The origin of tin deposits in the Mount Wells region,Pine Creek Geosyncline,Northern Territory

Tabular steeply dipping cassiterite‐bearing lodes in the Mount Wells region are hosted by lower greenschist fades metasediment of the Pine Creek Geosyncline within the contact aureole of late orogenic granitoids. The latter are predominantly I‐type, but S‐type phases are developed near the sediment‐granitoid contact.

Quartz, cassiterite, pyrite, arsenopyrite, chalcopyrite and pyrrhotite are the main minerals. Two types of lodes are present: (i) Sn‐quartz lodes containing 5–10 vol% sulphide minerals; and (ii) Sn‐sulphide lodes containing ～ 70 vol% sulphide minerals. At the surface, the former appear as normal quartz veins and the latter as hematite‐quartz breccia resulting from the collapse of original sulphide‐rich lodes as a consequence of volume reduction due to oxidation and leaching.

Two stages of quartz veining are recognized in both types of lodes. Cassiterite is present in stage I while stage II is composed of barren quartz with minor pyrite. Late stage III carbonate veinlets are present in Sn‐sulphide lodes. The lode‐wallrock contact is sharp with weak alteration effects confined to the fringe of the lodes. The alteration minerals include sericite, quartz, tourmaline, chlorite, pyrite and minor K‐feldspar.

Four types of fluid inclusions are present in vein quartz and cassiterite: Type A (CO₂ ± H₂O ± CH₄); Type B (H₂O+～ 20% vapour); Type C (H₂O+ < 15% vapour) and Type D (H₂O+ < 15% vapour + NaCl). Early ‘primary’ inclusions represented by Types A and B are present in stage I only and have a well‐defined temperature mode at ～300°C and a salinity range of 1–20 wt% eq NaCl. Types C and D inclusions are ‘secondary’ in stage I and primary in stage II and have a temperature mode at 120–160°C and salinities from about 1 to more than 26 wt% eq NaCl. Variable H₂O‐CO₂ ratios of Type A inclusions and homogenization in CO₂ or H₂O phase at near identical temperature indicate entrapment at the H₂O‐CO₂ solvus and define a pressure of ～ 100 MPa. The melting sequence of frozen inclusions suggests that the ore fluids were mainly H₂O‐CO₂‐CH₄‐Na‐Ca‐Cl brines. This is also confirmed by Raman Laser Spectrometry.

Oxygen and sulphur isotope data are consistent with a magmatic origin of the ore fluids. The δD values are up to 20%0 higher than those expected for magmatic fluids and probably resulted from interaction of the latter with the carbonaceous strata. This interpretation is supported by δ¹³C data on the fluid inclusion CO₂.

Fluid inclusions, stable isotope and mineralogical data are used to approximate the physico‐chemical parameters of the ore fluids which are as follows: T 300°C, m Cl～2, fO₂ ～ 10^‐35, mSS ～ 0.01, Sn ～ 1 ppm, Cu ～ 1 ppm and pH ～ 5.5.

It is suggested that fluids of granitic parentage interacted with the enclosing sediment and picked up CO₂, CH₄ and possibly Ca. The granitic phases became reduced due to this interaction and developed S‐type characteristics. Tin was probably partitioned into the CH₄‐bearing reduced fluids. At some stage the fluid overpressure exceeded the lithostatic lode enforcing failure of the carapace and the intruded rocks by hydraulic fracturing causing CH₄ and CO₂ loss resulting in the precipitation of the ore minerals.     

Leaching capabilities of iodine monochloride (ICl) and diethylenetriamine pentaacetic acid (DPTA) at different concentrations and pH for some major and trace metals from coal and coal fly ash

In the present study, coal from Chakwal (Pakistan) was leached with an aqueous solutions of iodine monochloride (ICl) and diethylenetriamine pentaacetic acid (DPTA) of different concentrations. The effect of stirring time, concentration and pH was studied on the leaching of different metals from coal. The physicochemical parameters indicated that the coal was of reasonably good quality. The results indicated that with increase in time duration, the extraction of metals increased. In most of the cases, metal concentration increased in the leachate with increasing the concentration of the leaching agents. DPTA was found to be the best leaching agent for most of the metals. Higher extraction of metals from coal fly ash indicated that coal organic matter has a pronounced effect on the leaching. Higher concentration of metals was extracted from virgin coal and coal fly ash at low pH (p?>?0.00) as compared to high pH. DPTA extracted metals in higher concentration from virgin coal and coal fly ash at low pH as compared to ICl. Based on the present study, the most leached metals were Fe, Cu, Mn and the least were Pb, Ni, Cd and Cr.     

Dynamic vertical compliance of strip foundations in layered soils

In this paper, results of a detailed investigation on the dynamic response of rigid strip foundations in viscoelastic soils under vertical excitation are presented. An advanced boundary element algorithm developed by incorporating isoparametric quadratic elements and a sophisticated self-adapting numerical integration scheme has been used for this investigation. Foundations supported on three types of soil profiles, namely, homogeneous half-space, stratum-over-half-space and stratum-over-bedrock are considered. The influence of material properties like Poisson's ratio and material damping as well as the influence of geometrical properties such as depth of embedment and layer thickness are studied. The effect of the type of contact at the soil-foundation interface is also investigated.     

Utility Efficient Frontier: An Application in the Oil and Gas Industry

Current practice shows that the use of portfolio and utility theory is very low among petroleum companies. This article advocates the use of both portfolio theory and utility theory as decision-making tools to improve performance of oil and gas companies. We introduce a model that can be practically used and applied in the oil and gas industry. This model generates an optimized, efficient portfolio and, at the same time, enables the decision maker to incorporate his risk attitude and policy. This can only be done by combining both the portfolio theory and utility theory through an approach called the utility mean-variance model. A typical oil portfolio optimization problem is investigated by applying both portfolio and utility theories. Through the utility mean-variance model, an efficient frontier that captures decision maker risk attitude is achieved.     

An Experiment Using the High Resolution Eta and WRF Models to Forecast Heavy Precipitation over India

In the present study using the Weather Research and Forecasting (WRF) and Eta models, recent heavy rainfall events that occurred (i) over parts of Maharastra during 26 to 27 July, 2005, (ii) over coastal Tamilnadu and south coastal Andhra Pradesh during 24 to 28 October, 2005, and (iii) the tropical cyclone of 30 September to 3 October, 2004/Monsoon Depression of 2 to 5 October 2004, that developed during the withdrawal phase of the southwest monsoon season of 2004 have been investigated. Also sensitivity experiments have been conducted with the WRF model to test the impact of microphysical and cumulus parameterization schemes in capturing the extreme weather events. The results show that the WRF model with the microphysical process and cumulus parameterization schemes of Ferrier et al. and Betts-Miller-Janjic was able to capture the heavy rainfall events better than the other schemes. It is also observed that the WRF model was able to predict mesoscale rainfall more realistically in comparison to the Eta model of the same resolution.     

Eco-friendly smart hydrogels for soil conditioning and sustain release fertilizer

In the agricultural industry, biomass waste generated along with the production of food, is transformed into value-added products. Also, the demand for the slow or control release fertilizer is increasing to reduce the cost of maintaining the agricultural land. These issues are tackled by converting biomass waste to a slow fertilizer release vehicle and biodegradable water retention material that could reduce the cost for fertilizer application and simultaneously preserved the soil from dryness. A series of carboxymethyl sago pulp (CMSP) hydrogels were prepared by electron beam irradiation. Slow release systems were evaluated by loading potassium nitrate (KNO₃) and ammonium nitrate (NH₄NO₃) into the CMSP hydrogels. These CMSP hydrogels endow slow release property, biodegradability and a soil moisture preservation property that could find greener application in agricultural industries. The results indicate that CMSP hydrogels have a great potential as an agent for slow release of fertilizers.     

Peculiar motions of galaxy clusters: correlation function approach

The correlation function theory on the basis of prescribed boundary conditions provides a deeper understanding in studying the dynamical parameters of galaxy clusters. The approach approximates that the moderate dense systems discussed by a two point correlation function is helpful for describing the dynamical nature of galaxy clusters. The projected theory of two point correlation function for point mass and extended mass structures can be used an alternative tool in measuring the average peculiar motion and temperature profile of galaxy clusters.     

Temporal change of glaciers area and geomorphometric parameters in Parbati valley,Himachal Pradesh,India

Temporal change in the glacier coverage is analyzed for the period between 1962 and 2003 in Parbati valley, Himachal Pradesh. It is observed that the total glacier cover has been decreased by 17% ranging between 8 and 100% for individual glacier. The pattern of de-glaciation shows a high degree of shrinkage in outer zone of Parbati valley, while least shrinkage is observed in the inner valley. The present study is conducted to establish relationship between glacio-geomorphic parameters and glaciers shrinkage pattern to predict the future glacier cover in warming scenario. A systematic change is observed for glacio-geomorphic parameters associated with temporal change in glacier cover. It is observed that mean and minimum elevation, slope, relief and duration of insolation have changed substantially. Maximum elevation, plan/profile curvatures and aspect have shown less change from 1962 to 2003. A correlation matrix between glacio-geomorphic parameters for glaciers between 1962 and 2003 shows that the recent glaciers are much more controlled by terrain characteristics than that in the recent past.