Isoprene and Its Oxidation Products Methyl Vinyl Ketone, Methacrolein, and Isoprene Related Peroxides Measured Online over the Tropical Rain Forest of Surinam in March 1998

Airborne measurements of volatile organic compounds (VOC) were performed overthe tropical rainforest in Surinam (0–12 km altitude,2°–7° N, 54°–58° W) using the proton transferreaction mass spectrometry (PTR-MS) technique, which allows online monitoringof compounds like isoprene, its oxidation products methyl vinyl ketone,methacrolein, tentatively identified hydroxy-isoprene-hydroperoxides, andseveral other organic compounds. Isoprene volume mixing ratios (VMR) variedfrom below the detection limit at the highest altitudes to about 7 nmol/molin the planetary boundary layer shortly before sunset. Correlations betweenisoprene and its product compounds were made for different times of day andaltitudes, with the isoprene-hydroperoxides showing the highest correlation.Model calculated mixing ratios of the isoprene oxidation products using adetailed hydrocarbon oxidation mechanism, as well as the intercomparisonmeasurement with air samples collected during the flights in canisters andlater analysed with a GC-FID, showed good agreement with the PTR-MSmeasurements, in particular at the higher mixing ratios.Low OH concentrations in the range of 1–3 × 10⁵molecules cm^-3 averaged over 24 hours were calculated due to lossof OH and HO₂ in the isoprene oxidation chain, thereby stronglyenhancing the lifetime of gases in the forest boundary layer.     

The post-depositional reactivity of iron and managanese in the sediments of a macrotidal estuarine system

Four cores of anoxic sediments were collected from the Seine estuary to assess the early diagenesis pathways leading to the formation of previously reactive phase. Pore waters were analyzed for dissolved iron (Fe) and manganese (Mn) and different ligands (e.g., sulfate, chloride, total inorganic carbon). The anoxic zone is present up to the first centimeter depth, in these conditions the reduction of Mn and Fe oxides and SO₄ ²⁻ was verified. The sulfate reduction was well established with a subsequent carbon mineralization in the NORMAI94 core. The chemical speciation of Mn and Fe in the dissolved and solid phases was determined. For the dissolved phase, thermodynamic calculations were used to characterize and illustrate the importance of carbonate and phosphate phases as sinks for Fe and Mn. The ion activity product (IAP) of Fe and Mn species was compared to the solubility products (Ks) of these species. In the solid phase, the presence of higher concentration of calcium carbonate in the Seine sediments is an important factor controlling Mn cycle. The carbonate-bound Mn can reach more than 75% of the total concentration. This result is confirmed by the use of electron spin resonance (ESR) spectroscopy. The reduction of Fe is closely coupled to the sulfate reduction by the formation of new solid phases such as FeS and FeS₂, which can be regarded as temporal sinks for sulfides. These forms were quantified in all cores as acid volatile sulfide (AVS: FeS+ free sulfide) and chromium reducible sulfide (CRS: FeS₂+elemental sulfur S⁰).     

Reliability-based design of R/C water tank structures under seismic action

Based on a reliability level 2 method, a procedure is proposed to design reinforced concrete structures for elevated tanks subjected to seismic action, with a specified probability of failure in a 50-year design life. To evaluate the probability of failure the ultimate limit state is obtained when the top column displacement demanded by the earthquake, a random variable, reaches the allowable displacement, which is here treated as deterministic. The seismic action is characterized probabilistically by the power spectral density function of the ground acceleration, which is obtained from a design spectrum. The strength and ductility of an annular column section of confined reinforced concrete for cyclic loads are evaluated with design aids. Design charts are made for a given tank capacity and specified seismic zone that allow one to choose different combinations of strength, stiffness and ductility for the same tolerable probability of failure. A step by step method is suggested for the design of the annular column section, choosing finally the most convenient design. The advantage of this methodology is shown through a numerical example.     

Epiphytic orchids and their ecological niche under anthropogenic influence in central Himalayas,Nepal

The survival chance of epiphytic orchids today not only depends on the natural site conditions required by the orchids but also on anthropogenic changes in site conditions.This study answers two questions:(1) What is the ecological niche of the different epiphytic orchid species?(2) What are the ecological factors that threaten epiphytic orchid's population under anthropogenic disturbances? Our study area was the Kathmandu valley,Nepal,with its subtropical forest.We established 156 systematically selected sampling points in the Kathmandu area covering different types of ecosystems under human impacts such as densely populated area,agricultural land,mixed agricultural and settled area,old tree patches,and a natural forest in a national park.The ecological niche of the orchid species was analyzed with a principal component analysis(PCA).The correlations between the different site factors were statistically significant.Spearman's rank correlation matrices showed that the variables land-use intensities with altitude,and height with diameter in breast height(dbh) of host had the highest significant positive correlation coefficient(0.67 and 0.64 respectively).On the other hand,host bark p H and altitude as well as land use had a significantly strong negative correlation coefficient(-0.80 and-0.61,respectively).Different epiphytic orchid species interact differently with the given set ofenvironmental factors:for occurrence of Vanda cristata there is no single environmental factor of special influence,while for Rhynchostylis retusa high bark p H and high light availability are important.First two axis of the PCA explained more than 50% of the total variance.Most orchid species occupy a specific,narrow niche in this ecological space.The main causes of anthropogenic influence of orchid population in the Kathmandu Valley are loss of adequate host trees(species and size) and increasing air pollution,resulting in increasing host bark p H.     

Bodenkundliche Probleme in ihrer Bedeutung für die Geologie

Ohne Zusammenfassung     

Methane emission measurements in urban areas in Eastern Germany

We have investigated methane emissions from urban sources in the former East Germany using innovative measurement techniques including a mobile real-time methane instrument and tracer release experiments. Anthropogenic and biogenic sources were studied with the emphasis on methane emissions from gas system sources, including urban distribution facilities and a production plant. Methane fluxes from pressure regulating stations ranged from 0.006 to 24. l/min. Emissions from diffuse sources in urban areas were also measured with concentration maps and whole city flux experiments. The area fluxes of the two towns studied were 0.37 and 1.9 g/m²/s. The emissions from individual gas system stations and total town emissions of this study are comparable to results of similar sites examined in the United States.     

Change-points in climate extremes in the Zhujiang River Basin, South China, 1961–2007

In this paper, change-points in time series of annual extremes in temperature and precipitation in the Zhujiang River Basin are analyzed with the CUSUM test. The data cover the period 1961–2007 for 192 meteorological stations. Annual indicators are analyzed: mean temperature, maximum temperature, warm days, total precipitation, 5-day maximum precipitation, and dry days. Significant change-points (1986/87, 1997/98, 1968/69, and 2003/04) are detected in the time series of most of the indicators. The change-point in 1986/87 is investigated in more detail. Most stations with this change-point in temperature indicators are located in the eastern and coastal areas of the basin. Stations with this change-point in dry days are located in the western area. The means and trends of the temperature indicators increase in the entire basin after 1986/87. The highest magnitudes can be found at the coast and delta. Decreasing (increasing) tendencies in total and 5-day maximum precipitation (dry days) are mostly observed in the western and central regions. The detected change-points can be explained by changes in the indices of the Western Pacific subtropical high and the East Asian summer monsoon as well as by change-points in wind directions. In years when the indices simultaneously increase and decrease (indices taking reverse directions to negative and positive) higher annual temperatures and lower annual precipitation occur in the Zhujiang River Basin. The high station density and data quality are very useful for spatially assessing change-points of climatic extreme events. The relation of the change points to large-scale oscillation can provide valuable data for planning adaptation measures against climate risks, e.g. for flood control, disaster preparedness, and water resource management.