Mechanisms of fine extinction band development in vein quartz: new insights from correlative light and electron microscopy

Fine extinction bands (FEBs) (also known as deformation lamellae) visible with polarized light microscopy in quartz consist of a range of nanostructures, inferring different formation processes. Previous transmission electron microscopy studies have shown that most FEB nanostructures in naturally deformed quartz are elongated subgrains formed by recovery of dislocation slip bands. Here we show that three types of FEB nanostructure occur in naturally deformed vein quartz from the low-grade metamorphic High-Ardenne slate belt (Belgium). Prismatic oriented FEBs are defined by bands of dislocation walls. Dauphiné twin boundaries present along the FEB boundaries probably formed after FEB formation. In an example of two sub-rhombohedral oriented FEBs, developed as two sets in one grain, the finer FEB set consists of elongated subgrains, similar to FEBs described in previous transmission electron microscopy studies. The second wider FEB set consists of bands with different dislocation density and fluid-inclusion content. The wider FEB set is interpreted as bands with different plastic strain associated with the primary growth banding of the vein quartz grain. The nanometre-scale fluid inclusions are interpreted to have formed from structurally bounded hydroxyl groups that moreover facilitated formation of the elongate subgrains. Larger fluid inclusions aligned along FEBs are explained by fluid-inclusion redistribution along dislocation cores. The prismatic FEB nanostructure and the relation between FEBs and growth bands have not been recognized before, although related structures have been reported in experimentally deformed quartz.     

Overview of the Geology of Cuba

Cuba is the largest island in the Greater Antilles(GA) and has been part of the North American Plate(NOAM) since Upper Eocene time. It is separated from other GA islands by the North Caribbean Transform Fault System which defines the present boundary between the NOAM and the Caribbean Plate(CARIB). The GA began to form ~135 Ma ago, after the breakup of Pangea, in the leading edge of CARIB, due to subduction of Proto-Caribbean lithosphere(NOAM) beneath CARIB until collision with the Bahamian platform in the Middle to Late Eocene time(~48 to 40 Ma). Between the Maastrichtian and the Late Eocene the Cayman spreading ridge and the Oriente transform formed and western CARIB was transferred to NOAM. The geology of Cuba is dominated by three lithotectonic units, which reflects its evolution as a Cretaceous-Paleogene convergent margin:(1) deformed(para)autochthonous NOAM Jurassic and Cretaceous continental margin and basin sections and PaleoceneEocene synorogenic foredeep;(2) ophiolite complexes and serpentinite mèlanges and ~135 to 47 Ma magmatic arc suite interbedded with or overlain by Latest CretaceousPaleogene synorogenic strata; and(3)(neo)autochthonous late Upper Eocene to Recent deposits which unconformably overlie the two older units.     

Late Variscan deformation in the Iberian Peninsula; a late feature in the Laurentia–Gondwana dextral collision

International Journal of Earth Sciences - The Late Variscan deformation event in Iberia is characterized by an intraplate deformation regime induced by the dextral oblique collision between...     

The External Tanger Unit (Intrarif sub-Domain,External Rifian Zones,Morocco): an interdisciplinary study

The External Tanger Unit represents one of the most complete Cretaceous-Miocene successions in the central areas of the Internal Intrarif sub-Domain (External Rif Zones, Morocco). An interdisciplinary study has been carried out to propose a new characterization of this unit which would allow a better comprehension of the confused and complex relationships among different units of the same sub-domain. The results achieved can be summarized as follows: (1) redefinition of the stratigraphic (litho-, bio-, and chrono-) record and introduction of a new, informal lithostratigraphic terminology; (2) recognition of two main depositional sequences (lower-middle Eocene p.p. and lower Oligocene p.p.-lower Miocene p.p.) separated by extended gaps (latest Cretaceous-early Eocene p.p. and middle Eocene p.p.-early Oligocene p.p.); (3) reconstruction of the evolution of the sedimentary realm, and of the relationships between tectonics and sedimentation; and (4) comparison between the upper Cretaceous-Miocene stratigraphic record and tectonic events of the Intrarif, which is located in the western external portion of the Maghrebian Flysch Basin, and the equivalent sedimentary record of the eastern portion of this basin in the Tunisian Tell. More in general, our results allowed (i) a first reconstruction of the Cretaceous-Miocene main tectono-sedimentary events; (ii) a more detailed location of the sedimentary suite in the external African Margin in the context of a wider palaeogeographic framework; and (iii) the definition of the main stages of the geological evolution of the area.     

Plankton carbon metabolism and air–water CO2 fluxes at a hypereutrophic tropical estuary

Multiple biotic and abiotic drivers regulate the balance between CO₂ assimilation and release in surface waters. In the present study, we compared in situ measurements of plankton carbon metabolism (primary production and respiration) to calculated air–water CO₂ fluxes (based on abiotic parameters) during 1 year (2008) in a hypereutrophic tropical estuary (Recife Harbor, NE Brazil – 08°03′S, 34°52′W) to test the hypothesis that high productivity leads to a net CO₂ flux from the atmosphere. The calculated CO₂ fluxes through the air–water interface (FCO₂) were negative throughout the year (FCO₂: –2 to –9 mmol C·m^?2·day^?1), indicating that Recife Harbor is an atmospheric CO₂ sink. Respiration rates of the plankton community ranged from 2 to 45 mmol C·m^?2·hr^?1. Gross primary production ranged from 0.2 to 281 mmol C·m^?2·hr^?1, exceeding respiration during most of the year (net autotrophy), except for the end of the wet season, when the water column was net heterotrophic. The present results highlight the importance of including eutrophic tropical shallow estuaries in global air–water CO₂ flux studies, in order to better understand their role as a sink of atmospheric CO₂.     

Hydrogeological origin of the CO2-rich mineral water of Vilajuïga in the Eastern Pyrenees (NE Catalonia,Spain)

The mineral water of Vilajuïga village in Alt Empordà (NE Catalonia, Spain) owes its uniqueness to an emanation of geogenic CO₂ that modifies groundwater hydrochemistry to produce a differentiated HCO₃–Na- and CO₂-rich groundwater among the usual Ca–HCO₃ type found in this region. A hydrogeological conceptual model attributes its occurrence to the intersection of two faults: La Valleta and Garriguella-Roses. The former provides a thrust of metamorphic over igneous rocks, formed during the Paleozoic, over a layer of ampelitic shale that, from a hydrogeological perspective, acts as a confining layer. The Garriguella-Roses normal fault, which originated during the Neogene, permits the degassing of geogenic CO₂ that is attributed to volcanic activity occurring in the Neogene. Groundwater mixing from the metamorphic and igneous rock units plus the local occurrence of CO₂ creates a HCO₃–Na water that still holds free-CO₂ in solution. Interaction with the gas phase is restricted at the intersection of the two faults. Radiocarbon dating, after correcting for geogenic dead carbon, estimates an age of 8,000 years BP. The low tritium content (0.7 TU) indicates that Vilajuïga water is a mix of “older” groundwater recharged in the metamorphic rocks of the Albera range and “younger” groundwater from the igneous rocks of the Rodes range, over a recharge area of 45 km² and a maximum elevation of 600 m. Given its origin as rare groundwater in the southern slope of the Eastern Pyrenees, purposeful monitoring is necessary to evaluate the groundwater vulnerability and anticipate impacts from nearby wells and climate-change effects.