Nb–Ta–(Ti–Sn) oxide mineral chemistry as tracer of rare-element granitic pegmatite fractionation in the Borborema Province,Northeastern Brazil

The Borborema Pegmatitic Province (BPP), northeastern Brazil, is historically important for tantalum mining and also famous for top-quality specimens of exotic Nb–Ta oxides and, more recently, for the production of gem quality, turquoise blue, ‘Paraíba Elbaite.’ With more than 750 registered mineralized rare-element granitic pegmatites, the BPP extends over an area of about 75 by 150 km in the eastern part of the Neoproterozoic Seridó Belt. The Late Cambrian pegmatites are mostly hosted by a sequence of Neoproterozoic cordierite–sillimanite biotite schists of the Seridó Formation and quartzites and metaconglomerates of the Equador Formation. The trace-element ratios in feldspar and micas allow to classify most pegmatites as belonging to the beryl–columbite phosphate subtype. Electron microprobe analyses (EMPA) of columbite, tapiolite, niobian–tantalian rutile, ixiolite and wodginite group minerals from 28 pegmatites in the BPP are used to evaluate the effectiveness of Nb–Ta oxide chemistry as a possible exploration tool, to trace the degree of pegmatite fractionation and to classify the pegmatites. The columbite group mineral composition allows to establish a compositional trend from manganoan ferrocolumbite to manganocolumbite and on to manganotantalite. This trend is typical of complex spodumene- and/or lepidolite-subtype pegmatites. It clearly contrasts with another trend, from ferrocolumbite through ferrotantalite to ferrowodginite and ferrotapiolite compositions, typical of pegmatites of the beryl–columbite phosphate subtype. Large scatter and anomalous trends in zoned crystals partially overlap and conceal the two main evolution patterns. This indicates that a large representative data set of heavy mineral concentrate samples, collected systematically along cross-sections, would be necessary to predict the metallogenetic potential of individual pegmatites. Other mineral species, e.g. garnets and/or tourmaline, with a more regular distribution than Nb–Ta oxides, would be more appropriate and less expensive for routine exploration purposes. The currently available Nb–Ta oxide chemistry data suggest the potential for highly fractionated Ta–Li–Cs pegmatites in the BPP, so far undiscovered, and encourages further, more detailed research.     

Late-Pleistocene and mid-Holocene environmental changes in highland valley head areas of Santa Catarina state, Southern Brazil

Low resolution of the continental sedimentary record is a common source of skepticism about the application of geomorphology and sedimentology to Quaternary studies. In spite of this, when supported by independent proxy data, geomorphology and sedimentology may favor palaeo-hydrologic interpretation. This paper associates geomorphologic, stratigraphic, sedimentologic, isotopic, palynologic and geochronologic data. The research was conducted in valley head sites in southern Brazilian highlands, under mild subtropical climate. The results point to environmental changes, the ages of which coincide to Marine Isotopic Stages (MIS) 5b, 3, 2 and 1. Although late-Pleistocene temperatures and precipitation were lower than those of today, the study valley heads seem to have sustained locally wetter environments, which fed shallow soil–water saturated zones. These saturated zones are believed to have expanded during transitions between stadial and interstadial states, contributing to hillslope erosion and sedimentation regardless of the sign of the climatic change. The interior organization of holocenic slope-wash deposits suggests that the mid-Holocene climate was drier than today’s and was under the influence of seasonally contrasting precipitation regimes. The predominance of overland flow-related sedimentary records suggests that an excess of precipitation over evaporation influenced local palaeo-hydrology. This palaeo-hydrologic condition seems to have been recurrent and also explains the alternating periods of pedogenesis and sedimentation.     

Taphonomy and zooarchaeology in the Neotropics: A view from northwestern Patagonian forest and steppe

Modes of faunal exploitation in NW Chubut Province (Patagonia, Argentina) during the last 3500 calibrated years BP are discussed, based on taphonomic and zooarchaeological analyses. Bone assemblages were recovered from archaeological sites of the Sub-Antarctic forests and the extra-Andean Patagonian steppe, where huemul (Hippocamelus bisulcus) and guanaco (Lama guanicoe) were, respectively, the main staple. In the steppe, lesser rhea (Pterocnemia pennata), a medium-sized flightless bird, also was integrated into the hunter-gatherer diet. Rodents, carnivores, flying birds, and fishes also were recovered. Different processes and agents were involved in the accumulation of small vertebrates bone assemblages (e.g. birds of prey, foxes, and small carnivores). In the steppe, only two taxa of small vertebrates—birds and mountain viscacha (Lagidium viscacia)—can be related with human subsistence activities. These two taxa and all large vertebrates reveal fat-oriented carcass processing.Guanaco bone assemblages associated both with ceramic and non-ceramic technologies do not show changes in carcass processing. Moreover, the similarities in bone grease exploitation suggest boiling prior to the appearance of pottery.     

Impact of intensive fish farming on methane emission in a tropical hydropower reservoir

Fisheries and aquaculture are important sources of food for hundreds of millions of people around the world. World fish production is projected to increase by 15% in the next 10 years, reaching around 200 million tonnes per year. The main driver of this increase will be based on fish farming management in developing countries. In Brazil, fish farming is increasing due to the climate conditions and large supply of water resources, with the production system based on Nile tilapia (Oreochromis niloticus) farming in reservoirs. Inland waters like reservoirs are a natural source of methane (CH₄) to the atmosphere. However, knowledge of the impact from intensive fish production in net cages on CH₄ fluxes is not well known. This paper presents in situ measurements of CH₄ fluxes and dissolved CH₄ (DM) in the Furnas Hydroelectric Reservoir in order to evaluate the impact of fish farming on methane emissions. Measurements were taken in a control area without fish production and three areas with fish farming. The overall mean of diffusive methane flux (DMF) (5.9?±?4.5 mg CH₄ m^?2 day^?1) was significantly lower when compared to the overall mean of bubble methane flux (BMF) (552.9?±?1003.9 mg CH₄ m^?2 day^?1). The DMF and DM were significantly higher in the two areas with fish farming, whereas the BMF was not significantly different. The DMF and DM were correlated to depth and chlorophyll-a. However, the low production of BMF did not allow the comparison with the limnological parameters measured. This case study shows that CH₄ emissions are influenced more by reservoir characteristics than fish production. Further investigation is necessary to assess the impact of fish farming on the greenhouse gas emissions.     

The ecohydrological imprint of deforestation in the semiarid Chaco: insights from the last forest remnants of a highly cultivated landscape

The semiarid Chaco plains present one of the highest rates of forest clearing and agricultural expansion of the world. In other semiarid plains, such massive vegetation replacements initiated a groundwater recharge and salt mobilization process that, after decades, raised regional water tables and salts to the surface, degrading agricultural and natural ecosystems. Indirect evidence suggests that this process (known as dryland salinity) began in the Chaco plains. Multiple approaches (deep soil profiles, geoelectric surveys and monitoring of groundwater salinity, level and isotopic composition) were combined to assess the dryland salinity status in one of the oldest and most active agricultural hotspots of the region, where isolated forest remnants occupy an extremely flat cultivated matrix. Full vadose moisture and chloride profiles from paired agriculture‐forest stands (17 profiles, six sites) revealed the following: a generalized onset of deep drainage with cultivation (32 to >87 mm year^?1), full leaching of native chloride pools (13.7 ± 2.5 kg m^?2) down to the water table after >40 years following clearing and differential groundwater table rises (0.7 to 2 m shallower water tables under agriculture than under neighbouring forests). Continuous level monitoring showed abrupt water table rises under annual crops (up to 2.6 m in 15 days) not seen under forests or pastures. Varying deep drainage rates and groundwater isotopic composition under agricultural plots suggest that these pulses are strongly modulated by crop choices and sequences. In contrast to other dryland salinity‐affected areas of the world, forest remnants in the study area (10–20% of the area) are not only surviving the observed hydrological shifts but also sustaining active salty groundwater transpirative discharge, as evidenced by continuous water table records. The overall impact of these forest remnants on lowering neighbouring water tables would be limited by the low hydraulic conductivity of the sediments. As highly cultivated areas of the Chaco evolve to new hydrological conditions of shallower saline water tables, innovative crop rotations that minimize recharge, enhance transpirative discharge and tolerate salinity will be needed. Copyright © 2016 John Wiley & Sons, Ltd.     

Semi‐Micro Reflux Procedure for Minimization of Chloride Interference by COD Determination

In this study, a semi‐micro procedure for the COD (Chemical Oxygen Demand) was undertaken to allow the measurement of effluent samples with a high chloride content. It was found that the COD values for standard and effluent samples, corresponded closely to those obtained using the standard method of Burns and Marshall. When the method was applied to samples of industrial wastewater, with a very high chloride content, the recommended procedure proved to be accurate and precise, with RSDs of 6% and 4.3% for the standard and effluent solutions, respectively. The required amount of hazardous reagents was similar to that found in the standard closed reflux method. It was also possible to determine the total amount of oxidized halides. The use of this low‐cost, laboratory‐made system made it unnecessary to acquire an expensive, imported analytical system, while maintaining a high level of accuracy in the determinations.     

Late Quaternary landscape reconstruction and geochronology in the northern Pampas of Buenos Aires province,Argentina

This paper reports the main sedimentary characteristics, soil micromorphology and optically-stimulated luminescence (OSL) ages, and details the pedosedimentary reconstruction, of the Hudson site situated in the northern Pampas of Buenos Aires province. It also provides the OSL chronology and a reinterpretation of previously reported micromorphological features for the nearby site of Gorina. Finally, the stratigraphic records of both sites are compared and the main environmental events discussed in a regional context.At Hudson, situated at a low altitude environment close to the coastal plain, the basal fine-grained paludal deposits were unconformably covered by coastal marine sediments with an OSL age of ca. 128 ka supporting its correlation with the high stand of sea level of marine isotope stage 5e. A paleosol developed on the marine deposits and the underlying paludal sediments. OSL ages suggest that soil development and its subsequent erosion occurred over some period between ca. 128 and 54 ka. Fine sediment accumulation in a paludal environment continued until prior to ca. 23 ka when the accumulation of the uppermost loess mantle started. It continued until the early Holocene when present soil development began. At Gorina, OSL ages suggest that the upper part of the pedocomplex formed at some stage between ca. 194 and 56 ka. Loess then accumulated followed by an erosional phase; loess deposition restarted by ca. 29 ka and continued until the beginning of the Holocene (ca. 9 ka) when the present land surface was established.The stratigraphic and paleoenvironmental differences exhibited by the Hudson and Gorina records result from their contrasting geomorphological settings. The OSL geochronology suggests that the last interglacial (MIS 5) at Hudson is marked by the accumulation of marine deposits (MIS 5e) and the subsequent development of a paleosol. The equivalent soil-forming interval at Gorina is represented by the upper part of the buried pedocomplex. Both at Gorina and Hudson, loess accumulation was dominant especially during MIS 2. Loess accumulation continued during MIS 1 until the early Holocene with apparently somewhat higher sedimentation rates in Hudson. Pedogenesis has been predominant during the rest of the Holocene, resulting in the formation of the surface soil profiles.     

Modeling the Acid–Base Surface Properties of Aquatic Sediments

We propose a model that explains the acid–base surface properties of clastic sediments from two Argentinean reservoir lakes. The model uses potentiometric titration data sets and fixed parameters such as the apparent stability constants and reaction stoichiometries of acid–base equilibriums involving known mineral phases. The model considers that sediments act as a set of independent sorption surfaces, such as organic matter, clay silicate, and iron (hydr)oxides, thus the acid–base equilibrium and the correspondent protolytic constants are represented by a humic acid, a Na-illite, and a poor crystalline Fe-hydr(oxide). In agreement with experimental data, the model predicts that all sediment samples show a similar charging behavior, increasing the negative charge as the pH increases. The net charge of sediments is controlled by the presence of negatively charged minerals and/or organic matter coatings. This reveals the great influence of clays and organic matter functional groups on the acid–base surface properties of sediments, and consequently on the surface reactivity toward contaminant transport.