Time–Latitudinal Development of the White-Light Coronal Structures over a Solar Cycle

Large-scale coronal structures (helmet streamers) observed in the white-light corona during total solar eclipses and/or with ground-based coronagraphs are mostly located only above quiescent types of prominences. These helmet streamers are maintained due to the magnetic fields of the Sun. Time–latitudinal distribution of prominences during a solar cycle, however, shows both the poleward and equatorward migrations, similar to the 530.3 nm emission corona (the green corona) intensities. Distribution of observed coronal helmet streamers during total solar eclipses, enlarged with the helmet streamers as were obtained by the ground-based coronagraph observations, are compared with the heliographic distribution of prominences and the green corona intensities for the first time. It is shown that the distribution of above-mentioned helmet streamers, reflects – roughly – the time–latitudinal distribution of prominences and emission corona branches, and migrates together with them over a solar cycle.     

Depth-profiles and surface enrichment of the halogens in four Antarctic H5 chondrites and in two non-Antarctic chondrites

Abstract— Depth-profiles of F, Cl, Br and I concentrations were determined in four different Antarctic H5 chondrites from the Allan Hills and in the two chondrites Allende (C3) and Holbrook (L6). Pieces of the meteorites were studied by analysis of stepwise removed layers of 0.5–1.0 mm thickness up to a depth of 9 mm. Neutron activation analysis and ion-selective potentiometry were used for the determination of Cl, Br, I and for F, respectively. The Antarctic meteorites show higher concentrations of the halogens at the surface compared to the interior. The highest enrichment factors are found for I and Cl and the lowest for Br. In contrast, F shows the steepest concentration gradient and is only enriched in the first 2.5 mm below the surface. The other halogens have penetrated deeper into the meteorites. The measured enrichments at the surfaces are not correlated to the visible degree of weathering. The analysed non-Antarctic meteorites, which were recovered shortly after their observed fall, demonstrate similar halogen concentrations at the surface, including the fusion crust, as in the interior. Based on these results we present a model to estimate the degree of contamination and the relation to the duration of exposure at the surface of the Antarctic ice.     

The heat flux density in a non-homogeneous bare loessial soil

This work describes the relationship between the diurnal patterns of the radiant energy exchange in the atmospheric surface layer and the soil heat flux density of a bare irrigated soil in an arid environment. The measurements show that the soil heat flux density is a large fraction of the net radiation. The soil moisture content has little effect on this fraction but modifies the phase relationship between the net radiation and the soil heat flux density waves. Differences between the thermal regimes of the wet and dry soil appear to be caused by latent heat exchanges rather than changes of the soil thermal properties. The data also show that the variation with depth of the soil thermal properties strongly influences the propagation of the temperature and heat flux density waves in the soil. A heat diffusion theory for non-homogeneous conductors (Lettau, 1962) which enables the thermal properties of the soil to be predicted is tested by comparison with experimental determinations in the field.     

Die elektrochemische Bestimmung des im Wasser gelösten Sauerstoffs mit Hilfe einer modifizierten Membranelektrodentechnik

Zusammenfassung Die Anwendungsm?glichkeiten der elektrochemischen Sauerstoffbestimmung wurden durch die Einführung der Kurzzeitmessung erweitert. Diese Methode gibt eine gr?ssere Empfindlichkeit und erlaubt somit die Sauerstoffbestimmung im μg/l-Bereich. Ferner wurde ein System entwickelt, das von der Membrandicke und dem Membranmaterial unabh?ngig ist. Das ist ein Vorteil, der speziell für Sauerstoffmessungen in Kl?ranlagen interessant sein dürfte.

---

Summary This paper presents a new electrochemical technique for DO measurements by means of membrane electrodes. In stead of the well-known steady state measurements, a transient technique which is more sensitive was used. This gives the possibility of measuring oxygen in the μl/l range. The system is independent of the membrane material and the membrane thickness. The stirring influence is considerably less than for steady state measurements. The independence of the membrane material will be especially useful for oxygen measurements in waste purification plants.

     

Phytoplankton photosynthetic response to light in an internal tide dominated environment

The influence of internal tides on phytoplankton photosynthetic response to light was studied in the Lower St. Lawrence Estuary. Photosynthesis at saturating light intensity responded to variations in the vertical density gradient, which were linked to the internal tides. The photosynthetic response was lag-correlated to the vertical water stratification. This suggests that the link between photosynthesis and the internal tides may have resulted from phytoplankton light adaptation.     

On the photodissociation of water vapour in the mesosphere

The photodissociation of water vapour in the mesosphere depends on the absorption of solar radiation in the region (175–200 nm) of the O₂ Schumann-Runge band system and also at H-Lyman alpha. The photodissociation products are OH + H, OH + H, O + 2H and H₂ + O at Lyman alpha; the percentages for these four channels are 70, 8, 12 and 10%, respectively, but OH + H is the only channel between 175 and 200 nm. Such proportions lead to a production of H atoms corresponding to practically the total photodissociation of H₂O, while the production of H₂ molecules is only 10% of the H₂O photodissociation by Lyman alpha.The photodissociation frequency (s^?1) at Lyman alpha can be expressed by a simple formula

$\text{J}{}_{\mathrm{<mtext>Ly</mtext><mtext>\alpha </mtext>}}\text{H}{}_2\text{O=4.5 ×10}{}^{\mathrm{?6}}\text{1+0.2}\text{F}{}_{10.7}\text{?65}\text{100}\text{exp}\text{[?4.4 ×10}{}^{\mathrm{?19}}\text{N}{}^{0.917}\text{]}$

where F_{10.7 cm} is the solar radioflux at 10.7 cm and N the total number of O₂ molecules (cm^?2), and when the following conventional value is accepted for the Lyman alpha solar irradiance at the top of the Earth's atmosphere ($\text{Δλ = 3.5}\text{A}\text{?}$) q_Lyα,∞ = 3 × 10¹¹ photons cm^?2 s^1?.The photodissociation frequency for the Schumann-Runge band region is also given for mesospheric conditions by a simple formula

$\text{J}{}_{\mathrm{<mtext>SRB</mtext>}}\text{(}\text{H}{}_2\text{O}\text{) = J}{}_{\mathrm{<mtext>SRB</mtext><mtext>,\infty </mtext>}}\text{(}\text{H}{}_2\text{O}\text{) exp [?10}{}^{\mathrm{?7}}\text{N}{}^{0.35}\text{]}$

where J_SRB,∞(H₂O) = 1.2 × 10^?6 and 1.4 × 10^?6 s^?1 for quiet and active sun conditions, respectively.The precision of both formulae is good, with an uncertainty less than 10%, but their accuracy depends on the accuracy of observational and experimental parameters such as the absolute solar irradiances, the variable transmittance of O₂ and the H₂O effective absorption cross sections. The various uncertainties are discussed. As an example, the absolute values deduced from the above formulae could be decreased by about 25-20% if the possible minimum values of the solar irradiances were used.     

Atmospheric input of nitrogen into the North Sea: ANICE project overview

The aim of the atmospheric nitrogen inputs into the coastal ecosystem (ANICE) project is to improve transport–chemistry models that estimate nitrogen deposition to the sea. To achieve this, experimental and modelling work is being conducted which aims to improve understanding of the processes involved in the chemical transformation, transport and deposition of atmospheric nitrogen compounds. Of particular emphasis within ANICE is the influence of coastal zone processes. Both short episodes with high deposition and chronic nitrogen inputs are considered in the project. The improved transport–chemistry models will be used to assess the atmospheric inputs of nitrogen compounds into the European regional seas (the North Sea is studied as a prototype) and evaluate the impact of various emission reduction strategies on the atmospheric nitrogen loads. Assessment of the impact of atmospheric nitrogen on coastal ecosystems will be based on comparisons of phytoplankton nitrogen requirements, other external nitrogen inputs to the ANICE area of interest and the direct nitrogen fluxes provided by ANICE. Selected results from both the experimental and modelling components are presented here. The experimental results show the large spatial and temporal variability in the concentrations of gaseous nitrogen compounds, and their influences on fluxes. Model calculations show the strong variation of both concentrations and gradients of nitric acid at fetches of up to 25 km. Aerosol concentrations also show high temporal variability and experimental evidence for the reaction between nitric acid and sea salt aerosol is provided by size-segregated aerosol composition measured at both sides of the North Sea. In several occasions throughout the experimental period, air mass back trajectory analysis showed connected flow between the two sampling sites (the Weybourne Atmospheric Observatory on the North Norfolk coast of the UK and Meetpost Noordwijk, a research tower at 9 km off the Dutch coast). Results from the METRAS/SEMA mesoscale chemistry transport model system for one of these cases are presented. Measurements of aerosol and rain chemical composition, using equipment mounted on a commercial ferry, show variations in composition across the North Sea. These measurements have been compared to results obtained with the transport–chemistry model ACDEP which calculates the atmospheric inputs into the whole North Sea area. Finally, the results will be made available for the assessment of the impact of atmospheric nitrogen on coastal ecosystems.     

Nonlinear saturation-based whitecapping dissipation in SWAN for deep and shallow water

This study investigates the effectiveness of a revised whitecapping source term in the spectral wind wave model SWAN (Simulating WAves Nearshore) that is local in frequency space, nonlinear with respect to the variance density and weakly dependent on the wave age. It is investigated whether this alternative whitecapping expression is able to correct the tendency towards underprediction of period measures that has been identified in the default SWAN model. This whitecapping expression is combined with an alternative wind input source term that is more accurate for young waves than the default expression. The shallow water source terms of bottom friction, depth-induced breaking and triad interaction are left unaltered. It is demonstrated that this alternative source term combination yields improved agreement with fetch- and depth-limited growth curves. Moreover, it is shown, by means of a field case over a shelf sea, that the investigated model corrects the erroneous overprediction of wind-sea energy displayed by the default model under combined swell-sea conditions. For a selection of field cases recorded at two shallow lakes, the investigated model generally improves the agreement with observed spectra and integral parameters. The improvement is most notable in the prediction of period measures.