A Comparative Study of Five Reference Materials and the Lombard Meteorite for the Determination of the Platinum‐Group Elements and Gold by LA‐ICP‐MS

A range of independently characterised reference materials (RMs) for LA‐ICP‐MS, used for the determination of the platinum‐group elements (PGE) and Au in a sulfide matrix, were analysed and compared: 8b, PGE‐A, NiS‐3, Po727‐T1, Po724‐T and the Lombard meteorite. The newly developed RM NiS‐3 was used as the RM for the calibration of all LA‐ICP‐MS analyses and the measured concentrations of the other RMs compared against their published concentrations. This data were also used to assess the consistency of concentrations calibrated against the different RMs. It was found that Po727‐T1 and 8b produced results that were comparable, within uncertainty, for all elements. Po727‐T1 also produced consistent results with NiS‐3 for all elements. All other RMs showed differences for some elements, especially Ru in Po724‐T, and Os, Ir and Au in PGE‐A. The homogeneity of the PGE and Au in each RM was assessed, by comparing the precision of multiple LA‐ICP‐MS spot analyses with the average uncertainty of the signal. Po724‐T, Po727‐T1 and the Lombard meteorite were found to be homogeneous for all elements, but 8b, PGE‐A and NiS‐3 were heterogeneous for some elements. This is the first direct comparison between a range of independently characterised PGE and Au LA‐ICP‐MS RMs.     

Canadian gravimetric geoid model 2010

A new gravimetric geoid model, Canadian Gravimetric Geoid 2010 (CGG2010), has been developed to upgrade the previous geoid model CGG2005. CGG2010 represents the separation between the reference ellipsoid of GRS80 and the Earth’s equipotential surface of $W_0=62{,}636{,}855.69~\mathrm{m}^2\mathrm{s}^{-2}$ W 0 = 62 , 636 , 855.69 m 2 s ? 2 . The Stokes–Helmert method has been re-formulated for the determination of CGG2010 by a new Stokes kernel modification. It reduces the effect of the systematic error in the Canadian terrestrial gravity data on the geoid to the level below 2 cm from about 20 cm using other existing modification techniques, and renders a smooth spectral combination of the satellite and terrestrial gravity data. The long wavelength components of CGG2010 include the GOCE contribution contained in a combined GRACE and GOCE geopotential model: GOCO01S, which ranges from $-20.1$ ? 20.1 to 16.7 cm with an RMS of 2.9 cm. Improvement has been also achieved through the refinement of geoid modelling procedure and the use of new data. (1) The downward continuation effect has been accounted accurately ranging from $-22.1$ ? 22.1 to 16.5 cm with an RMS of 0.9 cm. (2) The geoid residual from the Stokes integral is reduced to 4 cm in RMS by the use of an ultra-high degree spherical harmonic representation of global elevation model for deriving the reference Helmert field in conjunction with a derived global geopotential model. (3) The Canadian gravimetric geoid model is published for the first time with associated error estimates. In addition, CGG2010 includes the new marine gravity data, ArcGP gravity grids, and the new Canadian Digital Elevation Data (CDED) 1:50K. CGG2010 is compared to GPS-levelling data in Canada. The standard deviations are estimated to vary from 2 to 10 cm with the largest error in the mountainous areas of western Canada. We demonstrate its improvement over the previous models CGG2005 and EGM2008.     

Collagen fingerprinting for the species identification of archaeological amphibian remains

Amphibians are well known as being one of the main groups of animals today most threatened by environmental changes but they are also some of the least well understood of all terrestrial vertebrates. This gap in knowledge is much greater as we look further back into the relatively recent past, despite representing an invaluable resources in archaeological and palaeontological assemblages that are more indicative of palaeoclimate conditions than most other vertebrate taxa. This in part stems from their remains being typically much less studied, partly due to the less common forms of expertise required for identifications based on skeletal morphology – the most frequently observed tissue that remains in ancient assemblages. Here we apply a method of biomolecular species identification by collagen peptide mass fingerprinting to the British Late Pleistocene assemblage of Pin Hole Cave (Creswell Crags, UK) as well as a range of relevant extant taxa for comparison. Our results demonstrate the ability to separate at the species level with all modern taxa investigated, allowing for the identification of these archaeological remains to the amphibian taxa known to exist in Late Pleistocene Britain. Analyses of the Pin Hole assemblage found a dominance of the two species previously known from the site (common frogs and toads: Rana temporaria and Bufo bufo, respectively) and also a small number of the rarer natterjack toad (Epidalea calamita) not previously identified in the Creswell Crags region but known from other sites in the UK; additionally, one specimen appeared to yield the fingerprint of the moor frog (R. arvalis), now extinct in the UK. As such, collagen fingerprinting is here shown to widen the known palaeobiodiversity of taxa, and highlights the further potential to enhance our understanding of climate change in the past.     

Modelling of Tsunami Propagation in the Vicinity of the French Coast of the Mediterranean

The problem of tsunami-risk for the French coast of the Mediterraneanis discussed. Historical data of tsunami manifestation on the French coast are described and analysed.Numerical simulation of potential tsunamis in the Ligurian Sea is done and the tsunami wave heightdistribution along the French coast is calculated. For the earthquake magnitude 6.8 (typical value forMediterranean) the tsunami phenomenon has a very local character. It is shown that the tsunami tide-gaugerecords in the vicinity of Cannes–Imperia present irregularoscillations with characteristic periodof 20–30 min and total duration of 10–20h.Tsunami propagating from the Ligurian sea to the west coastof France have significantly lesser amplitudes and they are more low-frequency (period of 40–50min).The effect of far tsunamis generated in the southern Italy and Algerian coast is studied also, thedistribution of the amplitudes along the French coast for far tsunamis is more uniform.     

Establishing constraints on groundwater ages with Cl,C, H,and noble gases: A case study in the eastern Paris basin,France

Groundwaters from the Tithonian/Kimmeridgian, Oxfordian and Upper Dogger aquifers, within the eastern part of the Paris basin (France), were characterised using ³H, ¹⁴C and ³⁶Cl, and noble gases tracers, to evaluate their residence times and determine their recharge period. This information is an important prerequisite to evaluating the confinement properties of the Callovo-Oxfordian clay formation sandwiched between the Oxfordian aquifer and the Dogger aquifer, currently being investigated by the French nuclear waste management agency (Andra) for radioactive waste disposal. Data presented in this paper are used to test 4 hypotheses.     

Fluidization of buried mass-wasting deposits in lake sediments and its relevance for paleoseismology: Results from a reflection seismic study of lakes Villarrica and Calafquén (South-Central Chile)

A dense grid of very-high resolution seismic profiles on Lake Villarrica provides a quasi-3D view on intercalated lenses of low-amplitude reflections, which are connected by acoustic wipe-out patches and fractures to an underlying voluminous mass-wasting deposit. The lenses are interpreted as being created by earthquake-triggered liquefaction in this buried mass-wasting deposit and subsequent sediment fluidization and extrusion at the paleo-lake bottom. These sediment volcanoes are mapped in detail. They have a rather uniform circular geometry and show a linear relationship between apparent width and maximum thickness on a seismic section. The largest sediment volcanoes are up to 80 m wide and 1.9 m thick. Their slope angles designate a syn- to post-depositional sagging of most sediment volcanoes. Sediment volcano detection and mapping from nearby Lake Calafquén further strengthen the revealed geometrical relationships. Locally, some of the sediment/fluid escape structures extend to a higher position in the stratigraphy, which points to a polyphase escape process associated with multiple multi-century spaced strong earthquakes. Thickness and morphology of the source layer seem to exert a dominant control in the production of sediment/fluid extrusions. This study shows that reflection seismic profiling allowed recognizing 4 different seismic events in the studied stratigraphic interval, which are evidenced by mass-wasting deposits and/or fluidization features.     

An experimental study of Fe–Ni exchange between sulfide melt and olivine at upper mantle conditions: implications for mantle sulfide compositions and phase equilibria

The behavior of nickel in the Earth’s mantle is controlled by sulfide melt–olivine reaction. Prior to this study, experiments were carried out at low pressures with narrow range of Ni/Fe in sulfide melt. As the mantle becomes more reduced with depth, experiments at comparable conditions provide an assessment of the effect of pressure at low-oxygen fugacity conditions. In this study, we constrain the Fe–Ni composition of molten sulfide in the Earth’s upper mantle via sulfide melt–olivine reaction experiments at 2 GPa, 1200 and 1400 °C, with sulfide melt \(X_{{{\text{Ni}}}}^{{{\text{Sulfide}}}}=\frac{{{\text{Ni}}}}{{{\text{Ni}}+{\text{Fe}}}}\) (atomic ratio) ranging from 0 to 0.94. To verify the approach to equilibrium and to explore the effect of \({f_{{{\text{O}}_{\text{2}}}}}\) on Fe–Ni exchange between phases, four different suites of experiments were conducted, varying in their experimental geometry and initial composition. Effects of Ni secondary fluorescence on olivine analyses were corrected using the PENELOPE algorithm (Baró et al., Nucl Instrum Methods Phys Res B 100:31–46, 1995), “zero time” experiments, and measurements before and after dissolution of surrounding sulfides. Oxygen fugacities in the experiments, estimated from the measured O contents of sulfide melts and from the compositions of coexisting olivines, were 3.0?±?1.0 log units more reduced than the fayalite–magnetite-quartz (FMQ) buffer (suite 1, 2 and 3), and FMQ ??1 or more oxidized (suite 4). For the reduced (suites 1–3) experiments, Fe–Ni distribution coefficients \(K_{{\text{D}}}^{{}}=\frac{{(X_{{{\text{Ni}}}}^{{{\text{sulfide}}}}/X_{{{\text{Fe}}}}^{{{\text{sulfide}}}})}}{{(X_{{{\text{Ni}}}}^{{{\text{olivine}}}}/X_{{{\text{Fe}}}}^{{{\text{olivine}}}})}}\) are small, averaging 10.0?±?5.7, with little variation as a function of total Ni content. More oxidized experiments (suite 4) give larger values of K_D (21.1–25.2). Compared to previous determinations at 100 kPa, values of K_D from this study are chiefly lower, in large part owing to the more reduced conditions of the experiments. The observed difference does not seem attributable to differences in temperature and pressure between experimental studies. It may be related in part to the effects of metal/sulfur ratio in sulfide melt. Application of these results to the composition of molten sulfide in peridotite indicates that compositions are intermediate in composition (\(X_{{{\text{Ni}}}}^{{{\text{sulfide}}}}\)?~?0.4–0.6) in the shallow mantle at 50 km, becomes more Ni rich with depth as the O content of the melt diminishes, reaching a maximum (0.6–0.7) at depths near 80–120 km, and then becomes more Fe rich in the deeper mantle where conditions are more reduced, approaching (\(X_{{{\text{Ni}}}}^{{{\text{sulfide}}}}\)?~?0.28)?>?140 km depth. Because Ni-rich sulfide in the shallow upper mantle melts at lower temperature than more Fe-rich compositions, mantle sulfide is likely molten in much of the deep continental lithosphere, including regions of diamond formation.     

Considérations sur le volcanisme post-ophiolitique dans les Alpes occidentales

Résumé L'activité magmatique ophiolitique du géosynclinal alpin (diabases, gabbros, serpentines, etc.) a été suivie par une activité à caractère volcanique moins bien connue. En effet, les appareils correspondant à cette activité ont complètement disparu; nous devons nous contenter pour tous renseignements de l'étude des fragments de roches contenus dans des grauwackes tertiaires appartenant au Flysch (grès de Taveyanne, grès d'AItdorf pro parte, grès du Champsaur).La détermination de la nature originelle des laves est, en outre, rendue difficile par le fait, découvert récemment, que ces grauwackes ont subi un métamorphisme régional les plaçant dans le faciès à zéolites; on peut raisonnablement admettre qu'il s'agissait d'andésites basaltiques.L'áge des épanchements est encore indéterminé, il doit être compris entre le Crétacé supérieur et la fin de l'Eocène. L'hypothèse la plus plausible consiste à admettre que les volcans, aujourd'hui complètement érodés se trouvaient dans la partie la plus interne du domaine pennique. Toutefois au moment du dépôt des grès de Taveyanne, les coulées ne se trouvaient plus dans leur position initiale, elles avaient glissé vers l'avant-pays sous forme d'une nappe.Il est très probable que cette activité volcanique post-ophiolitique n'est pas restreinte au segment franco-suisse des Alpes occidentales mais que des formations analogues aux grès de Taveyanne se retrouvent ailleurs, notamment en Sicile et dans les Apennins.

---

The magmatic activity which gave birth to the ophiolites (diabases, gabbros, serpentinites) of the alpine geosyncline was followed by subaerial volcanism. This volcanic activity is not well known as the volcanoes were completely destroyed by erosion. Our only source of information is to be found in fragments of volcanic rocks which are part of Tertiary Flysch graywackes (Taveyanne sandstones, part of the Altorf sandstones, Champsaur sandstones).The determination of the initial composition of the lavas is further complicated by metasomatic transformations; it has been recently shown that the Taveyanne graywackes were submitted to a light regional metamorphism corresponding to the zeolitic facies ofCoombs. However, it seems that these lavas were originally basaltic andesites.The age of this volcanism is not precisely known, it cannot be later than Upper Eocene as the time of deposition of the Taveyanne sandstones is Uppermost Eocene-Lower Oligocene; it is probably post-Cenomanian. It is likely that the volcanoes were located in the southern part of the Penninic zone; however at the time of deposition of the graywackes the volcanic flows had already left their initial location, gliding toward the Foreland as part of a Nappe.Very probably, remnants of this post-ophiolitic volcanism are not restricted to the French-Swiss segment of the Western Alps, but will be found elsewhere, particularly in the Apennine Mountains and in Sicily.

---

Zusammenfassung Die magmatische Tätigkeit, die Ophiolithe (Diabase, Gabbros, Serpentinite) der alpinen Geosynklinale entstehen ließ, wurde von subärischem Vulkanismus abgelöst. Diese Vulkantätigkeit ist wenig bekannt, da die Vulkane durch Erosion völlig zerstört wurden. Unsere einzige Informationsquelle findet sich in vulkanischen Gesteinsfragmenten, die Bestandteile der Tertiär-Flysch-Grauwacken sind.Die Bestimmung der ursprünglichen Zusammensetzung der Laven wird weiter durch metasomatische Umwandlungen erschwert. Kürzlich wurde gezeigt, daß die Taveyanne-Grauwacken einem regionalen Metamorphismus ausgesetzt waren, welcher der zeolithischen Fazies von Coombs entspricht. Es scheint jedoch, daß diese Laven ursprünglich basaltische Andésite waren.Das Alter dieses Vulkanismus ist nicht genau bekannt; es kann aber nicht später sein als das Obere Eozän, da die Ablagerungszeit der Taveyanne-Sandsteine Oberstes Eozän—Unteres Oligozän ist. Wahrscheinlich lagen die Vulkane im südlichen Teil der penninischen Zone; zur Zeit der Ablagerung der Grauwacken waren die Vulkanite bereits in die Überschiebungsmassen mit einbezogen.Sehr wahrscheinlich sind die Überreste dieses nach-ophiolithischen Vulkanismus nicht auf den französisch-schweizerischen Abschnitt der Westalpen beschränkt, sondern werden sich auch andernorts speziell auf dem Apennin und in Sizilien finden lassen.

---

, (, ) , . , . , . . , Taveyane ( Coombs'y), , . .

     

Contribution of geophysical surveys to groundwater modelling of a porous aquifer in semiarid Niger: An overview

Subsurface geophysical surveys were carried out using a large range of methods in an unconfined sandstone aquifer in semiarid south-western Niger for improving both the conceptual model of water flow through the unsaturated zone and the parameterization of numerical a groundwater model of the aquifer. Methods included: electromagnetic mapping, electrical resistivity tomography (ERT), resistivity logging, time domain electromagnetic sounding (TDEM), and magnetic resonance sounding (MRS). Analyses of electrical conductivities, complemented by geochemical measurements, allowed us to identify preferential pathways for infiltration and drainage beneath gullies and alluvial fans. The mean water content estimated by MRS (13%) was used for computing the regional groundwater recharge from long-term change in the water table. The ranges in permeability and water content obtained with MRS allowed a reduction of the degree of freedom of aquifer parameters used in groundwater modelling.