Bismuth‐melt trails trapped in cassiterite–quartz veins

Native bismuth in the form of metallic melt has been considered instrumental to the formation of some metallic ore deposits via a mechanism dubbed the “Liquid Bismuth Collector Model.” Here, we provide petrographical documentation of trail‐forming, μm‐sized blebs of native bismuth in cassiterite–quartz veins from the Santa Bárbara greisen Sn deposit in the Rondônia tin province of northern Brazil. These inclusions suggest the trapping of a Bi melt that took place during vein formation, in a mechanism similar to the entrapment of fluid inclusions.     

Monitoring large oil slick dynamics with moderate resolution multispectral satellite data

Accidental release of crude oil into the sea due to human activity causes water pollution and heavy damages to natural ecosystems killing birds, fish, mammals and other organisms. A number of monitoring systems are used for tracking the spills and their effects on the marine environment, as well as for collecting data for feeding models. Among them, Earth observation technologies play a crucial role and moderate spatial resolution satellite systems are able to collect images with a very short revisit time or even daily. This paper describes the use of Moderate-Resolution Imaging Spectroradiometer data for monitoring large oil slicks with the fluorescence/emissivity index and object-based image analysis. Two case studies are presented: the Deepwater Horizon (2010) and the Campos Basin (2011) oil spill accidents. Results show that it is possible to track the dynamics of the slick both for massive and long-lasting accidents and for smaller and very quick accidents. The main advantages of the method proposed are a straightforward implementation, a fast and semi-automated data processing and the capability of integration of daytime and nighttime acquisitions, as well as its adaptability to different sensors.     

Quality control algorithms for rainfall measurements

One of the basic requirements for a scientific use of rain data from raingauges, ground and space radars is data quality control. Rain data could be used more intensively in many fields of activity (meteorology, hydrology, etc.), if the achievable data quality could be improved. This depends on the available data quality delivered by the measuring devices and the data quality enhancement procedures. To get an overview of the existing algorithms a literature review and literature pool have been produced. The diverse algorithms have been evaluated to meet VOLTAIRE objectives and sorted in different groups. To test the chosen algorithms an algorithm pool has been established, where the software is collected. A large part of this work presented here is implemented in the scope of the EU-project VOLTAIRE (Validation of multisensors precipitation fields and numerical modeling in Mediterranean test sites).     

Controls on event runoff coefficients in the eastern Italian Alps

Analyses of event runoff coefficients provide essential insight on catchment response, particularly if a range of catchments and a range of events are compared by a single indicator. In this study we examine the effect of climate, geology, land use, flood types and initial soil moisture conditions on the distribution functions of the event runoff coefficients for a set of 14 mountainous catchments located in the eastern Italian Alps, ranging in size from 7.3 to 608.4 km². Runoff coefficients were computed from hourly precipitation, runoff data and estimates of snowmelt. A total of 535 events were analysed over the period 1989–2004. We classified each basin using a “permeability index” which was inferred from a geologic map and ranged from “low” to “high permeability”. A continuous soil moisture accounting model was applied to each catchment to classify ‘wet’ and ‘dry’ initial soil moisture conditions. The results indicate that the spatial distribution of runoff coefficients is highly correlated with mean annual precipitation, with the mean runoff coefficient increasing with mean annual precipitation. Geology, through the ‘permeability index’, is another important control on runoff coefficients for catchments with mean annual precipitation less than 1200 mm. Land use, as indexed by the SCS curve number, influences runoff coefficient distribution to a lesser degree. An analysis of the runoff coefficients by flood type indicates that runoff coefficients increase with event snowmelt. Results show that there exists an intermediate region of subsurface water storage capacity, as indexed by a flow–duration curve-based index, which maximises the impact of initial wetness conditions on the runoff coefficient. This means that the difference between runoff coefficients characterised by wet and dry initial conditions is negligible both for basins with very large storage capacity and for basins with small storage capacity. For basins with intermediate storage capacities, the impact of the initial wetness conditions may be relatively large.     

Hydrodynamic and isotopic investigations for evaluating the mechanisms and amount of groundwater seepage through a rockslide dam

This study addresses the influence of landslide dams on surface water drainage and groundwater flow. In the study area of Scanno Lake and Sagittario River (Central Italy), a limestone rockslide‐avalanche formed a lake, which has an outlet that is occasionally active, showing infiltration into the rockslide dam. Several springs are present at the lake's base and are partly fed by seepage through the rockslide debris. Piezometric surveys, discharge measurements, pumping tests and chemical analyses are tools used to build a conceptual model of the groundwater flow and to evaluate the flow through the rockslide debris. Seasonal water isotopic signatures validate the assumed model, showing a mixing of infiltration recharge and groundwater seepage throughout the rockslide debris. Various recharge areas have been found for springs, pointing out those directly fed by the rockslide debris aquifer. Hypotheses about seasonal groundwater mixing between the regional carbonate aquifer and the rockslide debris aquifer are supported by isotope results. Seasonal changes in groundwater table level due to recharge and surface losses from seasonal outlet have been correlated with isotopic groundwater composition from the rockslide debris aquifer and the downstream springs; this relationship highlights the role of the rockslide dam body on the hydrodynamics of the studied area. Relationships between surface waters and groundwater in the area have been completely understood on the basis of water isotopic fingerprinting, finally obtaining a complete evaluation of groundwater renewable resources and its regimen. Copyright © 2010 John Wiley & Sons, Ltd.     

An integrated procedure to evaluate hydrological models

The growing concern for health‐related problems deriving from pollutants leaching is driving national and international administrations to support the development of tools for evaluating the effects of alternate management scenarios and identifying vulnerable areas. Cropping systems models are powerful tools for evaluating leachates under different environmental, social, and management conditions. As percolating water is the transport vehicle for pollutants transport in soil, a reliable evaluation of water balance models is a fundamental prerequisite for investigating pesticides and nitrate fate. As specific approaches for the evaluation of multi‐layer evolution of state variables are missing, we propose a fuzzy‐based, integrated indicator (I_SWC: 0, best; 1, worst) for a comprehensive evaluation of soil water content (SWC) simulations. We aggregated error metrics with others quantifying the homogeneity of errors across different soil layers, the capability of models to reproduce complex dynamics function of both time and soil depth, and model complexity. We tested I_SWC on a sample dataset where the models CropSyst and CERES‐Wheat were used to simulate SWC for winter wheat systems. I_SWC revealed that, in the explored conditions, the global assessment of the two models' performances allowed identification of CropSyst as the best (average I_SWC = 0·441, with a value of 0·537 obtained by CERES‐Wheat), although each model prevailed for some of the metrics. CropSyst presented the highest accuracy (average agreement module = 0·400), whereas CERES‐Wheat's accuracy was slightly worse, although achieved with a simplified modelling approach (average Akaike Information Criterion = − 230·44), thereby favouring large‐area applicability. The non‐univocal scores achieved by the models for the different metrics support the use of multi‐metric evaluation approaches for quantifying the different aspects of water balance model performances. Copyright © 2010 John Wiley & Sons, Ltd.     

Embedding reach-scale fluvial dynamics within the CAESAR cellular automaton landscape evolution model

We introduce a new computational model designed to simulate and investigate reach-scale alluvial dynamics within a landscape evolution model. The model is based on the cellular automaton concept, whereby the continued iteration of a series of local process ‘rules’ governs the behaviour of the entire system. The model is a modified version of the CAESAR landscape evolution model, which applies a suite of physically based rules to simulate the entrainment, transport and deposition of sediments. The CAESAR model has been altered to improve the representation of hydraulic and geomorphic processes in an alluvial environment. In-channel and overbank flow, sediment entrainment and deposition, suspended load and bed load transport, lateral erosion and bank failure have all been represented as local cellular automaton rules. Although these rules are relatively simple and straightforward, their combined and repeatedly iterated effect is such that complex, non-linear geomorphological response can be simulated within the model. Examples of such larger-scale, emergent responses include channel incision and aggradation, terrace formation, channel migration and river meandering, formation of meander cutoffs, and transitions between braided and single-thread channel patterns. In the current study, the model is illustrated on a reach of the River Teifi, near Lampeter, Wales, UK.     

Plio-Quaternary volcanotectonic activity in the northern sector of the Main Ethiopian Rift: relationships with oblique rifting

Deformation and magmatism within the 90 km wide northern Ethiopian Rift system is concentrated along a narrow zone - the Wonji Fault Belt. Two key areas (the Nazret-Dera and Asela-Ziway areas), located along the eastern margin of the north-northeast to northeast trending Main Ethiopian Rift, have been investigated in order to reconstruct the recent tectonomagmatic evolution of the northern branch of the Main Ethiopian Rift. In these areas, Early Pleistocene volcanic products (Wonji Group) overlie Pliocene volcanic rocks (Eastern Margin Unit). Detailed stratigraphical reconstructions have revealed the presence of several tectonomagmatic units which can be correlated between the two study areas. The stratigraphical and petrological study of these units outlined (1) the bimodal composition (basalts-pantellerites) of the oldest and youngest units and the unimodal character (pantellerites) of the products erupted during the intervening period; (2) the mainly fissural origin of the ignimbrites and oldest basalts; and (3) a mafic/felsic volumetric ratio of 1:5.The geological data suggest that, around the Pliocene-Quaternary boundary, a change in the stress field occurred in this Main Ethiopian Rift sector, passing from a direction of extension roughly orthogonal to the rift shoulders, to oblique rifting related to an east-west trending extension. In this framework the change in the style of volcanism observed in the Nazret-Dera and Asela-Ziway areas can be related to the change of the stress field. A new geodynamic model is presented for the Late Pliocene to Recent evolution of this sector of the Main Ethiopian Rift. According to this model, a large volume of rhyolitic products was erupted during an oblique rifting phase, following a previous period of pure extension. The change in the tectonic regime favoured partial melting of the underplated basalts as a decrease in the pressure and an elevation of isotherms occurred.