Field investigation and modelling of coupled stream discharge and shallow water‐table dynamics in a small Mediterranean catchment (Sardinia)

In the semi‐arid Mediterranean environment, the rainfall–runoff relationships are complex because of the markedly irregular patterns in rainfall, the seasonal mismatch between evaporation and rainfall, and the spatial heterogeneity in landscape properties. Watersheds often display considerable non‐linear threshold behavior, which still make runoff generation an open research question. Our objectives in this context were: to identify the primary processes of runoff generation in a small natural catchment; to test whether a physically based model, which takes into consideration only the primary processes, is able to predict spatially distributed water‐table and stream discharge dynamics; and to use the hydrological model to increase our understanding of runoff generation mechanisms. The observed seasonal dynamics of soil moisture, water‐table depth, and stream discharge indicated that Hortonian overland‐flow was negligible and the main mechanism of runoff generation was saturated subsurface‐flow. This gives rise to base‐flow, controls the formation of the saturated areas, and contributes to storm‐flow together with saturation overland‐flow. The distributed model, with a 1D scheme for the kinematic surface‐flow, a 2D sub‐horizontal scheme for the saturated subsurface‐flow, and ignoring the unsaturated flow, performed efficiently in years when runoff volume was high and medium, although there was a smoothing effect on the observed water‐table. In dry years, small errors greatly reduced the efficiency of the model. The hydrological model has allowed to relate the runoff generation mechanisms with the land‐use. The forested hillslopes, where the calibrated soil conductivity was high, were never saturated, except at the foot of the slopes, where exfiltration of saturated subsurface‐flow contributed to storm‐flow. Saturation overland‐flow was only found near the streams, except when there were storm‐flow peaks, when it also occurred on hillslopes used for pasture, where soil conductivity was low. The bedrock–soil percolation, simulated by a threshold mechanism, further increased the non‐linearity of the rainfall–runoff processes. Copyright © 2013 John Wiley & Sons, Ltd.     

The pressure-induced ringwoodite to Mg-perovskite and periclase post-spinel phase transition: a Bader’s topological analysis of the ab initio electron densities

In order to characterize the pressure-induced decomposition of ringwoodite (γ-Mg₂SiO₄), the topological analysis of the electron density ρ(r), based upon the theory of atoms in molecules (AIM) developed by Bader in the framework of the catastrophe theory, has been performed. Calculations have been carried out by means of the ab initio CRYSTAL09 code at the HF/DFT level, using Hamiltonians based on the Becke- LYP scheme containing hybrid Hartree–Fock/density functional exchange–correlation terms. The equation of state at 0 K has been constructed for the three phases involved in the post-spinel phase transition (ringwoodite → Mg-perovskite + periclase) occurring at the transition zone–lower mantel boundary. The topological results show that the decomposition of the ringwoodite at high pressures is caused by a conflict catastrophe. Furthermore, topological evidences of the central role played by the oxygen atoms to facilitate the pressure-induced ringwoodite decomposition and the subsequent phase transition have been noticed.     

A continuous multi-millennial record of surficial bivalve mollusk shells from the São Paulo Bight,Brazilian shelf

To evaluate the potential of using surficial shell accumulations for paleoenvironmental studies, an extensive time series of individually dated specimens of the marine infaunal bivalve mollusk Semele casali was assembled using amino acid racemization (AAR) ratios (n = 270) calibrated against radiocarbon ages (n = 32). The shells were collected from surface sediments at multiple sites across a sediment-starved shelf in the shallow sub-tropical São Paulo Bight (São Paulo State, Brazil). The resulting ¹⁴C-calibrated AAR time series, one of the largest AAR datasets compiled to date, ranges from modern to 10,307 cal yr BP, is right skewed, and represents a remarkably complete time series: the completeness of the Holocene record is 66% at 250-yr binning resolution and 81% at 500-yr binning resolution. Extensive time-averaging is observed for all sites across the sampled bathymetric range indicating long water depth-invariant survival of carbonate shells at the sediment surface with low net sedimentation rates. Benthic organisms collected from active depositional surfaces can provide multi-millennial time series of biomineral records and serve as a source of geochemical proxy data for reconstructing environmental and climatic trends throughout the Holocene at centennial resolution. Surface sediments can contain time-rich shell accumulations that record the entire Holocene, not just the present.     

Antigorite equation of state and anomalous softening at 6 GPa: an in situ single-crystal X-ray diffraction study

The compressibility of antigorite has been determined up to 8.826(8) GPa, for the first time by single crystal X-ray diffraction in a diamond anvil cell, on a specimen from Cerro del Almirez. Fifteen pressure–volume data, up to 5.910(6) GPa, have been fit by a third-order Birch–Murnaghan equation of state, yielding V ₀ = 2,914.07(23) Å³, K _T0 = 62.9(4) GPa, with K′ = 6.1(2). The compression of antigorite is very anisotropic with axial compressibilities in the ratio 1.11:1.00:3.22 along a, b and c, respectively. The new equation of state leads to an estimation of the upper stability limit of antigorite that is intermediate with respect to existing values, and in better agreement with experiments. At pressures in excess of 6 GPa antigorite displays a significant volume softening that may be relevant for very cold subducting slabs.     

Multiple spacecraft rendezvous maneuvers by differential drag and low thrust engines

A novel two-phase hybrid controller is proposed to optimize propellant consumption during multiple spacecraft rendezvous maneuvers in Low Earth Orbit. This controller exploits generated differentials in aerodynamic drag on each involved chaser spacecraft to effect a propellant-free trajectory near to the target spacecraft during the first phase of the maneuver, and then uses a fuel optimal control strategy via continuous low-thrust engines to effect a precision dock during the second phase. In particular, by varying the imparted aerodynamic drag force on each of the chaser spacecraft, relative differential accelerations are generated between each chaser and the target spacecraft along two of the three translational degrees of freedom. In order to generate this required differential, each chaser spacecraft is assumed to include a system of rotating flat panels. Additionally, each chaser spacecraft is assumed to have continuous low-thrust capability along the three translational degrees of freedom and full-axis attitude control. Sample simulations are presented to support the validity and robustness of the proposed hybrid controller to variations in the atmospheric density along with different spacecraft masses and ballistic coefficients. Furthermore, the proposed hybrid controller is validated against a complete nonlinear orbital model to include relative navigation errors typical of carrier-phase differential GPS (CDGPS). Limitations of the proposed controller appear relative to the target spacecraft’s orbit eccentricity and a general characterization of the atmospheric density. Bounds on these variables are included to provide a framework within which the proposed hybrid controller can effect an extremely low propellant rendezvous of multiple chaser spacecraft to a desired target spacecraft.     

Titan's methane cycle

Methane is key to sustaining Titan's thick nitrogen atmosphere. However, methane is destroyed and converted to heavier hydrocarbons irreversibly on a relatively short timescale of approximately 10-100 million years. Without the warming provided by CH₄-generated hydrocarbon hazes in the stratosphere and the pressure induced opacity in the infrared, particularly by CH₄-N₂ and H₂-N₂ collisions in the troposphere, the atmosphere could be gradually reduced to as low as tens of millibar pressure. An understanding of the source-sink cycle of methane is thus crucial to the evolutionary history of Titan and its atmosphere. In this paper we propose that a complex photochemical-meteorological-hydrogeochemical cycle of methane operates on Titan. We further suggest that although photochemistry leads to the loss of methane from the atmosphere, conversion to a global ocean of ethane is unlikely. The behavior of methane in the troposphere and the surface, as measured by the Cassini-Huygens gas chromatograph mass spectrometer, together with evidence of cryovolcanism reported by the Cassini visual and infrared mapping spectrometer, represents a “methalogical” cycle on Titan, somewhat akin to the hydrological cycle on Earth. In the absence of net loss to the interior, it would represent a closed cycle. However, a source is still needed to replenish the methane lost to photolysis. A hydrogeochemical source deep in the interior of Titan holds promise. It is well known that in serpentinization, hydration of ultramafic silicates in terrestrial oceans produces H_2(aq), whose reaction with carbon grains or carbon dioxide in the crustal pores produces methane gas. Appropriate geological, thermal, and pressure conditions could have existed in and below Titan's purported water-ammonia ocean for “low-temperature” serpentinization to occur in Titan's accretionary heating phase. On the other hand, impacts could trigger the process at high temperatures. In either instance, storage of methane as a stable clathrate-hydrate in Titan's interior for later release to the atmosphere is quite plausible. There is also some likelihood that the production of methane on Titan by serpentinization is a gradual and continuous on-going process.     

Partitioning between “wedge-top” river- and wave-dominated successions: an example from the late Tortonian — early Messinian Terravecchia Formation (NW Sicily)

Detailed field sedimentological and facies analyses have been performed in the Terravecchia Formation cropping out in NW Sicily, in order to differentiate and describe, for the first time, wave- and river-dominated shallow-marine (deltaic) siliciclastic successions. The latter were deposited filling syntectonic basins, developed between the late Tortonian and early Messinian time, within the wedge-top depozone of the Sicilian Foreland Basin System. It has been observed that river-dominated successions, recording the deposition of small fan-deltas are characterized by fining- to coarsening upward, transgressive-regressive sequences which were mostly deposited filling relatively narrow and often oversupplied basins. These basins were probably located in a proximal sector of the wedge-top depozone, closer to emergent sectors of the chain and probably sheltered from the main marine areas. Wavedominated successions, on the other hand, are characterized by upward fining, mostly transgressive sequences which were deposited filling wider basins open to major marine regions and located in a more distal position of the wedge-top depozone. The documented partitioning between river- and wave-dominated successions, as a function of the position of the sedimentary basin within the wedge-top depozone, is coherent with data from analyses of the deformational patterns of the Terravecchia Formation in this study area. Furthermore, the data here presented could be considered as a preliminary database for future characterization and analysis of siliciclastic reservoirs from Sicilian outcrop analogues.     

Peculiar earthquake damage on a reinforced concrete building in San Gregorio (L��Aquila, Italy): site effects or building defects?

In San Gregorio (L’Aquila, Italy) a three-story, reinforced concrete (RC) building had the first floor collapsed following the earthquake of April 6, 2009. The remaining two stories fell with a displacement in the horizontal projection of about 70 cm. This unusual behaviour is made more puzzling by the fact that buildings located at a short distance and with similar features had little or no damage reported. To understand the causes of the collapse we performed strong motion recordings, microtremor measurements, a detailed geological survey, a high-resolution geo-electrical tomography, a borehole with a down-hole test. On the building we performed a geometrical survey and laboratory tests on concrete cores. The acceleration and noise recordings have shown a high amplification with uphill-downhill direction. The geological survey has revealed the presence of co-seismic fractures on stiff soils. Geo-electrical tomography has shown an unexpected, strong discontinuity just below the building. Taking advantage of excavations in adjacent lots, we have highlighted rare cataclastic decimetric bands with a very low resistance material incorporated in well-stratified calcarenites. The same soft material has been founded in the borehole down to 17 m from ground level, showing a shear wave velocity that starts at 250 m/s, increases with depth and has an abrupt transition in calcarenites at 1,150 m/s. The surface geophysical measurements in the vicinity of the site have not shown similar situations, with flat HVSR curves as expected for a rock outcrop, except for a lateral extension of the soft zone. The analysis on the quality of the building materials has yielded values higher than average for the age and type of construction, and no special design or construction deficiencies have been observed. A strong, peculiar site effect thus appears to be the most likely cause of the damage observed.