Baseline geochemical mapping of Sardinia (Italy)

A total of about 20,000 stream sediment samples from about 13,000 km² were collected in Sardinia and analysed for eleven elements (Ag, Co, Cr, Cu, F, Hg, Mn, Mo, Ni, Pb, Sb and Zn) by Ente Minerario Sardo (EMS), aimed at mineral exploration. We have reutilized 16,890 samples (covering an area of 7987 km²) of the above data to compile geochemical baseline maps for all single elements as well as maps showing the regional variability of factor scores resulting from R-mode factor analysis. This type of maps has a particular relevance to environmental issues, especially in a region such as Sardinia which has been mined since pre-Roman times.     

The dependence of asteroid lightcurves on the orientation parameters and the shapes of asteroids

The dependence of asteroidal light curves has been derived from the obliquity, aspect and phase angles. The effects of an angle variation are discussed taking into account the possible geometry of an asteroidal body.The amplitude-aspect relation is discussed for different asteroidal shapes.On the basis of this relation a graphical attempt to determine the value of the aspect from the light curves' amplitude is described.     

Seasonal changes of the profundal macrobenthic community in a polluted lake

Late summer and winter structures of the profundal macrobenthos in a polluted lake (Lake Nemi, Central Italy) were compared to verify the relative differences in the faunal structure and the magnitude of the winter recovery of this community. Densities of Oligochaetes and Chironomids did not vary significantly from summer to winter, the latter not showing any recolonization of the profundal zone. Structure and diversity of the total fauna, and Oligochaete/Chironomid ratio were very similar in the two periods. Our results suggest that in a severely polluted lake, with a strong and lasting oxygen deficit in the hypolimnic zone, a lack of recovery of profundal macrobenthos may be expected in improved environmental winter conditions.     

Observing water-level variations from space-borne high-resolution Synthetic Aperture Radar (SAR) image correlation

The potential of correlating high-resolution Synthetic Aperture Radar images to estimate local water-level variations is analysed based on observing the motions of floating structures. By computing range and azimuth offsets on a COSMO-SkyMed multi-temporal data-set in an area of the French Atlantic Coast, displacement signatures were detected in several harbours of the region. They can be associated with specific floating structures, whose vertical motion is mostly driven by tides. Although the image resolution is not the best achievable for the COSMO-SkyMed sensor, comparison with ground-based tide information revealed that the obtained space-borne measurements are consistent with the tide gauges to a decimetric accuracy. Even if the requirements for traditional users of tidal data are not met by the current revisit time of the COSMO-SkyMed constellation, the method proposed here provides complementary measures, which are already well aligned to requirements of users concerned with long-term sea-level variation and river or lake water stocks.     

The environmental risk posed by small dumps of complex arsenic,antimony, nickel and cobalt sulphides

Mine waste dumps sited in the vicinity of mine workings typically consist of fragmented rock masses which in chemical terms may be defined as "complex systems", due to uncertainties in accurately simulating their behaviour, when water or aqueous solutions percolate through them. Remediation of the contamination problems created by abandoned mine dumps concerns many former mining areas from Europe to Africa. These dumps usually range in size from a few hundred thousand up to million cubic meters of rock defined as “waste” but which still contain significant amounts of potentially toxic elements. Although relatively small, they are often densely distributed in the territory impacting on surface and ground-water. This scenario is particularly applicable to the region of Sardinia, Italy, where several small dumps of uncommon sulphide minerals still exist on derelict mine sites. This paper reports on the results of a research project aimed at defining appropriate remedial measures of acid rock drainage. A dump of a Co–Ni–As–Sb complex sulphides mine was investigated and simulated in a laboratory leaching column. The column was irrigated with distilled water and a repetitive behaviour of the polluting elements concentrations in the effluents was observed for each run. Regardless of the campaign duration and the extent of the intervals between tests metal ions concentration peaks (250–50 ppm for Ni, 35–20 ppm for Co, 1.6–0.4 ppm for As, 20–15 ppm for Zn and 0.03–0.002 ppm for Sb) and acidic conditions (pH 2.5–3.5), on resumption of each irrigation, was noticed. As percolation continued, the ion concentrations decreased within the discharge limits after the replacement of only two pore volumes of the column material. This produces the conception that a sufficiently long rainfall period could remediate the polluting effects. Conception contradicted by field experiences: sporadic rainfall events, typical of the region, are not sufficient to completely leach out the metal ions. The repetitive nature of the leaching processes, both quantitatively and qualitatively, can be explained only by the activity of a microflora thriving in the rock mass even during long dry periods. Microbial tests and neutralisation campaigns confirmed this hypothesis and suggested that any effective remediation strategy must take into consideration the interaction between environmental factors with microbiological activities.     

Patterns of basin fill in Triassic turbidites of the Nanpanjiang basin: implications for regional tectonics and impacts on carbonate‐platform evolution

The Nanpanjiang Basin occurs in a key position for resolving controversies of basin tectonics and patterns of plate assembly at the junction between south China and Southeast Asian plates. Paleocurrent measurements indicate that siliciclastic turbidites in the basin were sourced by the Precambrian Jiangnan uplift to the northeast, the Precambrian Yunkai uplift to the southeast and the Triassic Songma suture to the south. Detrital zircon geochronology reveals Archean (2500 Ma), Paleoproterozoic (1800–1900 Ma), Neoproterozoic (900–1000 Ma) and Paleozoic (420–460 Ma) ages consistent with derivation from the Jiangnan and Yunkai uplifts. A large Permian‐Triassic peak of 250 Ma is present in the southern basin and attenuates northward suggesting derivation from an arc developed along the Songma suture. Sandstone QFL compositions average 65/12/23% and plot in the recycled orogen field except for a few samples in the southern basin that fall in the dissected arc field. The compositions are consistent with derivation from Precambrian basement that includes orogenic complexes. In the southern basin, Middle Triassic turbidites contain greater lithics and feldspars and Lower Triassic turbidites have volcaniclastic composition consistent with derivation from a southerly arc. Our preferred interpretation is evolution from remnant basin to a large peripheral foreland with southward subduction and convergence with Indochina along the Songma suture. The previously proposed Dian‐Qiong zone is not a suture as its map location places it within carbonate platforms bounded by identical stratigraphy. The Nan‐Uttaradit zone is too distant to have provided voluminous siliciclastic flux to the basin. The Nanpanjiang Basin provides an example of the evolution of an exceptionally large foreland with far‐field rejuvenation of Precambrian uplifts and carbonate platforms that were significantly influenced by siliciclastic flux. The timing and pattern of turbidite basin fill impacted platform evolution by enabling margin progradation in areas proximal to siliciclastic sources, whereas platforms distant from sources were driven to aggradation and extreme relief with large‐scale gravitational sector collapse.     

On the potential of mapping sea level anomalies from satellite altimetry with Random Forest Regression

Ocean Dynamics - The sea level observations from satellite altimetry are characterised by a sparse spatial and temporal coverage. For this reason, along-track data are routinely interpolated into...     

New gravity maps of the Eastern Alps and significance for the crustal structures

The deep seismic profile Transalp crosses, from north to south, Germany, Austria and Italy. The gravity measurements for each country were made by national agencies with different reference systems and data reduction methods. Within the frame of the Transalp-project a comprehensive database of the Eastern Alps was compiled covering an area of 3.5° by 4° in longitude and latitude (275 by 445 km), respectively. To increase the data coverage in the south Alpine area two gravity surveys were carried out, resulting in 469 areally distributed new stations, of which 215 have been measured with the intent to improve the geoid in the area of the planned Brenner Basistunnel (BBT). The resulting gravity database is the best in terms of resolution and data quality presently available for the Eastern Alps. Here the free air, Bouguer and isostatic gravity fields are critically discussed. The spatial density of existing gravity stations in the three countries is discussed. On the Italian side of the Alps the spatial density is rather sparse compared to the Austrian side. The Bouguer-gravity field varies between − 190 * 10^− 5 m/s² and + 25 * 10^− 5 m/s², with the minimum located along the Alpine high topographic chain, but with a small offset (a few tens of km) to the greatest topographic elevation, showing that the Airy-type local isostatic equilibrium does not fully apply here. The maximum of the Bouguer anomaly has an elongated shape of 100 by 50 km located between the towns of Verona and Vicenza and covers the Venetian Tertiary Volcanic Province (VTVP), a feature not directly related to the plate collision in the Eastern Alps. The gravity high is only partly explainable by high-density magmatic rocks and requires also a deeper source, like a shallowing of the Moho. The isostatic residual anomalies (Airy model) are in the range ± 50 * 10^− 5 m/s², with the greatest positive anomaly corresponding to the location of the VTVP, indicating here under-compensation of masses. At last a discussion of a 2D density model based on reflection seismic data and receiver functions is made.