An experimental study of Fe–Ni exchange between sulfide melt and olivine at upper mantle conditions: implications for mantle sulfide compositions and phase equilibria

The behavior of nickel in the Earth’s mantle is controlled by sulfide melt–olivine reaction. Prior to this study, experiments were carried out at low pressures with narrow range of Ni/Fe in sulfide melt. As the mantle becomes more reduced with depth, experiments at comparable conditions provide an assessment of the effect of pressure at low-oxygen fugacity conditions. In this study, we constrain the Fe–Ni composition of molten sulfide in the Earth’s upper mantle via sulfide melt–olivine reaction experiments at 2 GPa, 1200 and 1400 °C, with sulfide melt \(X_{{{\text{Ni}}}}^{{{\text{Sulfide}}}}=\frac{{{\text{Ni}}}}{{{\text{Ni}}+{\text{Fe}}}}\) (atomic ratio) ranging from 0 to 0.94. To verify the approach to equilibrium and to explore the effect of \({f_{{{\text{O}}_{\text{2}}}}}\) on Fe–Ni exchange between phases, four different suites of experiments were conducted, varying in their experimental geometry and initial composition. Effects of Ni secondary fluorescence on olivine analyses were corrected using the PENELOPE algorithm (Baró et al., Nucl Instrum Methods Phys Res B 100:31–46, 1995), “zero time” experiments, and measurements before and after dissolution of surrounding sulfides. Oxygen fugacities in the experiments, estimated from the measured O contents of sulfide melts and from the compositions of coexisting olivines, were 3.0?±?1.0 log units more reduced than the fayalite–magnetite-quartz (FMQ) buffer (suite 1, 2 and 3), and FMQ ??1 or more oxidized (suite 4). For the reduced (suites 1–3) experiments, Fe–Ni distribution coefficients \(K_{{\text{D}}}^{{}}=\frac{{(X_{{{\text{Ni}}}}^{{{\text{sulfide}}}}/X_{{{\text{Fe}}}}^{{{\text{sulfide}}}})}}{{(X_{{{\text{Ni}}}}^{{{\text{olivine}}}}/X_{{{\text{Fe}}}}^{{{\text{olivine}}}})}}\) are small, averaging 10.0?±?5.7, with little variation as a function of total Ni content. More oxidized experiments (suite 4) give larger values of K_D (21.1–25.2). Compared to previous determinations at 100 kPa, values of K_D from this study are chiefly lower, in large part owing to the more reduced conditions of the experiments. The observed difference does not seem attributable to differences in temperature and pressure between experimental studies. It may be related in part to the effects of metal/sulfur ratio in sulfide melt. Application of these results to the composition of molten sulfide in peridotite indicates that compositions are intermediate in composition (\(X_{{{\text{Ni}}}}^{{{\text{sulfide}}}}\)?~?0.4–0.6) in the shallow mantle at 50 km, becomes more Ni rich with depth as the O content of the melt diminishes, reaching a maximum (0.6–0.7) at depths near 80–120 km, and then becomes more Fe rich in the deeper mantle where conditions are more reduced, approaching (\(X_{{{\text{Ni}}}}^{{{\text{sulfide}}}}\)?~?0.28)?>?140 km depth. Because Ni-rich sulfide in the shallow upper mantle melts at lower temperature than more Fe-rich compositions, mantle sulfide is likely molten in much of the deep continental lithosphere, including regions of diamond formation.     

Enhanced residual mean circulation during the evolution of split type sudden stratospheric warming in observations and model simulations

Residual mean circulation changes during the evolution of sudden stratospheric warming (SSW) are investigated by composite analyses of 76 major warming events identified in a present day simulation performed with a coupled ocean–troposphere–stratosphere model from 299 winters. Their dynamical signatures are compared with the 17 SSW events identified from 35 years of Era-Interim data. The main difference is that, relative frequency of simulated SSW events is smaller than that obtained from reanalysis. SSW events are classified as displacement or split events based on the geopotential field values at 10 hPa. The geopotential field values identify 10 and 3 split events in simulation and observation respectively. The model quite accurately simulates some of the dynamical features associated with the major SSW. Residual mean circulation induced by EP-flux divergence, sum of advection and residual forcing are stronger in split events than in displacement type SSW has been confirmed by both simulation and observation. Moreover, the contribution of EP-flux divergence or planetary wave forcing is larger than the contribution of other types of forcing.     

Do sedentary behavior and physical activity spatially cluster? Analysis of a population-based sample of Boston adolescents

Sedentary behavior and lack of physical activity are key modifiable behavioral risk factors for chronic health problems, such as obesity and diabetes. Little is known about how sedentary behavior and physical activity among adolescents spatially cluster. The objective was to detect spatial clustering of sedentary behavior and physical activity among Boston adolescents. Data were used from the 2008 Boston Youth Survey Geospatial Dataset, a sample of public high school students who responded to a sedentary behavior and physical activity questionnaire. Four binary variables were created: (1) TV watching (>2 h/day), (2) video games (>2 h/day), (3) total screen time (>2 h/day); and (4) 20 min/day of physical activity (≥5 days/week). A spatial scan statistic was utilized to detect clustering of sedentary behavior and physical activity. One statistically significant cluster of TV watching emerged among Boston adolescents in the unadjusted model. Students inside the cluster were more than twice as likely to report >2 h/day of TV watching compared to respondents outside the cluster. No significant clusters of sedentary behavior and physical activity emerged. Findings suggest that TV watching is spatially clustered among Boston adolescents. Such findings may serve to inform public health policy-makers by identifying specific locations in Boston that could provide opportunities for policy intervention. Future research should examine what is linked to the clusters, such as neighborhood environments and network effects.     

Satellite estimates and subpixel variability of rainfall in a semi-arid grassland

卫星估雨精度的不确定性受到当地降雨类型和像元内降雨非均匀性影响,而结合这两个关键因素开展半干旱草原卫星估雨的研究有限.2009年夏,我们在中国锡林郭勒半干旱草原用多部微雨雷达和雨量计构建了9 km卫星像元降雨观测网,观测了像元内降雨非均匀性(空间变异系数CV),并评估了卫星估雨精度.结果表明:(1)CV值受像元内平均降雨量,降雨类型,降雨云面积及移向等影响,如高Cv值的降雨过程大多为平均降雨量小,对流性降雨过程,降雨云边缘像元CV值较高;(2)TRMM 3B42V7卫星估雨产品适用性较好,CMORPH和PERSIANN次之,但TRMM 3B42V7易在半干旱草原湖泊处高估降雨.     

Statistical forecast of the marine surge

Natural Hazards - This paper studies different machine learning methods for solving the regression problem of estimating the marine surge value given meteorological data. The marine surge is...     

Stormwater harvesting in ephemeral streams: how to bypass clogging and unsaturated layers

To cope with water scarcity in drylands, stormwater is often collected in surface basins and subsequently stored in shallow aquifers via infiltration. These stormwater harvesting systems are often accompanied by high evaporation rates and hygiene problems. This is commonly a consequence of low infiltration rates, which are caused by clogging layers that form on top of the soil profile and the presence of a thick vadose zone. The present study aims to develop a conceptual solution to increase groundwater recharge rates in stormwater harvesting systems. The efficiency of vadose-zone wells and infiltration trenches is tested using analytical equations, numerical models, and sensitivity analyses. Dams built in the channel of ephemeral streams (wadis) are selected as a study case to construct the numerical simulations. The modelling demonstrated that vadose-zone wells and infiltration trenches contribute to effective bypassing of the clogging layer. By implementing these solutions, recharge begins 2250–8100% faster than via infiltration from the bed surface of the wadi reservoir. The sensitivity analysis showed that the recharge rates are especially responsive to well length and trench depth. In terms of recharge quantity, the well had the best performance; it can infiltrate up to 1642% more water than the reservoir, and between 336 and 825% more than the trench. Moreover, the well can yield the highest cumulative recharge per dollar and high recharge rates when there are limitations to the available area. The methods investigated here significantly increased recharge rates, providing practical solutions to enhance aquifer water storage in drylands.

     

Petrogenesis of lunar impact melt rock meteorite Oued Awlitis 001

Oued Awlitis 001 is a highly feldspathic, moderately equilibrated, clast‐rich, poikilitic impact melt rock lunar meteorite that was recovered in 2014. Its poikilitic texture formed due to moderately slow cooling, which judging from textures of rocks in melt sheets of terrestrial impact structures, is observed in impact melt volumes at least 100 m thick. Such coherent impact melt volumes occur in lunar craters larger than ~50 km in diameter. The composition of Oued Awlitis 001 points toward a crustal origin distant from incompatible‐element‐rich regions. Comparison of the bulk composition of Oued Awlitis 001 with Lunar Prospector 5° γ‐ray spectrometer data indicates a limited region of matches on the lunar farside. After its initial formation in an impact crater larger than ~50 km in diameter, Oued Awlitis 001 was excavated from a depth greater than ~50 m. The cosmogenic nuclide inventory of Oued Awlitis 001 records ejection from the Moon 0.3 Ma ago from a depth of at least 4 m and little mass loss due to ablation during its passage through Earth's atmosphere. The terrestrial residence time must have been very short, probably less than a few hundred years; its exact determination was precluded by a high concentration of solar cosmic ray‐produced ¹⁴C. If the impact that excavated Oued Awlitis 001 also launched it, this event likely produced an impact crater >10 km in diameter. Using petrologic constraints and Lunar Reconnaissance Orbiter Camera and Diviner data, we test Giordano Bruno and Pierazzo as possible launch craters for Oued Awlitis 001.     

Trophic modeling of the Northern Humboldt Current Ecosystem, Part II: Elucidating ecosystem dynamics from 1995 to 2004 with a focus on the impact of ENSO

The Northern Humboldt Current Ecosystem is one of the most productive in the world in terms of fish production. Its location near to the equator permits strong upwelling under relatively low winds, thus creating optimal conditions for the development of plankton communities. These communities ultimately support abundant populations of grazing fish such as the Peruvian anchoveta, Engraulis ringens. The ecosystem is also subject to strong inter-annual environmental variability associated with the El Niño Southern Oscillation (ENSO), which has major effects on nutrient structure, primary production, and higher trophic levels. Here our objective is to model the contributions of several external drivers (i.e. reconstructed phytoplankton changes, fish immigration, and fishing rate) and internal control mechanisms (i.e. predator-prey) to ecosystem dynamics over an ENSO cycle. Steady-state models and time-series data from the Instituto del Mar del Perú (IMARPE) from 1995 to 2004 provide the base data for simulations conducted with the program Ecopath with Ecosim. In simulations all three external drivers contribute to ecosystem dynamics. Changes in phytoplankton quantity and composition (i.e. contribution of diatoms and dino- and silicoflagellates), as affected by upwelling intensity, were important in dynamics of the El Niño of 1997–98 and the subsequent 3 years. The expansion and immigration of mesopelagic fish populations during El Niño was important for dynamics in following years. Fishing rate changes were the most important of the three external drivers tested, helping to explain observed dynamics throughout the modeled period, and particularly during the post-El Niño period. Internal control settings show a mix of predator–prey control settings; however a “wasp-waist” control of the ecosystem by small pelagic fish is not supported.     

Decline of Pseudodiaptomus hessei (Copepoda, Calanoida) in two water bodies located in the Senegal River hydrosystem (West Africa): Hypotheses and perspectives

Pseudodiaptomus hessei is a key species in many water bodies in the Senegal River hydrosystem but it became rare or completely disappeared from two ecosystems (Lake Guiers and Dakar Bango Reservoir; Senegal, West Africa) after major hydrological changes caused by human action, mainly impoundments on the river in 1985, and the opening of a new estuary mouth in 2003. Kâ et al. [Kâ, S., Pagano, M., Ba, N., Bouvy, M., Leboulanger, C., Arfi, R., Thiaw, O.T., Ndour, E.H.M., Corbin, D., Defaye, D., Cuoc, C., Kouassi, E., 2006. Zooplankton distribution related to environmental factors and phytoplankton in a shallow tropical lake (Lake Guiers, Senegal, West Africa). International Review of Hydrobiology 91(5), 389–405] put forward several hypotheses to explain the reasons for this decline: salinity and chemical changes in the water, predation by a cyclopid predator Mesocyclops ogunnus and/or the inhibiting effects of cyanobacteria and/or diatoms (allelopathy). This study assessed these hypotheses by studying the distribution of P. hessei in 13 stations (including the Dakar Bango reservoir and Lake Guiers) in relation to physical, chemical and biological (phyto- and zooplanktons) factors at each station. We produced a distribution pattern for this species in the Senegal River hydrosystem. Rank correlations and principal component analysis showed that P. hessei was not correlated with conductivity but was positively correlated with pH and alkalinity, suggesting chemical effects. The clear association with two filamentous cyanobacteria (Cylindrospermopsis raciborskii and Anabaena sp.) did not appear to support the hypothesis of cyanobacteria inhibition but blooming conditions were never encountered during the study. Negative correlation with diatoms (especially with Fragilaria sp.) suggested that aldehyde producing diatoms had a negative effect. Negative correlations with cyclopids such as Mesocyclops supported the hypothesis of cyclopid predation to explain the decline of P. hessei. This study proposes several lines of research for future studies to test these hypotheses.     

Molluscan assemblages of seagrass-covered and bare intertidal flats on the Banc d'Arguin, Mauritania, in relation to characteristics of sediment and organic matter

The Banc d'Arguin, a non-estuarine area of shallows and intertidal flats off the tropical Saharan coast of Mauritania, is characterised by extensive intertidal and subtidal seagrass beds. We examined the characteristics of intertidal seagrass (Zostera noltii) meadows and bare areas in terms of the presence and abundance of molluscs (gastropods and bivalves). To explain observed differences between molluscan assemblages in seagrass and bare patches, some aspects of the feeding habitat (top-5 mm of the sediment) and of food (organic materials) of molluscs were examined. The novelty of this study is that phytopigments were measured and identified to assess source and level of decay (freshness) of organic material in the sediment and to study their importance as an explanatory variable for the distribution of molluscs. Over an area of 36 km² of intertidal flats, at 12 sites, paired comparisons were made between seagrass-covered and nearby bare patches. Within seagrass meadows, dry mass of living seagrass was large and amounted to 180 ±10 g AFDM m^− 2 (range 75–240). Containing twice the amount of silt per unit dry sediment mass, seagrass sediments were muddier than bare areas; the relative amount of organic material was also larger. The total number of species of bivalves and gastropods amounted to 27, 14 of which were found only in seagrass areas, 4 only in bare and 9 in both types of habitat. Among the three numerically most abundant species, the bivalves Anadara senilis, Dosinia hepatica and Loripes lacteus, the first was numerically most abundant in bare and the other two in seagrass-covered areas. Bare intertidal areas had greater mean total biomass of molluscs (80.5 g AFDM m^− 2) than seagrass meadows (30.0 g AFDM m^− 2). In both habitats, the bulk of the biomass was made up by A. senilis. Excluding this species, bare mudflats contained on average only 3.1 g AFDM m^− 2 and seagrass meadows 6.9 g AFDM m^− 2. As compared to previous surveys in 1980–1986, the biomass of A. senilis had increased almost 10-fold and D. hepatica, previously found in very small numbers, had become the most numerous species. However, the total biomass excluding that of A. senilis was similar. Concentrations of phytopigments were similar to those observed at temperate mudflats, indicating that the Banc d'Arguin might not be as oligotrophic as previously thought. Per unit of dry sediment mass, smaller amounts of phytopigments were found in bare than in seagrass areas. Per unit of dry organic material, bare sediments contained most (fresh) phytopigments. This suggests that in seagrass-covered meadows the organic material is more degraded than in bare sediments. Overall, the composition of phytopigments, quite surprisingly, indicated a benthic-diatom-dominated trophic system. Multivariate statistics revealed that patterns of zoobenthic assemblages were correlated with patterns of a combination of four environmental parameters: grain size of the sediment, amount of fresh phytopigments and amounts of leaves and roots of seagrass.