Paleolimnological investigations of anthropogenic environmental change in Lake Tanganyika: VII. Carbonate isotope geochemistry as a record of riverine runoff

Evaporation dominates the removal of water from Lake Tanganyika, and therefore the oxygen isotope composition of lake water has become very positive in comparison to the waters entering the lake. The surface water in Lake Tanganyika has remained relatively unchanged over the last 30 years with a seasonal range of +3.2 to +3.5 VSMOW. Water from small rivers entering the lake seems to have a ¹⁸O value between –3.5 and –4.0, based on scattered measurements. The two largest catchments emptying into the lake deliver water that has a ¹⁸O value between these two extremes. This large contrast is the basis of a model presented here that attempts to reconstruct the history of runoff intensity based on the ¹⁸O of carbonate shells from Lake Tanganyika cores. In order to use biogenic carbonates to monitor changes in the ¹⁸O of mixing-zone water, however, the oxygen isotope fractionation between water and shell carbonate must be well understood. The relatively invariant environmental conditions of the lake allow us to constrain the fractionation of both oxygen and carbon isotope ratios. Although molluskan aragonitic shell ¹⁸O values are in agreement with published mineral-water fractionations, ostracode calcite is 1.2 more positive than that of inorganic calcite precipitated under similar conditions. Ostracode shell ¹⁸O data from two cores from central Lake Tanganyika suggest that runoff decreased in the first half of this millennium and has increased in the last century. This conclusion is poorly constrained, however, and much more work needs to be done on stable isotope variation in both the waters and carbonates of Lake Tanganyika. We also compared the ¹³C of shells against predicted values based solely on the ¹³C of lake water dissolved inorganic carbon (DIC). The ostracode Mecynocypria opaca is the only ostracode or mollusk that falls within the predicted range. This suggests that M. opaca has potential for reconstructing the carbon isotope ratio of DIC in Lake Tanganyika, and may be a useful tool in the study of the history of the lakes productivity and carbon cycle.     

Dissolution–precipitation processes governing the carbonation and silicification of the serpentinite sole of the New Caledonia ophiolite

The weathering of mantle peridotite tectonically exposed to the atmosphere leads commonly to natural carbonation processes. Extensive cryptocrystalline magnesite veins and stock-work are widespread in the serpentinite sole of the New Caledonia ophiolite. Silica is systematically associated with magnesite. It is commonly admitted that Mg and Si are released during the laterization of overlying peridotites. Thus, the occurrence of these veins is generally attributed to a per descensum mechanism that involves the infiltration of meteoric waters enriched in dissolved atmospheric CO₂. In this study, we investigate serpentinite carbonation processes, and related silicification, based on a detailed petrographic and crystal chemical study of serpentinites. The relationships between serpentine and alteration products are described using an original method for the analysis of micro-X-ray fluorescence images performed at the centimeter scale. Our investigations highlight a carbonation mechanism, together with precipitation of amorphous silica and sepiolite, based on a dissolution–precipitation process. In contrast with the per descensum Mg/Si-enrichment model that is mainly concentrated in rock fractures, dissolution–precipitation process is much more pervasive. Thus, although the texture of rocks remains relatively preserved, this process extends more widely into the rock and may represent a major part of total carbonation of the ophiolite.     

The Juchatengo complex: an upper-level ophiolite assemblage of late Paleozoic age in Oaxaca,southern Mexico

International Journal of Earth Sciences - The Juchatengo complex (JC) suite is located between the Proterozoic Oaxacan complex to the north and the Xolapa complex to the south, and was amalgamated...     

Process length variation of the cyst of the dinoflagellate Protoceratium reticulatum in the North Pacific and Baltic‐Skagerrak region: calibration as an annual density proxy and first evidence of pseudo‐cryptic speciation

Process length variation of cysts of the dinoflagellate Protoceratium reticulatum (Claparède et Lachmann) Bütschli in surface sediments from the North Pacific was investigated. The average process length showed a significant inverse relation to annual seawater density: σ_{t annual} = ?0.8674 × average process length + 1029.3 (R² = 0.84), with a standard error of 0.78 kg m^?3. A sediment trap study from Effingham Inlet in British Columbia revealed the same relationship between average process length and local seawater density variations. In the Baltic–Skagerrak region, the average process length variation was related significantly to annual seawater density: σ_{t annual} = 3.5457 × average process length ? 993.28 (R² = 0.86), with a standard error of 3.09 kg m^?3. These calibrations cannot be reconciled, which accentuates the regional character of the calibrations. This can be related to variations in molecular data (small subunit, long subunit and internal transcribed spacer sequences), which show the presence of several genotypes and the occurrence of pseudo‐cryptic speciation within this species. Copyright © 2012 John Wiley & Sons, Ltd.     

Time-Dependent Modulation of Cosmic Rays in the Heliosphere

The time-dependent modulation of galactic cosmic rays in the heliosphere is studied by computing intensities using a time-dependent modulation model. By introducing recent theoretical advances in the transport coefficients in the model, computed intensities are compared with Voyager 1, International Monitoring Platform (IMP) 8, and Ulysses proton observations in search of compatibility. The effect of different modulation parameters on computed intensities is also illustrated. It is shown that this approach produces, on a global scale, realistic cosmic-ray proton intensities along the Voyager 1 spacecraft trajectory and at Earth up to ≈?2004, whereafter the computed intensities recover much more slowly towards solar minimum than observed in the inner heliosphere. A modified time dependence in the diffusion coefficients is proposed to improve compatibility with the observations at Earth after ≈?2004. This modified time dependence led to an improved compatibility between computed intensities and the observations along the Voyager 1 trajectory and at Earth even after ≈?2004. An interesting result is that the cosmic-ray modulation during the current polarity cycle is not determined only by changes in the drift coefficient and tilt angle of the wavy current sheet, but is also largely dependent on changes in the diffusion coefficients.     

Stratigraphic and geochemical study of the organic-rich black shales in the Tarcău Nappe of the Moldavidian Domain (Carpathian Chain,Romania)

An integrated stratigraphic analysis has been made of the Tarcău Nappe (Moldavidian Domain, Eastern Romanian Carpathians), coupled with a geochemical study of organic-rich beds. Two Main Sequence Boundaries (Early Oligocene and near to the Oligocene–Aquitanian boundary, respectively) divide the sedimentary record into three depositional sequences. The sedimentation occurred in the central area of a basin supplied by different and opposite sources. The high amount of siliciclastics at the beginning of the Miocene marks the activation of the “foredeep stage”. The successions studied are younger than previously thought and they more accurately date the deformation of the different Miocene phases affecting the Moldavidian Basin. The intervals with black shales identified are related to two main separate anoxic episodes with an age not older than Late Rupelian and not before Late Chattian. The most important organic-rich beds correspond to the Lower Menilites, Bituminous Marls and Lower Dysodilic Shales Members (Interval 2). These constitute a good potential source rock for petroleum, with homogeneous Type II oil-prone organic matter, highly lipidic and thermally immature. The deposition of black shales has been interpreted as occurring within a deep, periodically isolated and tectonically controlled basin.     

EVA: GPS-based extended velocity and acceleration determination

In this work, a new GPS carrier phase-based velocity and acceleration determination method is presented that extends the effective range of previous techniques. The method is named ‘EVA’, and may find applications in fields such as airborne gravimetry when rough terrain or water bodies make difficult or impractical to set up nearby GPS reference receivers. The EVA method is similar to methods such as Kennedy (Precise acceleration determination from carrier phase measurements. In: Proceedings of the 15th international technical meeting of the satellite division of the Institute of Navigation. ION GPS 2002, Portland pp 962–972, 2002b) since it uses L1 carrier phase observables for velocity and acceleration determination. However, it introduces a wide network of stations and it is independent of precise clock information because it estimates satellite clock drifts and drift rates ‘on-the-fly’, requiring only orbit data of sufficient quality. Moreover, with EVA the solution rate is only limited by data rate, and not by the available precise satellite clocks data rate. The results obtained are more robust for long baselines than the results obtained with the reference Kennedy method. An advantage of being independent of precise clock information is that, beside IGS Final products, also the Rapid, Ultra-Rapid (observed) and Ultra-Rapid (predicted) products may be used. Moreover, the EVA technique may also use the undifferenced ionosphere-free carrier phase combination (LC), overcoming baseline limitations in cases where ionosphere gradients may be an issue and very low biases are required. During the development of this work, some problems were found in the velocity estimation process of the Kennedy method. The sources of the problems were identified, and an improved version of the Kennedy method was used for this research work. An experiment was performed using a light aircraft flying over the Pyrenees, showing that both EVA and the improved Kennedy methods are able to cope with the dynamics of mountainous flight. A RTK-derived solution was also generated, and when comparing the three methods to a known zero-velocity reference the results yielded similar performance. The EVA and the improved-Kennedy methods outperformed the RTK solutions, and the EVA method provided the best results in this experiment. Finally, both the improved version of the Kennedy method and the EVA method were applied to a network in equatorial South America with baselines of more than 1,770 km, and during local noon. Under this tough scenario, the EVA method showed a clear advantage for all components of velocity and acceleration, yielding better and more robust results.     

Efficient conceptual model for simulating the effect of aquifer heterogeneity on natural groundwater discharge to rivers

When linearity can be assumed (linear response of heads to stresses), stream–aquifer flow exchange can be simulated as the drainage of a number of independent linear reservoirs. This conceptual model, which can be mathematically deduced in a univocal way from an eigenvalue solution of the linear groundwater flow problem, facilitates the understanding of the physical phenomenon and the analysis of influencing factors. The number of reservoirs required to simulate stream depletion in some ideal homogeneous cases of stream–aquifer connection was analyzed in detail in a previous investigation using analytical eigenvalue solutions [16]. However, most aquifers are heterogeneous in nature and numerical solutions must be employed to analyze whether they could also be simulated using few reservoirs. This paper presents a stochastic analysis of the influence of heterogeneity on the simulation of natural groundwater discharges in aquifers connected to rivers, as a series of linear reservoirs. A Monte-Carlo approach was employed to perform this study. The results show that, on a monthly time scale, many cases (even heterogeneous aquifers) can be simulated using just a few reservoirs with sufficient accuracy and at minimum computational cost. Therefore, this modeling technique can be useful to efficiently simulate the integrated management of complex water resources systems at the basin scale (with many aquifers, reservoirs, demands, etc.) that need to simultaneously consider surface and groundwater flow and stream–aquifer interaction.