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891.
Eluvial concentration of platinum-group minerals (PGM) has developed in the south of New Caledonia, from the weathering of a mafic and ultramafic cumulate. The platinum/palladium (Pt/Pd) ratio evolution from the bottom to the top of the weathering profile indicates a chemical mobilization of Pd in supergene environment. The examination by scanning electron microscopy of the residual PGM collected in the weathering profile and their chemical characterization by electronic microprobe show a preservation of the structure and chemical signature (in the core of the grains) of the fresh PGM. This clearly demonstrates that the PGM studied here are residual and are affected by dissolution process.  相似文献   
892.
Airborne gamma-ray spectrometry data (uranium, potassium and thorium contents) reveal geochemical heterogeneities within the monolithological Hyrôme watershed (ca. 150 km2) in the Armorican massif (western France). Our observations and computations provide important constraints on the spatial distribution and the associated magnitudes of chemical erosion processes at the scale of a small watershed. Two distinct, partially preserved, weathering profiles exhibit a strong correlation between regolith evolution and airborne-derived K/Th ratios, suggesting that the variability is linked to supergene processes. Using both airborne data and laboratory measurements on rock samples, the total net export of potassium has been estimated at 422 ± 50 kg/m2 and the chemical weathering rate of potassium at 17 ± 2 kg/km2/a.  相似文献   
893.
In waterlogged soils, dynamics of water influence the redox conditions and thus the mobility of elements. Irrigation of rice in Camargue (South eastern France) induces yearly dynamics of water. In order to determine the impact of irrigation on the geochemical properties of ground waters, a continuously in situ record of physico-chemical parameters (pH, Eh, temperature and electric conductivity) is performed during 1 year in an irrigated rice field. Seasonal dynamics show large Eh and pH variations. An annual irrigation cycle generates fast precipitations of Ca–Mg carbonates and Fe oxides between 50 and 110 cm depth when the soil is waterlogged. The dissolution of these minerals is initiated during a year without irrigation.  相似文献   
894.
895.
896.
897.
An ephemeral estuarine turbidity maximum (ETM) occurs at high water in the macrotidal Taf estuary (SW Wales, United Kingdom). A new mechanism of ETM formation, due to resuspension and advection of material by flood tidal currents, is observed that differs from classical mechanisms of gravitational circulation and tidal pumping. The flood tide advances across intertidal sand flats in the main body of the estuary, progressively entraining material from the rippled sands. Resuspension creates, a turbid front that has suspended sediment concentrations (SSC) of about 4,000 mg I−1 by the time it reaches its landward limit which is also the landward limit of salt penetration. This turbid body constitutes the ETM. Deposition occurs at high slack water but the ETM retains SSC values up to 800 mg I−1, 1–2 orders of magnitude greater than ambient SSC values in the river and estuarine waters on either side. The ETM retreats down the estuary during the ebb; some material is deposited thinly across emergent intertidal flats and some is flushed out of the estuary. A new ETM is generated by the next flood tide. Both location and SSC of the ETM scale on Q/R3 where Q is tidal range and R is river discharge. The greatest expression of the ETM occurs when a spring tide coincides with low river discharge. It does not form during high river discharge conditions and is poorly developed on neap tides. Particles in the ETM have effective densities (120–160 kg m−3) that are 3–4 times less than those in the main part of the estuary at high water. High chlorophyll concentrations in the ETM suggest that flocs probably originate from biological production in the estuary, including production on the intertidal sand flats.  相似文献   
898.
Integration of fluid inclusion analysis with high spatial resolution Ar–Ar dating of K-feldspar cements has been used to resolve and reconstruct palaeo-fluid flow. Fluid inclusion analysis allows discrimination of distinct cement phases, thereby identifying discrete episodes of fluid flow. Ar–Ar dating of the same cements via high spatial resolution laserprobe establishes absolute age constraints on the framework previously constructed. Integration of these two datasets yields temperature–composition–time data.  相似文献   
899.
Stable isotopes were used to constrain the origin of CO2 involved in the ageing process of municipal solid waste incineration (MSWI) bottom ash under open-air conditions. The δ13C and δ18O values of CaCO3 occurring in MSWI bottom ash samples of variable age and the δ13C of the residual organic matter content were measured, and laboratory assessments made of the isotopic fractionation accompanying CaCO3 neo-formation during accelerated carbonation experiments of bottom ash or pure lime with atmospheric or industrial CO2. The results indicate that stable isotopic compositions exhibited by fresh and aged bottom ash samples reflect non-equilibrium processes resembling those described in the carbonation of concrete and mortar. They also lead to conclusions on the prevalent involvement of atmospheric CO2 in the open-air carbonation of MSWI bottom ash.  相似文献   
900.
Backstripping analysis and forward modeling of 162 stratigraphic columns and wells of the Eastern Cordillera (EC), Llanos, and Magdalena Valley shows the Mesozoic Colombian Basin is marked by five lithosphere stretching pulses. Three stretching events are suggested during the Triassic–Jurassic, but additional biostratigraphical data are needed to identify them precisely. The spatial distribution of lithosphere stretching values suggests that small, narrow (<150 km), asymmetric graben basins were located on opposite sides of the paleo-Magdalena–La Salina fault system, which probably was active as a master transtensional or strike-slip fault system. Paleomagnetic data suggesting a significant (at least 10°) northward translation of terranes west of the Bucaramanga fault during the Early Jurassic, and the similarity between the early Mesozoic stratigraphy and tectonic setting of the Payandé terrane with the Late Permian transtensional rift of the Eastern Cordillera of Peru and Bolivia indicate that the areas were adjacent in early Mesozoic times. New geochronological, petrological, stratigraphic, and structural research is necessary to test this hypothesis, including additional paleomagnetic investigations to determine the paleolatitudinal position of the Central Cordillera and adjacent tectonic terranes during the Triassic–Jurassic. Two stretching events are suggested for the Cretaceous: Berriasian–Hauterivian (144–127 Ma) and Aptian–Albian (121–102 Ma). During the Early Cretaceous, marine facies accumulated on an extensional basin system. Shallow-marine sedimentation ended at the end of the Cretaceous due to the accretion of oceanic terranes of the Western Cordillera. In Berriasian–Hauterivian subsidence curves, isopach maps and paleomagnetic data imply a (>180 km) wide, asymmetrical, transtensional half-rift basin existed, divided by the Santander Floresta horst or high. The location of small mafic intrusions coincides with areas of thin crust (crustal stretching factors >1.4) and maximum stretching of the subcrustal lithosphere. During the Aptian–early Albian, the basin extended toward the south in the Upper Magdalena Valley. Differences between crustal and subcrustal stretching values suggest some lowermost crustal decoupling between the crust and subcrustal lithosphere or that increased thermal thinning affected the mantle lithosphere. Late Cretaceous subsidence was mainly driven by lithospheric cooling, water loading, and horizontal compressional stresses generated by collision of oceanic terranes in western Colombia. Triassic transtensional basins were narrow and increased in width during the Triassic and Jurassic. Cretaceous transtensional basins were wider than Triassic–Jurassic basins. During the Mesozoic, the strike-slip component gradually decreased at the expense of the increase of the extensional component, as suggested by paleomagnetic data and lithosphere stretching values. During the Berriasian–Hauterivian, the eastern side of the extensional basin may have developed by reactivation of an older Paleozoic rift system associated with the Guaicáramo fault system. The western side probably developed through reactivation of an earlier normal fault system developed during Triassic–Jurassic transtension. Alternatively, the eastern and western margins of the graben may have developed along older strike-slip faults, which were the boundaries of the accretion of terranes west of the Guaicáramo fault during the Late Triassic and Jurassic. The increasing width of the graben system likely was the result of progressive tensional reactivation of preexisting upper crustal weakness zones. Lateral changes in Mesozoic sediment thickness suggest the reverse or thrust faults that now define the eastern and western borders of the EC were originally normal faults with a strike-slip component that inverted during the Cenozoic Andean orogeny. Thus, the Guaicáramo, La Salina, Bitúima, Magdalena, and Boyacá originally were transtensional faults. Their oblique orientation relative to the Mesozoic magmatic arc of the Central Cordillera may be the result of oblique slip extension during the Cretaceous or inherited from the pre-Mesozoic structural grains. However, not all Mesozoic transtensional faults were inverted.  相似文献   
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