Paleolimnological investigations of anthropogenic environmental change in Lake Tanganyika: VII. Carbonate isotope geochemistry as a record of riverine runoff

Evaporation dominates the removal of water from Lake Tanganyika, and therefore the oxygen isotope composition of lake water has become very positive in comparison to the waters entering the lake. The surface water in Lake Tanganyika has remained relatively unchanged over the last 30 years with a seasonal range of +3.2 to +3.5 VSMOW. Water from small rivers entering the lake seems to have a ¹⁸O value between –3.5 and –4.0, based on scattered measurements. The two largest catchments emptying into the lake deliver water that has a ¹⁸O value between these two extremes. This large contrast is the basis of a model presented here that attempts to reconstruct the history of runoff intensity based on the ¹⁸O of carbonate shells from Lake Tanganyika cores. In order to use biogenic carbonates to monitor changes in the ¹⁸O of mixing-zone water, however, the oxygen isotope fractionation between water and shell carbonate must be well understood. The relatively invariant environmental conditions of the lake allow us to constrain the fractionation of both oxygen and carbon isotope ratios. Although molluskan aragonitic shell ¹⁸O values are in agreement with published mineral-water fractionations, ostracode calcite is 1.2 more positive than that of inorganic calcite precipitated under similar conditions. Ostracode shell ¹⁸O data from two cores from central Lake Tanganyika suggest that runoff decreased in the first half of this millennium and has increased in the last century. This conclusion is poorly constrained, however, and much more work needs to be done on stable isotope variation in both the waters and carbonates of Lake Tanganyika. We also compared the ¹³C of shells against predicted values based solely on the ¹³C of lake water dissolved inorganic carbon (DIC). The ostracode Mecynocypria opaca is the only ostracode or mollusk that falls within the predicted range. This suggests that M. opaca has potential for reconstructing the carbon isotope ratio of DIC in Lake Tanganyika, and may be a useful tool in the study of the history of the lakes productivity and carbon cycle.     

Neoproterozoic–Cambrian synsedimentary magmatism in the Central Iberian Zone (Spain): geology,petrology and geodynamic significance

Petrographic, geochemical and field studies in low grade metamorphic areas (Ciudad Rodrigo-Hurdes-Sierra de Gata domain, CRHSG, central-western Spain) show that Neoproterozoic-Lowermost Cambrian series in the Central Iberian Zone (CIZ) record two kinds of provenance sources including: (1) detrital material derived from recycled orogens and (2) a Cadomian coeval juvenile contribution that governs their isotopic signature. Evidence of magmatism contemporaneous with Neoproterozoic-Cambrian sedimentation is provided by the presence of coherent, massive volcanic rocks (metabasalts, metaandesites, and metarhyolites), volcaniclastic shales, sandstones, conglomerates and breccias. The appearance of volcanogenic lithic fragments and crystals mixed in different proportions with siliciclastic constituents and also present within calcareous components in the sedimentary succession, reinforces this evidence. Although most of the selected volcanic and volcaniclastic samples appear to show tholeiitic affinity, some of them display calc-alkaline affinity. Different trace element ratios, such as Sm/Nd, Nb/Yb and Ta/Yb, suggest a magmatic evolution in the same tectonic setting. The geochemical results reported here support the existence of an active geodynamic setting as a direct contributor to the synsedimentary and magmatic content of the Neoproterozoic–Lowermost Cambrian successions in the CIZ. In particular, the relatively high Nd _(T) values and the high range of f ^Sm/Nd ratios are consistent with an active margin during the Neoproterozoic–Early Cambrian. The existence of tectonic activity is also confirmed by the presence of synsedimentary deformation and volcanic rocks. All of these traits favour a geodynamic model in which the Iberian Cadomian segment represented in the CIZ would have been part of an active northern margin of Gondwana, with an associated magmatic arc and related basins during Neoproterozoic–Lower Cambrian times. A proposed link between the Ossa Morena and the Central Iberian Zones might account for late Cadomian pull-apart basins developed on both sides of the magmatic arc, sharing the same scenario and involving similar magmatic activity during the Neoproterozoic–Cambrian transition.

Reducing greenhouse gas emissions from deforestation and forest degradation in developing countries: revisiting the assumptions

The United Nations Framework on Climate Change (UNFCCC), at its thirteenth meeting in 2005 (COP-11), agreed to start a work program to explore a range of policy approaches and positive incentives for Reducing Emissions from Deforestation and Degradation (REDD). This process was further encouraged in the 2007 COP-13 with the explicit consideration of REDD activities as a means to enhance mitigation action by developing countries in the future. This paper outlines the context of this ongoing political process by reviewing the science indicating that land-use change is a key contributor of greenhouse emissions globally and the assumptions that REDD activities may be competitive—in terms of cost effectiveness—in comparison to other mitigation options. The paper then examines REDD proposals submitted by Parties before COP-13 and identifies key economic, technological, methodological and institutional challenges associated with their implementation. These proposals are discussed in the light of major drivers of deforestation and ongoing efforts to address deforestation. This reveals another set of challenges which, if not taken into account, may undermine REDD effectiveness. The paper aims to aid the policy process and contribute to the best possible design of a REDD framework under the future climate regime.     

Simulated decadal oscillations of the Atlantic meridional overturning circulation in a cold climate state

The significance of the Atlantic meridional overturning circulation (MOC) for regional and hemispheric climate change requires a complete understanding using fully coupled climate models. Here we present a persistent, decadal oscillation in a coupled atmosphere–ocean general circulation model. While the present study is limited by the lack of comparisons with paleo-proxy records, the purpose is to reveal a new theoretically interesting solution found in the fully-coupled climate model. The model exhibits two multi-century-long stable states with one dominated by decadal MOC oscillations. The oscillations involve an interaction between anomalous advective transport of salt and surface density in the North Atlantic subpolar gyre. Their time scale is fundamentally determined by the advection. In addition, there is a link between the MOC oscillations and North Atlantic Oscillation (NAO)-like sea level pressure anomalies. The analysis suggests an interaction between the NAO and an anomalous subpolar gyre circulation in which sea ice near and south of the Labrador Sea plays an important role in generating a large local thermal anomaly and a meridional temperature gradient. The latter induces a positive feedback via synoptic eddy activity in the atmosphere. In addition, the oscillation only appears when the Nordic Sea is completely covered by sea ice in winter, and deep convection is active only near the Irminger Sea. Such conditions are provided by a substantially colder North Atlantic climate than today.     

Influence of olive mill waste application on the role of soil as a carbon source or sink

Organic matter (OM) is involved in the enhancement of soil quality since it acts on soil structure, nutrient storage and biological activity. Organic carbon (OC), the dominant element constituent of OM, and related soil properties are probably the most widely acknowledged indicator of soil quality. The typically Mediterranean climate of the South of Spain promotes low yields on crops and low organic carbon in soil. The present work was carried out to evaluate the effect of the application of alperujo, olive oil waste difficult to eliminate, on the fixation or emission of carbon on soil in an olive grove situated in Montoro (Córdoba, Spain). In the study three treatments were considered: 15 kg (A), 7.5 kg (B), 0 kg (C) of alperujo per tree and the implementation of the amendment has been made for three consecutive years. The results confirm the benefits of the amendment on the carbon content organic soil with a fixation with respect to control of 4.8 and 6.1 t ha^???1 for the first year and 8.7 and 6.8 t ha^???1 for the second in treatments A and B, respectively. Of the different climatic agents considered in the study, it was the temperature which had a major influence on the emissions of CO₂ into the atmosphere and the flow of gas presented the highest values in soils treated with the highest dose.     

Tropical response to the Atlantic Equatorial mode: AGCM multimodel approach

On the frame of the AMMA-EU project, sensitivity experiments for an Atlantic Equatorial mode (AEM) which origin, development and damping resembles the observed one during the last decades of the 20th century, has been analysed in order to investigate the influence on the anomalous summer West African rainfall. Recent studies raise the matter of the AEM influence on the next Pacific ENSO episodes and also on the Indian Monsoon. This paper evaluates the response of four different atmospheric global circulation models, using the above-mentioned AEM sensitivity experiments, to study the tropical forcing associated with the Atlantic Niño mode. The results show a remote signal in both the Pacific and Indian basins. For a warm phase of the AEM the associated southward location of the ITCZ, with rising motions over the Equatorial Atlantic, leads to a global subsidence over the rest of the tropics, weakening the Asian Monsoon and favouring the La Niña conditions in the central Pacific. Although ocean–atmosphere coupled experiments are required to test the latter hypothesis, the present studies shows how the AEM is able to influence the rest of the tropics, a result with important implications on ENSO seasonal predictability.     

Gas kinematics in the halo of the warm ULIRG PKS1345+12

We use long-slit spectra taken with the William Herschel Telescope on La Palma and high-resolution Hubble Space Telescope imaging to study the gas kinematic in the halo of the ultraluminous infrared/radio galaxy PKS1345+12 (z=0.122). Our long-slit spectra show line splitting at the locations of massive star clusters ( $10^{6}<M_{\mathrm{SSC}}^{\mathrm{YSP}}<10^{7}$ M_⊙), indicating that they are moving at up to 450 km?s^?1 with respect to the local ambient gas. Given their kinematics, it is plausible that these super star clusters have been formed either in fast-moving gas streams or tidal tails that are falling back into the nuclear regions as part of the merger process, or as a consequence of jet-induced star formation linked to the extended, diffuse radio emission detected in the halo of the galaxy.     

The Jiddat al Harasis 073 strewn field,Sultanate of Oman

Abstract— The recently discovered Jiddat al Harasis (JaH) 073 strewn field is the largest found so far in the Sultanate of Oman, covering an area of 19 × 6 km. The 3463 single stones collected range in weight from 52.2 kg down to <1 g (total weight 600.8 kg) and show a pronounced mass sorting. The strewn field shape can be approximated by a NW‐SE‐oriented ellipsoid, indicating an atmospheric entry from SE at a low angle relative to the surface. The meteorite belongs to the L6 ordinary chondrite group and shows S4 average shock grade. Smaller stones generally show a higher weathering grade resulting in a spread from W2 and W4. Enhanced weathering of the stones causing fragmentation after the fall is observed in sandy depressions. Five ¹⁴C measurements on stones of variable size and weathering grade yielded ¹⁴C from 3.8 to 49.9 dpm/kg. Three samples give a ¹⁴C/ ¹⁰Be age consistent with about 14.4 ka. For two samples the cosmogenic, trapped, and radiogenic noble gases were measured. The ratio of the ⁴He and ⁴⁰Ar gas retention ages of 0.29 ± 0.10 and that of the ³He and ²¹Ne cosmic ray exposure ages of 0.36 ± 0.08 Ma indicate that JaH 073 experienced a complex exposure history and lost ⁴He and ⁴⁰Ar due to a major collision. Fragmentation statistics indicate a single major atmospheric disruption and an originally relatively spherical shape of the object. Assuming the material collected represents the majority of fallen mass, and 90–99% of the original weight was lost by ablation, the pre‐atmospheric minimum radius of the meteoroid with density 3.4 g cm^?3would have been at least 75 cm.