Uptake and Accumulation of Arsenic in Different Organs of Carrot Irrigated with As‐Rich Water

Irrigation with arsenic (As)‐rich water in agricultural soil may increase high levels of As in crops and cause food chain contamination. In this study, a greenhouse experiment was established using Spanish agricultural soil (Valladolid and Segovia provinces), that are extensively cultivated for carrot plant, to investigate the process of As uptake, bioaccumulation, and translocation of As from root to shoot and leaves in carrot plant. Arsenic concentrations in different organs of carrot plant, rhizosphere soil, and soil solutions were determined by hydride generation atomic absorption spectrometry (AAS). High concentrations of As in irrigation water, and the alkaline and sandy character of this soil enhanced As uptake in carrot plants indicating the potential health risk from consumption of carrots cultivated in these areas. Bioaccumulation of As into the leaves and roots increased with increase of As concentration in irrigation water. Both roots and leaves demonstrated a higher accumulation rate of As at an As concentration of 41 than 131 µg L^?1 in the soil solution. The ratios of As_root/As_leaves showed no statistically significant differences for the different irrigation treatments, and had an average value of 0.36 indicating the high magnitude of As translocation from roots to leaves in carrot plants. The leaves of carrots had a higher affinity for As than roots did. The correlation between As uptake by leaves or roots of carrots and the soluble As in rhizosphere soil did not demonstrate a linear or a plateau curve, indicating a slow but continuous constant As absorption which could be prolonged over time with high potential environmental risks.     

Testing Stokes-Helmert geoid model computation on a synthetic gravity field: experiences and shortcomings

We report on testing the UNB (University of New Brunswick) software suite for accurate regional geoid model determination by use of Stokes-Helmert’s method against an Australian Synthetic Field (ASF) as “ground truth”. This testing has taken several years and has led to discoveries of several significant errors (larger than 5mm in the resulting geoid models) both in the UNB software as well as the ASF. It was our hope that, after correcting the errors in UNB software, we would be able to come up with some definite numbers as far as the achievable accuracy for a geoid model computed by the UNB software. Unfortunately, it turned out that the ASF contained errors, some of as yet unknown origin, that will have to be removed before that ultimate goal can be reached. Regardless, the testing has taught us some valuable lessons, which we describe in this paper. As matters stand now, it seems that given errorless gravity data on 1′ by 1′ grid, a digital elevation model of a reasonable accuracy and no topographical density variations, the Stokes-Helmert approach as realised in the UNB software suite is capable of delivering an accuracy of the geoid model of no constant bias, standard deviation of about 25 mm and a maximum range of about 200 mm. We note that the UNB software suite does not use any corrective measures, such as biases and tilts or surface fitting, so the resulting errors reflect only the errors in modelling the geoid.     

Realization of Einstein’s Machian Program: the Pioneers and fly-by anomalies Part I

In a previous paper (Berman, in Astrophys. Space Sci., 2011), we showed how to prove the two Pioneers Anomalies, and now we add the fly-bys, by means of a rotating Universe. We discuss Einstein’s Machian program, which we find as being fullfilled. Godlowski et al. (Los Alamos Archives, 2003) idea for a rotating General Relativistic Universe, led us to the adopted model. Updated evidence on rotation is cited (Godlowski, in Los Alamos Archives, 2011; Ni in Phys. Rev. Lett. 107(5):051103, 2011). We conclude that a rotating and expanding Universe may be the unique solution to the apparent divergences between Einstein and Mach. This is cosmologically important.     

Phase reddening on near-Earth asteroids: Implications for mineralogical analysis,space weathering and taxonomic classification

Phase reddening is an effect that produces an increase of the spectral slope and variations in the strength of the absorption bands as the phase angle increases. In order to understand its effect on spectroscopic observations of asteroids, we have analyzed the visible and near-infrared spectra (0.45–2.5 μm) of 12 near-Earth asteroids observed at different phase angles. All these asteroids are classified as either S-complex or Q-type asteroids. In addition, we have acquired laboratory spectra of three different types of ordinary chondrites at phase angles ranging from 13° to 120°. We have found that both, asteroid and meteorite spectra show an increase in band depths with increasing phase angle. In the case of the asteroids the Band I depth increases in the range of ～2° < g < 70° and the Band II depth increases in the range of ～2° < g < 55°. Using this information we have derived equations that can be used to correct the effect of phase reddening in the band depths. Of the three meteorite samples, the (olivine-rich) LL6 ordinary chondrite is the most affected by phase reddening. The studied ordinary chondrites have their maximum spectral contrast of Band I depths at a phase angle of ～60°, followed by a decrease between 60° and 120° phase angle. The Band II depths of these samples have their maximum spectral contrast at phase angles of 30–60° which then gradually decreases to 120° phase angle. The spectral slope of the ordinary chondrites spectra shows a significant increase with increasing phase angle for g > 30°. Variations in band centers and band area ratio (BAR) values were also found, however they seems to have no significant impact on the mineralogical analysis. Our study showed that the increase in spectral slope caused by phase reddening is comparable to certain degree of space weathering. In particular, an increase in phase angle in the range of 30–120° will produce a reddening of the reflectance spectra equivalent to exposure times of ～0.1 × 10⁶–1.3 × 10⁶ years at about 1 AU from the Sun. This increase in spectral slope due to phase reddening is also comparable to the effects caused by the addition of different fractions of SMFe. Furthermore, we found that under some circumstances phase reddening could lead to an ambiguous taxonomic classification of asteroids.     

Surface moisture area during rainfall–run‐off events to understand the hydrological dynamics of a basin in a plain region

The understanding of the hydrology of plain basins may be improved by the combined analysis of rainfall–run‐off records and remote sensed surface moisture data. Our work evaluates the surface moisture area (SMA) produced during rainfall–run‐off events in a plain watershed of the Argentine Pampas Region, and studies which hydrological variables are related to the generated SMA. The study area is located in the upper and middle basins of the Del Azul stream, characterized by the presence of small gently hilly areas surrounded by flat landscapes. Data from 9 rainfall–run‐off events were analysed. MODIS surface reflectance data were processed to calculate SMA subsequent to the peak discharge (post‐SMA), and previous to the rainfall events (prev‐SMA), to consider the antecedent wetness. Rainfall–run‐off data included total precipitation depth (P), maximum intensity of rainfall over 6 hr (I6max), surface run‐off registered between the beginning of the event and the day previous to the analysed MODIS scene (R), peak flow (Qp), and flood intensity (IF). In contrast with other works, post‐SMA showed a negative relationship with the R. Three groups of cases were identified: (a) Events of low I6max, high prev‐SMA, and low R were associated with slow and weakly channelized flow over plain areas, leading to saturated overland flow (SOF), with large SMA; (b) events of high I6max, low prev‐SMA, and medium to high R were rapidly transported along the gentle slopes of the basin, related to Hortonian overland flow (HOF) and low post‐SMA; and (c) events of medium to high I6max and prev‐SMA with medium R were related to heterogeneous input‐antecedent‐run‐off conditions combined: Local spatial conditions may have produced HOF or SOF, leading to an averaged response with medium SMA. The interactions between the geomorphology of the basin, the characteristics of the events, and the antecedent conditions may explain the obtained results. This analysis is relevant for the general knowledge of the hydrology of large plains, whose functioning studies are still in their early stages.     

Eutrophication and retention time affecting spatial heterogeneity in a tropical reservoir

Longitudinal heterogeneity in reservoirs is especially related to increase in sedimentation and water transparency along the river/dam axis. Consequently, primary production tends to reach higher values in intermediate regions where there is a balance between the availability of the main resources (light and nutrients) suitable for phytoplankton growth. Many factors such as reservoir morphometry, retention time, thermal stratification and geographical location can affect the boundaries between these regions. The tropical Funil Reservoir (Brazil), despite a low retention time, has experienced severe eutrophication in recent decades, with persistent cyanobacteria blooms. During the course of 1 year, samples were collected at four stations along the reservoir (fluvial, intermediate and lentic compartments) to evaluate if spatial heterogeneity could affect the occurrence and distribution of these blooms along the reservoir. Although the reservoir has a short annual retention time (mean 41.5 days), the typical zonation pattern was observed for the main abiotic variables and phytoplankton abundance. However, higher biomass occurred in the lentic compartment rather than in the intermediate zone. Despite the peculiar heterogeneity in total biomass, the phytoplankton composition and seasonal variability were very similar along the entire reservoir, with a few marked differences only in the fluvial zone. Phytoplankton total biomass in Funil Reservoir was high, even in periods of lower seasonal retention time (around 15 days), and was especially related to high input of nutrients. Moreover, retention time directly affects the spatial heterogeneity of phytoplankton biomass, since strong variability was only observed during the cold-dry season, corresponding to periods of longer retention time (around 80 days). While high availability of nutrients promoted high cyanobacterial biomass in the entire system, the few periods of heterogeneous spatiality seemed to be related to changes in retention time.     

Understanding Amazonian fluvial rias based on a Late Pleistocene–Holocene analog

Fluvial rias are elongated lakes at tributary mouths that can reach dozens of kilometers in length, constituting one of the most remarkable features in the Amazonian landscape. Thus far, definitive data which documents the genesis of fluvial rias have not been published. The main goal of this work was to integrate morphological, sedimentological and chronological information in order to characterize fluvial paleorias in the interfluve of the Purus and Madeira Rivers and discuss the most likely hypothesis for their genesis. These paleorias were first observed through remote sensing imagery as several elongated and interconnecting belts of open vegetation that are in sharp contact with the surrounding dense forest. The belts are branched and form a dendritic pattern similar to many modern drainage networks. The sedimentary record of these belts revealed the prevalence of sharp‐based sandstones and mudstones arranged into fining‐upward successions, which are compatible with deposition within channels. Active channel and abandoned channel deposits were recognized. These are topped by continuous mudstones related to rapid channel abandonment and formation of a low energy basin or ria environment. Radiocarbon dating of these deposits recorded only Late Pleistocene and Holocene ages ranging from 21 547–22 285 cal yr bp to 5928–6124 cal yr bp . This chronology for sediment deposition is not compatible with the hypothesis of Amazonian rias being formed by fluvial erosion during the Last Glaciation Maximum low sea level, with sediment accumulation during the subsequent Holocene transgression. Instead, the studied paleorias record previous tributaries of the Madeira River that became abandoned as the position of this river shifted southeastward and its interfluve tilted northward, inverting the drainage systems. Therefore, a neotectonic origin of some Amazonian paleorias seems most likely. This hypothesis should be considered in further investigations aiming at understanding the origin of numerous modern fluvial rias that typify the Amazonian landscape. Copyright © 2014 John Wiley & Sons, Ltd.