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41.
The reuse of waste materials as soil additives could be a welcome development in soil remediation. The mobility of Cd, Pb and As in a contaminated soil was investigated using natural and calcined poultry wastes (eggshell and chicken bone), CaCO3 and CaO at different application rates (0, 1, 3 and 5 %). The chemical composition accompanied with mineralogical composition indicated that CaCO3 and CaO were the major components in natural and calcined eggshells, respectively, while hydroxyapatite (HAP) dominated the natural and calcined chicken bones. The results showed that soil pH tended to increase in response to increasing application rates of all soil additives. The effectiveness of the additives in reducing Cd, Pb and As mobility was assessed by means of chemical extractions with 0.1 N HCl for Cd and Pb or 1 N HCl for As, according to Korean Standard Test (KST) method. Both calcined eggshell and chicken bone were equally effective with CaO or CaCO3 in reducing the concentration of 0.1 N HCl-extractable Cd from 6.17 mg kg?1 to below warning level of 1.5 mg kg?1, especially at the highest application rate. The application of calcined eggshell, CaO and CaCO3 also decreased the concentration of 0.1 N HCl-extractable Pb from 1,012 mg kg?1 to below warning level of 100 mg kg?1. The Pb concentration decreased significantly with an increasing application rate of chicken bone, but remained above warning level even at the highest application rate. On the contrary, natural and calcined chicken bones led to a significant increase in the mobility of As when compared with the control soil. These findings illustrate that calcined eggshell in particular is equally effective as pure chemical additives in stabilizing Cd and Pb in a contaminated agricultural soil. The presence of As in metal-contaminated soils should be taken into consideration when applying phosphate-containing materials as soil additives, because phosphate can compete with arsenate on adsorption sites and result in As mobilization.  相似文献   
42.
During the last decades, growth of urbanization and industrialization led to an increase in solid waste generation. Landfilling is the most prevalent ultimate disposal method for the municipal solid wastes in developing countries. The rapid municipal solid waste generation in Markazi province (central part of Iran) causes the need for precision in finding a suitable landfill site selection. In the present study, 12 factors (environmental and socioeconomic factors) have been applied to select the landfill site in Markazi province, Iran. The different methods including the analytic network process (ANP) combined with fuzzy linguistic quantifier, ordered weighted average (OWA), and weighted linear combination (WLC) approach in geographic information system was applied to find an appropriate landfill site. The OWA operator function permits the evaluation of the wide spectrum of consequences (with different scenario) obtained from different management strategies. Results revealed that integration of fuzzy logic, ANP, and OWA provides flexible and better ideas compared to the Boolean logic and WLC to select a suitable landfill site.  相似文献   
43.
Mujib watershed is an important groundwater basin which is considered a major source for drinking and irrigation water in Jordan. Increased dependence on groundwater needs improved aquifer management with respect to understanding deeply recharge and discharge issues, planning rates withdrawal, and facing water quality problems arising from industrial and agricultural contamination. The efficient management of this source depends on reliable estimates of the recharge to groundwater and is needed in order to protect Mujib basin from depletion. Artificial groundwater recharge was investigated in this study as one of the important options to face water scarcity and to improve groundwater storage in the aquifer. A groundwater model based on the MODFLOW program, calibrated under both steady- and unsteady-state conditions, was used to investigate different groundwater management scenarios that aim at protecting the Mujib basin. The scenarios include variations of abstraction levels combined with different artificial groundwater recharge quantities. The possibilities of artificial groundwater recharge from existing and proposed dams as well as reclaimed municipal wastewater were investigated. Artificial recharge options considered in this study are mainly through injecting water directly to the aquifer and through infiltration from reservoir. Three scenarios were performed to predict the aquifer system response under different artificial recharge options (low, moderate, and high) which then compared with no action (recharge) scenario. The best scenario that provides a good recovery for the groundwater table and that can be feasible is founded to be by reducing current abstraction rates by 20% and implementing the moderate artificial recharge rates of 26 million(M)m3/year. The model constructed in this study helps decision makers and planners in selecting optimum management schemes suitable for such arid and semi-arid regions.  相似文献   
44.
The optical anomalies, and surface and lamellar textures of a birefringent grossular garnet crystal from the Eden Mills, Belvidere Mountain, Vermont, USA, have been investigated by optical polarizing microscope, electron-probe micro-analyzer, back-scattered electron imaging, infrared spectroscopy, and single-crystal X-ray diffractometer from the standpoint of crystal growth. This grossular shows one-to-one correlation between natural surface features and its internal textures under crossed polarizers. Electron-probe micro-analyzer (EPMA) gave average chemical composition in (110) thin section, of bright lamella {Ca2.97Mn0.06}∑3.03 [Al1.59Fe0.37Ti0.01]∑1.97(Si3.00)∑3.00 (Gros79.5And18.9Sps1.6) and of dark host {Ca2.99Mn 0.06}∑3.05 [Al1.73Fe0.26 Ti0.01]∑2.00(Si2.97OH0.03)∑3.00 (Gros85.4And13Sps1.6). The correspondence of surface features and the internal textures with spiral or pyramidal growth mechanism suggest that the internal textures of the Eden Mills grossular are formed during growth process. The optical vibrational orientations and the growth steps inclination along [001] and \( \left[\overset{-}{1}10\right] \) directions predict monoclinic symmetry. With X-ray diffractometer (XRD) method, pseudocubic parameters are a = 11.839(2) Å, b = 11.855(1) Å, and c = 11.868(2) Å with interaxial angles α = 90.00(1)°, β = 89.99(1)°, and γ = 90.02(2)° that show orthorhombic symmetry of this crystal. Lamellar texture of Al3+-rich host with Fe3+-rich lamella infers cation ordering at octahedral site of the garnet structure. IR data favors the non-cubic orientation of [(OH) 4] at tetrahedral position in this grossular structure.  相似文献   
45.
Many surface and underground structures are constructed in heterogeneous rock formations. These formations have a combination of weak and strong rock layers. Due to the alternation of the weak and strong layers, selecting the equivalent and appropriate geomechanical parameters for these formations is challenging. One of these problems is choosing the equivalent strength (i.e., uniaxial compressive strength) of intact rock for a group of rocks. Based on the volume of weak and strong parts and their strength, the equivalent strength of heterogeneous rocks changes. Marinos and Hoek (Bull Eng Geol Environ 60(2):85–92, 2001) presented the “weighted average method” for defining the uniaxial compressive strength (UCS) of heterogeneous rock masses based on the volume of weak and strong parts. Laubscher (1977) used the volume ratio of the strength of a weak part to a strong part (UCS weak/UCS strong) to determine the equivalent strength. In this study, the two methods are compared and their validity is evaluated by experimental data and numerical analyses. The geomechanical parameters of two heterogeneous formations (Aghajari and Lahbari) in the west of Iran were estimated using these methods. The results of the present study obtained through numerical analyses using particle flow code are compared with those of previous studies and discussed. Laboratory and numerical results show UCS decrease and approach to weak strength with an increasing in volume of weak part. When strength ratio of strong to weak rock increase, equivalent strength decrease more severely. The findings show that Laubscher’s method gives more appropriate results than the weighted average method.  相似文献   
46.
Flood disasters and its consequent damages are on the rise globally. Pakistan has been experiencing an increase in flood frequency and severity along with resultant damages in the past. In addition to the regular practices of loss and damage estimation, current focus is on risk assessment of hazard-prone communities. Risk measurement is complex as scholars engaged in disaster science and management use different quantitative models with diverse interpretations. This study tries to provide clarity in conceptualizing disaster risk and proposes a risk assessment methodology with constituent components such as hazard, vulnerability (exposure and sensitivity) and coping/adaptive capacity. Three communities from different urban centers in Pakistan have been selected based on high flood frequency and intensity. A primary survey was conducted in selected urban communities to capture data on a number of variables relating to flood hazard, vulnerability and capacity to compute flood risk index. Households were categorized into different risk levels, such as can manage risk, can survive and cope, and cannot cope. It was found that risk levels varied significantly across the households of the three communities. Metropolitan city was found to be highly vulnerable as compared to smaller cities due to weak capacity. Households living in medium town had devised coping mechanisms to manage risk. The proposed methodology is tested and found operational for risk assessment of flood-prone areas and communities irrespective of locations and countries.  相似文献   
47.
Durability of building stones is an important issue in sustainable development. Crystallization of soluble salts is recognized as one of the most destructive weathering agents of building stones. For this reason, durability of Ghaleh-khargushi rhyodacite and Gorid andesite from Iran was investigated against sodium sulfate crystallization aging test. Petrographic and physico-mechanical properties and pore size distribution of these stones were examined before and after the aging test. The characteristics of the microcracks were quantified with fluorescence-impregnated thin sections. Durability and physico-mechanical characteristics of Ghaleh-khargushi rhyodacite are mainly influenced by preferentially oriented preexisting microcracks. Stress induced by salt crystallization led to the widening of preexisting microcracks in Ghaleh-khargushi rhyodacite, as confirmed by the pore size distributions before and after the aging test. The preexisting microcracks of Gorid andesite were attributed to the mechanical stress induced by contraction of lava during cooling. The number of transcrystalline microcracks was significantly increased after the aging test. The degree of plagioclase microcracking was proportional to its size. Durability of the studied stones depends on initial physico-mechanical properties, pore size distribution, and orientation of microcracks. Initial effective porosity is found to be a good indicator of the stones’ durability. Salt crystallization resulted in an increase in the effective porosity with a parallel decrease in the wave velocities. Surface microroughness parameters increased with the development of salt crystallization-induced microcracking. Gorid andesite showed higher quality and durability than Ghaleh-khargushi rhyodacite.  相似文献   
48.
Soil erosion, a serious environmental problem, is a global challenge. Once a portion of a fertile soil is lost, it is very difficult to replace it, and this leads to decrease in crop production, damage to drainage networks, and siltation of dams and reservoirs. Human practices like intensive agriculture, overgrazing, and deforestation have intensified the rate of soil erosion all over the world. The Jhelum basin which forms the north-western part of the complex mountain system Himalayas is not only highly vulnerable to natural hazards like earthquakes, landslides, and floods but is also highly susceptible to soil erosion. There is an immediate need to device strategies to reduce adverse impacts of soil erosion and to conserve natural resources like soil, water, and forests by means of proper watershed management programs in the Himalayan region. The present study is carried out for eight upper watersheds of Jhelum basin, an area which are facing serious issues like boulder extraction, deforestation, and unplanned urbanization. The present work demonstrates the use of morphometry, land use, and slope coupled with the multicriteria analytical (MCA) framework to estimate the soil erosion susceptibility of these watersheds using Remote Sensing and Geographical Information System techniques. The present study revealed that out of eight upper watersheds, Arapal, Lidder, and Bringi fall in high priority and need immediate attention and measures to reduce soil erosion in the area. Sandran, Rembiara, and Romshii fall in medium priority. Kuthar and Vishav fall in the low-priority category and are least susceptible to soil erosion.  相似文献   
49.
The developing countries at present have a high urban growth rate that is likely to continue for at least another quarter-century. In addition, many of these urban centres are located in the Neogene plate boundary zones and are subject to multiple earthquake and volcanic hazards. Slope failures and accelerated surface and channel erosion are particularly severe in cities near active plate margins, and in areas affected also by tropical cyclones. We discuss two extreme cases: Singapore and Kingston (Jamaica). Singapore is located in a stable environment and the urbanization related problems of flood and slope instability have been reduced by proper building and drainage practices at a considerable cost. In Kingston, the external disturbances are repetitive, large-scale, and very difficult to control. The fast-growing cities in the tropics need to be carefully monitored, especially when located in an unstable physical environment. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
50.
A chelating resin is prepared by condensation polymerization of aniline with formaldehyde and characterized by Fourier transform infrared spectrometer, elemental analysis and thermogravimetric analysis and studied for the preconcentration and determination of trace Molybdate ion from environmental water sample using inductive couple plasma atomic emission spectroscopy. The optimum pH value for sorption of the metal ion was 5. The sorption capacity of functionalized resin is 3.1 mg/g. The chelating sorbent can be reused for 20 cycles of sorption-desorption without any significant change in sorption capacity. The best desorption of the metal ions from resin was obtained by 0.5 mol/L nitric acid as eluting agent. The profile of molybdenum uptake on this sorbent reflects good accessibility of the chelating sites in the aniline-formaldehyde. Scatchard analysis revealed that the homogeneous binding sites were formed in the polymers. The equilibrium adsorption data of Molybdate ion modified resin were analyzed by five isotherm models such as Langmuir, Freundlich and Temkin. Langmuir isotherm parameters obtained from the four Langmuir linear equations by using linear method. Based on the Langmuir isotherm analysis, the monolayer adsorption capacity was determined to be 4.03 mg/g at 20 °C. The method was applied for molybdenum ions determination from river water sample.  相似文献   
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