Noble gas isotopic systematics of Fe-Ti-V oxide ore-related mafic-ultramafic layered intrusions in the Panxi area, China: The role of recycled oceanic crust in their petrogenesis

Olivine and clinopyroxene grains have been separated from four large Fe-Ti-V oxide ore-bearing intrusions (Panzhihua, Hongge, Baima and Taihe) in the Panxi area, Emeishan large igneous province, Southwest China, for He and Ar isotope studies. The samples examined revealed extremely low ³He/⁴He ratios (0.078-4.34 Ra with the mean value 0.78 Ra) for gases extracted by stepwise heating. This feature, combined with low ⁴⁰Ar/³⁶Ar ratios can be interpreted as due to addition of subduction-related fluids and melts that had been stored in the lithospheric mantle for long periods. Considering the regional geologic history, such addition can be attributed to the paleo subduction that occurred along the western margin of the Yangtze Block during the Neoproterozoic. The subducted oceanic crust beneath the Panxi area underwent eclogite-facies metamorphism and subsequent exhumation. The infiltration of subduction-related melts and fluids into the lithospheric mantle led to enriched isotopic signatures from that of the slightly depleted asthenopheric mantle which has been suggested by the Sr, Nd and Pb isotopic data of the Emeishan basalts and picrites. In addition, considerable amounts of eclogitic melts produced by partial melting of eclogite-facies oceanic crust extensively contaminated the lithospheric mantle. During the late Permian, partial melting of an upwelling mantle plume that contained an eclogite or pyroxenite component generated the parental Fe-rich magma that supplied the ore-bearing intrusions. The combination of these factors may have been the crucial reason that many world-class Fe-Ti-V oxides deposits are clustered in the Panxi area.     

Active Deformation along the Southern End of the Tosco-Abreojos Fault System: New Insights from Multibeam Swath Bathymetry

The relative motion of the Pacific plate with respect to the North America plate is partitioned between transcurrent faults located along the western margin of Baja California and transform faults and spreading ridges in the Gulf of California. However, the amount of right lateral offset along the Baja California western margin is still debated. We revisited multibeam swath bathymetry data along the southern end of the Tosco-Abreojos fault system. In this area the depths are less than 1,000?m and allow a finer gridding at 60?m cell spacing. This improved resolution unveils several transcurrent right lateral faults offsetting the seafloor and canyons, which can be used as markers to quantify local offsets. The seafloor of the southern end of the Tosco-Abreojos fault system (south of 24°N) displays NW?CSE elongated bathymetric highs and lows, suggesting a transtensional tectonic regime associated with the formation of pull-apart basins. In such an active tectonic context, submarine canyon networks are unstable. Using the deformation rate inferred from kinematic predictions and pull-apart geometry, we suggest a minimum age for the reorganization of the canyon network.     

Reconstruction of Late-Quaternary sea- and lake-level changes in a tectonically active marginal basin using seismic stratigraphy: The Gulf of Cariaco,NE Venezuela

The Gulf of Cariaco is a marginal basin located between the Cariaco Basin and the Paria Gulf, offshore NE Venezuela, along a system of active right-lateral strike-slip faults. It is connected to the Caribbean Sea via a shallow 58-m-deep sill implying that the gulf was disconnected from the global ocean during eustatic lowstands. A dense grid of high-resolution reflection seismic profiles has been used to determine the overall tectonic structure of the gulf and to establish the seismic stratigraphy of its sedimentary infill. Six unconformity-bounded seismic–stratigraphic units were identified in the upper ~ 200 m of the sedimentary infill. Detailed seismic–stratigraphic and seismic-facies analysis allowed defining a series of sedimentary features that can be used as indicators of past sea or lake level in the Gulf of Cariaco: i) delta offlap breaks, ii) evaporites, and iii) erosional unconformities. Using accurate measurements of these various indicators at several locations in the gulf and a simple total subsidence model, a relative sea/lake-level history encompassing the last 130 kyr could be reconstructed. In periods of connection with the open ocean, reconstructed relative sea level correlates well with eustatic sea level. In times of disconnection, distinct lake-level fluctuations occurred, which sometimes resulted in total dessication of the gulf. Lake-level fluctuations appear to correlate with major Heinrich Events, stadials and interstadials. MIS 4, the LGM and the Younger Dryas were thus identified in the Gulf of Cariaco sedimentary record. The last reconnection to the Caribbean Sea occurred during MWP1b (around 11.5 kyr). The very good fit of the Cariaco sea/lake-level curve with the eustatic sea-level curves (both in terms of amplitude and of timing) underscores potential for future paleoclimate research of the sedimentary record contained in this marginal basin, despite its active tectonic setting.     

Vegetative reproduction by multicellular propagules in Rhodophyta: an overview

This paper deals with vegetative reproduction by multicellular propagules in Rhodophyta. An extensive examination of the relevant literature shows that this phenomenon in Rhodophyta is not well known. A propagule is here defined as a vegetative multicellular structure which spontaneously detaches from the parent thallus and gives rise to a new individual. The origin and morphological features of multicellular propagules are examined in the various known propagule‐forming species. The importance of multicellular propagules as both overwintering and resting organs and as a taxonomic feature is also shown. Their role in increasing local populations and/or for long‐distance dispersal is discussed. The relative abundance of vegetative reproduction by multicellular propagules versus sexual reproduction, as well as the advantages of this additional mode of reproduction, are shown and discussed. The production of multicellular propagules may contribute to the capacity of species to increase populations, to weather unpredictable environmental changes, to survive in conditions that would be lethal for entire thalli, and to reach new habitats. As resting organs, they may also be responsible for long‐distance dispersal and may account for the introduction of some alien species. Accordingly, propagule‐forming species are probably more competitive than taxa that do not produce such propagules. These considerations should be taken into account in future studies of the biology, ecology and demography of Rhodophyta.     

Composition and structural aspects of naturally occurring ferrihydrite

A series of naturally occurring ferrihydrites sampled from an acid mine drainage environment were characterized and compared with synthetic 2-line ferrihydrite using high energy X-ray total scattering and pair distribution function analysis, Scanning Transmission X-ray Microscopy (STXM), Transmission Electron Microscopy (TEM), BET N₂ surface area measurements, and chemical extractions in order to place constraints on their structural and physical properties as a function of composition. Overall, the short- and intermediate-range ordering of the natural samples is comparable to synthetic ferrihydrite. However, with increasing Al, Si, and organic matter contents, a decrease in particle size and an increase in structural disorder were observed. Silica is suspected to have a pronounced effect on the crystallinity of ferrihydrite as a result of its inhibitory effect on Fe polymerization and particle growth, and it is likely complexed at the surfaces of ferrihydrite nanoparticles. Aluminum, on the other hand may substitute for Fe³⁺ in natural ferrihydrite. Organic matter is pervasive and intimately associated with ferrihydrite aggregates, and its presence during ferrihydrite precipitation may have contributed to additional structural disorder. The increase in impurity content affects not only the particle size and structural order of ferrihydrite but may also have a significant effect on its surface reactivity.     

Investigation of groundwater mineralization in the Hammamet–Nabeul unconfined aquifer,north-eastern Tunisia: geochemical and isotopic approach

Detailed hydrogeochemical and isotopic data of groundwaters from the Hammamet–Nabeul unconfined aquifer are used to provide a better understanding of the natural and anthropogenic processes that control the groundwater mineralization as well as the sources of different groundwater bodies. It has been demonstrated that groundwaters, which show Na–Cl and Ca–SO₄–Cl water facies, are mainly influenced by the dissolution of evaporates, the dedolomitization and the cation-exchange process; and supplementary by anthropogenic process in relation with return flow of irrigation waters. The isotopic signatures permit to classify the studied groundwaters into two different groups. Non-evaporated groundwaters that are characterized by depleted δ ¹⁸O and δ ²H contents highlighting the importance of modern recharge at higher altitude. Evaporated groundwaters with enriched contents reflecting the significance infiltration of return flow irrigation waters. Tritium data in the studied groundwaters lend support to the existence of pre-1950 and post-1960 recharge. Carbon-14 activities in shallow wells that provide evidence to the large contamination by organic ¹⁴C corroborate the recent origin of the groundwaters in the study area.     

Base flow hydrology and water quality of an Ozarks spring and associated recharge area,southern Missouri,USA

Human activities in the karst Ozark Plateaus can impact water quality of springs where surface water is rapidly transferred to subsurface conduits. Bennett Spring, in southern Missouri, is the fourth largest spring in the state and supports local tourism activities. Questions regarding poorly functioning on-site wastewater systems (OWS) have raised concerns over the long-term water quality of the spring. This study reports the results of a surface water quality monitoring program in the recharge area where monthly samples were collected at base flow to identify potential pollution sources to the spring. Base flow hydrology of the recharge area was highly variable over the study period, which was drier than normal, causing an incomplete sampling record due to no flow conditions at some sites. For most of the year, nutrient levels were less than the eutrophic threshold (ET) of 0.075 mg/l total phosphorus (TP) and 1.5 mg/l total nitrogen (TN). Sites that consistently displayed concentrations of TP and TN higher than the ET were influenced by wastewater treatment plants (WTP) or OWS. Sites with nutrient concentrations above the ET were likely influenced by the re-release of nonpoint source related TP and TN delivered to streams during storm events. Water quality and discharge at the spring outlet remained consistent over the sampling period suggesting diffuse recharge from a deep aquifer source is able to dilute shallow ground water sources carrying nonpoint pollutants at base flow. Historical and regional data comparisons show these trends have been consistent over at least the last two decades.     

Use of inhibitors for coastal bacteria and phytoplankton: Application to nitrogen uptake measurement

For several decades, prokaryotic and eukaryotic inhibitors have been used to exclude bacteria from microalgal cultures and for investigating prey-predator relationships. Recently there has been considerable interest in using specific inhibitors for studying the interactions between bacteria and phytoplankton, by selective repression of either organism’s activity. The effectiveness of chemical inhibitors must be tested before applying them to natural communities to partition metabolic activities between functional groups. Six different antibiotics selected from the most commonly reported in the literature were tested, at concentrations varying from 12.5 to 100 mg L⁻¹, for their effect on bacterial growth and functional diversity of natural communities from Mediterranean coastal waters. Penicillin and streptomycin each at a final concentration of 100 mg L⁻¹ significantly reduced bacterial growth within 2 h. There was a greater impact on bacterial functional diversity when both antibiotics were mixed together. This mixture did not have any significant effect on the growth of selected cultured phytoplankton strains, whereas the eukaryote inhibitor cycloheximide at 100 mg L⁻¹ reduced growth within 2 h of incubation. The penicillin–streptomycin mixture and cycloheximide alone successfully partitioned NH₄⁺ and NO₃⁻ uptake between bacteria and phytoplankton bi-weekly sampled in a coastal lagoon in Autumn, where bacterial contribution to total NH₄⁺ and NO₃⁻ uptake averaged 46 and 41%, respectively. The use of specific inhibitors may be a valuable method for studying interactions, such as competition and mutualism, or lack of interaction between the different components of microbial communities and could be used to study their relative importance in biogeochemical fluxes.     

A noble gas and cosmogenic radionuclide analysis of two ordinary chondrites from Almahata Sitta

Abstract– We present the results of a noble gas (He, Ne, Ar) and cosmogenic radionuclide (¹⁰Be, ²⁶Al, ³⁶Cl) analysis of two chondritic fragments (#A100, L4 and #25, H5) found in the Almahata Sitta strewn field in Sudan. We confirm their earlier attribution to the same fall as the ureilites dominating the strewn field, based on the following findings: (1) both chondrite samples indicate a preatmospheric radius of approximately 300 g cm^?2, consistent with the preatmospheric size of asteroid 2008 TC₃ that produced the Almahata Sitta strewn field; (2) both have, within error, a ²¹Ne/²⁶Al‐based cosmic ray exposure age of approximately 20 Ma, identical to the reported ages of Almahata Sitta ureilites; (3) both exhibit hints of ureilitic Ar in the trapped component. We discuss a possible earlier irradiation phase for the two fragments of approximately 10–20 Ma, visible only in cosmogenic ³⁸Ar. We also discuss the approximately 3.8 Ga (⁴He) and approximately 4.6 Ga (⁴⁰Ar) gas retention ages, measured in both chondritic fragments. These imply that the two chondrite fragments were incorporated into the ureilite host early in solar system evolution, and that the parent asteroid from which 2008 TC₃ is derived has not experienced a large break‐up event in the last 3.8 Ga.