Kalamata (Greece) were selected for which spatial damage information was available either in terms of modified Mercalli intensity or in EMS98 damage grades. The geological setting of the examined sites as well as the causative earthquakes are satisfactorily known. Ambient noise recordings compiled for all examined sites have been homogeneously processed by a technique developed and agreed upon SESAME project. Using a standard multivariate statistical analysis, namely, factor analysis and canonical correlation, the horizontal-to-vertical ambient noise spectral ratio (HVNSR) is correlated with damage pattern observed within examined urban areas. Results show that, in some cases (Thessaloniki, Palermo), the HVNSR seems to be able to differentiate between areas previously shown to be associated with higher damage. In other cases however (Angra do Heroismo, Fabriano, Kalamata), the correlation is not statistically significant indicating thus the complex character of the parameters involved, implying that currently there is no a straightforward way that a value of HVNSR can correctly predict the extent to which a given region will be associated with increased damage.     

Volatile-rich magma injection into the feeding system during the 2001 eruption of Mt. Etna (Italy): its role on explosive activity and change in rheology of lavas

The explosive behavior and the rheology of lavas in basaltic volcanoes, usually driven by differentiation, can also be significantly affected by the kinetics of magma degassing in the upper portion of the feeding system. The complex eruption of 2001 at Mt. Etna, Italy, was marked by two crucial phenomena that occurred at the Laghetto vent on the southern flank of the volcano: 1) intense explosive activity and 2) at the end of the eruption, emission of a lava flow with higher viscosity than flows previously emitted from the same vent. Here, we investigate the hypothesis that these events were driven by the injection of volatile-rich magma into the feeding system. The input and mixing of this magma into a reservoir containing more evolved magma had the twofold effect of increasing 1) the overall concentration of volatiles and 2) their exsolution with consequent efficient vesiculation and degassing. This led to an explosive stage of the eruption, which produced a ~75-m-high cinder cone. Efficient volatile loss and the consequent increase of the liquidus temperature brought about the nucleation of Fe-oxides and other anhydrous crystalline phases, which significantly increased the magma viscosity in the upper part of the conduit, leading to the emission of a high viscosity lava flow that ended the eruption. The 2001 eruption has offered the opportunity to investigate the important role that input of volatile-rich magma may exert in controlling not only the geochemical features of erupted lavas but also the eruption dynamics. These results present a new idea for interpreting similar eruptions in other basaltic volcanoes and explaining eruptions with uncommonly high explosivity when only basic magmas are involved.     

Transient processes in Stromboli’s shallow basaltic system inferred from dolerite and magmatic breccia blocks erupted during the 5 April 2003 paroxysm

We describe the mineralogy, geochemistry, and mesomicrostructure of fresh subvolcanic blocks erupted during the 5 April 2003 paroxysm of Stromboli (Aeolian Islands, Italy). These blocks represent ∼50 vol.% of the total erupted ejecta and consist of fine- to medium-grained basaltic lithotypes ranging from relatively homogeneous dolerites to strongly or poorly welded magmatic breccias. The breccia components are represented by angular fragments of dolerites entrapped in a matrix of vesiculated (lava-like to scoriae) crystal-rich (CR) basalt. All of the studied blocks are cognates with the CR basalt of the normal Strombolian activity or lavas and they are often coated by a few-centimeter thick layer of crystal-poor (CP) basaltic pumice erupted during the paroxysm. We suggest that they result from the rapid increase of pressure and related subvolcanic rock failure that occurred shortly before the 5 April 2003 explosion, when the uppermost portion of the edifice inflated and suffered brecciation as the result of the sudden rise of the gas-rich CP basalt that triggered the eruption. Dolerites and magmatic matrix of the breccias show major and trace element compositions that match those of the CR basalts erupted during normal Strombolian activity and effusive events at Stromboli volcano. Dolerites consist of (a) phenocrysts normally found in the CR basalts and (b) late-stage magmatic minerals such as sanidine, An_60-28 plagioclase, Fe–Mn-rich olivines (Fo_68-48), phlogopite, apatite, and opaque mineral pairs (magnetite and ilmenite), most of which are never found both in lava flows and scoriae erupted during the persistent explosive activity that characterizes typical Strombolian behavior. Subvolcanic crystallization of the Stromboli CR magma, leading to slowly cooled equivalents of basalts, could result from transient drainage of the magma from the summit craters to lower levels. Fingering and engulfing of the material that collapsed from the summit crater floor into the shallow basaltic system during the late evening of 28 December 2002 coupled with the short break in the summit persistent explosions between December 2002 and March 2003 permitted the CR magma pockets to solidify as dolerites, which were confined to the uppermost portion of the system and thus not involved in the ongoing flank effusive activity. Crystal size distribution of the basaltic blocks and crystallization of the finer-grained (<0.1 mm) mafic minerals of the dolerites over a time interval of ∼100 days closely agrees with the above interpretation. Vesicle filling (miarolitic cavities) locally found in some dolerites, with minerals deposited as vapor-phase crystallization is a result of continuous gas percolation through the rocks of the uppermost portion of the volcanic system. Poorly welded magmatic breccias formed during syn-eruptive processes of 5 April 2003, when the paroxysm strongly shattered the shallow subvolcanic system and many dolerite fragments were entrapped in the CR magma. In contrast, the high degree of welding between the dolerite clasts and the CR basaltic matrix in the strongly welded magmatic breccias provides a snapshot of subvolcanic intrusions of the CR basalt into the dolerite when, after a 2-month break in activity, CR magmas started to rise again to the summit craters. Blocks similar to these subvolcanic ejecta of 5 April 2003 were also erupted during previous paroxysms (e.g., 1930) suggesting that changes in the usual Strombolian activity (e.g., short breaks in the persistent mild explosions and/or flank effusive activity) lead to transient crystallization of dolerites in the shallow plumbing system.     

Variability of the Fe K line relativistic component in a sample of Seyfert 1 galaxies

We present the analysis of X‐ray spectral variability made on a sample of 7 Seyfert 1 bright galaxies, using XMM‐Newton data. From the “XMM‐Newton Science Archive” we selected those bright Seyfert 1 showing one or more prominent flares in their 2–10 keV light curves. For each of them we extracted spectra in 3 different time intervals: before, during and after the flare. We fitted them with a simple power law and then shifted a narrow emission and absorption line template across the 2.5–10 keV data, in order to investigate the presence of line‐like features with a confidence level greater than 99%. Some highly significant features were detected in 3 out of 7 sources studied. In particular, the 3 sources, namely PG 1211+143, NGC 4051 and NGC 3783, showed the presence of a variable emission feature in the 4.5–5.8 keV band, characterized by an increase of its intensity after the flare peak. Because of the observed variability pattern, this feature seems to be ascribable to a reverbered redshifted relativistic component of the Fe K line. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

The response of braided planform configuration to flow variations,bed reworking and vegetation: the case of the Tagliamento River,Italy

Morphological features of braided rivers (bars, channels and pools) experience major changes in area, shape and spatial distribution as a response to (i) the pulsation of discharge during a flood and (ii) the bed evolution induced by floods. In this work, at‐a‐station relationships between water level and planform configuration were investigated on the Tagliamento River, a large gravel‐bed braided river in northeast Italy, over a 2‐year study period comprising three bankfull events and several small‐to‐medium floods. The analysis was performed on two 1‐km‐long reaches, characterized by different riparian vegetation cover. Ground‐based images with an hourly temporal resolution were acquired using software‐controlled, digital cameras. Bars, channels, pools and vegetated patches were manually digitized on more than 100 rectified images. Sequences of constant‐level images spanning the study period were used to quantify the impact of floods on the stability of at‐a‐station relationships and on the turnover rate of water bodies. The analysis shows that wetted area increased almost linearly with water level in both reaches. The average number of branches per cross‐section peaked at intermediate flow levels, increasing from 2 at low flow up to 6–7. The number of branches displayed the largest fluctuations over time, with significant changes produced also by moderate floods. Turnover rates were high in both reaches, with more than 30% of wetted areas at low flow converting into bare gravel in less than 2 months. Vegetation colonization was found to limit the mobility of the low flow channels over time by concentrating the flow in fewer, deeper anabranches. The number of channels per cross‐section was 30–40% less in the vegetated reach and the proportion of low flow water bodies in the same position after 12 months increased from 3% to 14%. Copyright © 2012 John Wiley & Sons, Ltd.     

Calibration of a chalcogenide glass membrane ion-selective electrode for the determination of free Fe in seawater: I. Measurements in UV photooxidised seawater

Calibration of a chalcogenide glass membrane, Fe(III)ISE [Fe_2.5(Ge₂₈Sb₁₂Se₆₀)_97.5], in buffered saline media has been undertaken in order to assess the suitability of this ISE for seawater analyses. The electrode slopes in saline citrate and salicylate buffers were 26.3 and 28.2 mV/decade, respectively, for Fe³⁺ concentrations ranging from 10⁻¹⁰ M to less than 10⁻²⁵ M Fe³⁺. The calibration lines in the citrate and salicylate buffers were essentially collinear with the response in unbuffered chloride-free standards containing >10⁻⁵ M Fe³⁺, demonstrating that the response of the FeISE is unaffected by chloride ions. A mechanism involving a combination of charge transfer and ion-exchange of Fe(III), at the electrode diffusion layer, can be used to explain the ≈30 mV/decade slope of the FeISE. The response of the FeISE in UV photooxidised seawater containing 8 nM total Fe was measured as the pH was changed from 8.27 to 3.51. The slope of the response was 24.2 mV/decade [Fe³⁺] calculated as a function of pH using Fe(III) hydrolysis constants for seawater. Moreover, the response was essentially collinear with that in citrate buffers and in unbuffered solutions containing >10⁻⁵ M Fe³⁺ and the slope for the combined data was 26.2 mV/decade. This study was restricted to organic-free seawater because the certainty in Fe(III)–ligand stability constants is insufficient to warrant the selection of an ideal calibration buffer system, and there is evidence that powerful chelating ligands (e.g., EDTA along with humic and fulvic acids) may alter the response of the Fe(III)ISE. The Fe dissolution rate of the FeISE in UV photooxidised seawater was found to be 1.6×10⁻² nmol Fe/min, as measured by cathodic stripping voltammetry (CSV). This would contaminate a 100-ml sample by 0.8–1.6 nM Fe over a typical measurement period of 5–10 min obtained using a stability criterion of 0.5 mV/min. Various methods are proposed for reducing the level of contamination in open ocean samples that contain sub-nanomolar concentrations of iron. The FeISE has the potential to detect free Fe³⁺ at concentrations typically found in natural seawater.