Formation Environment of Main Brown Coal Seam in Xi-2 Minefield of Shengli Coalfield Based on Coal Ash Phase Analysis

The formation environment of the main coal seam in Shengli coal mine is analyzed, and the effect of coal ash parameters on the coal-forming environment is mainly discussed according to gray component parameters combined with other coal quality test analysis data. Results show that the hydrodynamic conditions of the main coal during coal accumulation have a general pattern of strong northeast and weak southwest, and lakeside swamp is generally in the retrograde process from south to north. The No.5 coal seam is a water entry cycle, and the No.5_lower coal is a water withdrawal cycle. The No.6 thick coal seam is formed in the peat swamp environment where the water is shallow and the groundwater activity is weak. The input of terrestrial debris material was most abundant in the formation period of No.5_lower coal, followed by No.5 coal, and that in No.6 coal is the least. Vertically, the peat swamp environment changed from weak reduction to weak oxidation to strong reducing environment. The ash yield was low to high to low from bottom to top. The organic sulfur is the main type of sulfur in the main coal seam. The weaker the hydrodynamic condition, the higher the organic sulfur content in the reduction environment, while lower organic sulfur content in the oxidation environment. The peat swamp water of No.5_lower coal is medium alkaline, and the peat swamp water of No.5 and No. 6 coals is weakly alkaline or acidic.     

基于等时界面识别的浅水三角洲-河流沉积体系研究--以高邮凹陷黄珏地区古近系垛一段为例

利用岩芯观察、粒度统计、古生物对比、测井分析及地震沉积学方法研究了苏北盆地高邮凹陷黄珏地区始新世三垛组一段浅水三角洲-河流沉积体系。研究结果表明:坡缓浅水沉积背景下除了发育传统认识中由构造控制的长期基准面旋回特征转换面,还可形成另一类由气候控制的、浅水三角洲与河流沉积之间稳定的浅水-陆上沉积环境变化界面。以气候主控等时界面为基础,借助地层切片直观分析了浅水三角洲与河流相的沉积演化特征及砂体展布规律,并验证了该界面的可靠性。两类等时界面的综合约束为浅水三角洲-河流沉积体系油气勘探提供了新思路。     

柴西地区扎哈泉致密油储层特征及评价

柴西地区致密油储层内部结构复杂、非均质性强,为了更高效地进行致密油勘探开发,利用岩芯薄片、X衍射、场发射扫描电镜、CT扫描和物性分析等方法,对扎哈泉地区上干柴沟组开展致密储层特征及储层物性控制因素研究。研究表明,上干柴沟组为典型的致密储层,以细砂岩和粉砂岩为主,填隙物含量较高,以原生孔隙为主,微米级孔隙是主要的储集空间,有效储层平均孔隙度为5. 9%,平均渗透率为0. 43 m D。储层内部孔隙分布较均匀,总体呈现微米级孔隙加纳米级喉道的特征,其中微米级孔隙基本呈片状分布,连通性好,纳米级孔隙则呈点孤立状分布。储层物性受原始沉积条件和后期成岩作用控制,坝砂泥质含量低,纯度高,物性较好。压实作用和碳酸盐胶结使储层变差,硬石膏胶结对孔隙的影响具有两面性,晚成岩期的溶蚀作用对储层改善作用明显。研究区致密油有效储层可分为三类,其中Ⅰ类有效储层为本区的"甜点"区,是下一步优先勘探开发的重点区块,Ⅱ-Ⅲ类有效储层则是重要的挖潜区,通过工程技术攻关可切实实现柴西地区的增产扩能。     

甘肃省龙首山芨岭铀矿床成矿热液流体特征研究

芨岭铀矿是中国北方最典型的钠交代型铀矿床之一,文章通过对芨岭矿床ZKJ9-4钻孔深部所见含矿蚀变闪长岩、近矿蚀变闪长岩、远矿蚀变闪长岩、闪长岩原岩地球化学特征和组分迁移计算及矿体中心部位的淡粉红色方解石脉流体包裹体特征、均一温度、盐度和激光拉曼光谱研究,认为芨岭钠交代型铀矿床的成矿流体含有大量碳酸铀酰络合物[UO_2(CO_3)_2]~(2–)和[UO_2(CO_3)_2]~(4–)的同时还含有丰富的SiO_2、Na~+、Ca~(2+)、Mg~(2+)、Fe~(2+)、Mn~(2+)、∑REE、U、Th、Ga、Sr、Zr、Ba、Rb、Nb、Mo、Cd、Sn、Hf、Ti、Ta、CO_2、H_2S和CH_4等组分,成矿流体具有较强的还原性,并对MnO、K_2O、Cr和Co具有较强的交代溶蚀作用。成矿流体是起源于岩浆演化晚期的再平衡岩浆水,热液温度为(300±20)℃,盐度为2.99 wt%~4.57 wt%NaCl,密度为0.75~0.77 g/cm~3。流体沸腾是芨岭钠交代型铀矿成矿物质的早期卸载机制,晚期成矿流体中加入了大量的大气降水,流体混合作用进一步促进了成矿物质的卸载。     

学前教育资源空间分布及可达性研究--以深圳市龙岗区普惠园为例

为研究学前教育资源的空间分布,以深圳市龙岗区普惠性幼儿园为例,从供给需求角度出发,运用传统两步移动搜索法和高斯两步移动搜索法分别计算不同阈值半径下的可达性数值,对龙岗区学前教育资源的配置现状进行分析和评价。研究结果表明:龙岗区学前教育资源配置存在明显的空间差异,高值区域呈现多中心结构,以各商业文化中心为核心向周边扩散;低值区域分布在龙岗区的西北方向、东南方向以及城市边缘地区;高斯型两步移动搜索法能准确地体现距离因素对可达性的影响,对空间可达性反映更加真实、客观。研究成果可为深圳市龙岗区学前教育设施合理布局提供科学依据。     

西藏班戈错水菱镁矿藻类成矿实验及其成因分析

目前关于天然水菱镁矿的形成认识主要有蒸发沉积成因和生物成因两类。前人在室内成功制备出水菱镁矿矿物,证实了该矿物的无机成因理论,但是实验结晶条件明显高于西藏班戈错的寒冷气候条件和水化学条件,并且班戈错湖水通过自然蒸发结晶也难以形成水菱镁矿矿物,而这一认识与周边阶地上正在形成水菱镁矿的现象相矛盾。因此,自然蒸发沉积可能不是现阶段班戈错水菱镁矿的主要形成过程,而已有研究表明,藻类具备诱导形成碳酸盐矿物的能力,本文利用西藏班戈错Ⅲ湖湖水及其藻类开展室内模拟实验,并与无藻类的湖水自然结晶结果相对照,探讨藻类生命活动与班戈错水菱镁矿的成因联系。研究发现,藻类不仅能够适应高盐度盐水环境（矿化度117.3 g/L）,并且在其光合作用过程中还能显著提高周围水体pH值（最高可达10.564）,诱导并促进球碳镁石在藻类网状节点处结晶沉淀,该矿物进一步脱水即能够形成水菱镁矿矿物;而人为提高班戈错Ⅲ湖湖水Mg2+浓度也仅能结晶形成三水菱镁矿矿物,无球碳镁石或水菱镁矿结晶析出。因此,西藏班戈错水菱镁矿的形成过程与藻类生物成矿作用密切相关,但是有关球碳镁石向水菱镁矿转变的具体条件以及藻类成矿作用的具体分子机制仍不清楚,有待于进一步研究。     

非常规与常规统一的含油气系统之初探

近年来,非常规页岩油气勘探开发的成功,为获取油气资源指出了新方向,同时提醒石油地质家重新审视传统的油气地质理论,需要将页岩油气的地质认识进展与传统的油气地质理论结合起来形成新的含油气系统理论。本文基于从常规与非常规在生烃、储层方面的研究进展,初步探讨涵盖常规和非常规的统一的含油气系统和二者协同的勘探思维。生烃研究由以往主要关注生油气高峰时的生烃量延伸到对油气生成、排出、滞留全过程的刻画;储层研究由关注无机矿物成岩演化中形成的米级—毫米级无机孔隙向成岩作用—成烃协同作用形成的微米级—纳米级有机质孔隙延伸;在此基础上提出狭义页岩气、广义页岩气藏和常规气藏的分类界限。在全新的含油气系统理论指导下,需要进行常规—非常规协同一体化评价基础上的勘探思维变革。以常规与非常规油气的成因联系为指导,深入分析同一套烃源岩的生成—排出—滞留过程,分析常规与非常规油气的资源配比关系与空间分布关系,有助于提升油气勘探效率和勘探成功率。     

落石冲击混凝土板与缓冲层组合结构的动力响应

钢筋混凝土（RC）板与一定厚度的土颗粒缓冲层组合结构被广泛用于山区高位单体及群发性崩塌落石的防治,为研究此类防护结构在落石作用下的冲击力衰减规律及RC板的破坏模式,开展了室外系列落石冲击试验。结果表明,增大缓冲层厚度能够有效减小最大冲击力,峰值加速度随缓冲层厚度减小而增大,尤其在缓冲层厚度为0.1 m及0.2 m时,最大值急剧增大,峰值加速度与缓冲层厚度的变化满足指数函数关系;根据量纲分析原理得到缓冲层最大冲击深度与动能的平方成正比、与最大入射冲击力成反比的计算公式,且与实测值较吻合;入射冲击力在缓冲层内的衰减率随缓冲层厚度的增加以指数函数递增,在0.6 m缓冲层厚度下可使峰值冲击力衰减70%左右;随累积冲击能级的增大,RC板经历了弯曲起裂及扩展、次级弯曲裂纹和剪裂纹产生及跨中弯曲裂纹贯通的过程,试验结束时RC板整体表现出典型的弯曲破坏特征。     

节理分布空间变异的地下洞室稳定性概率分析

以岩土材料力学参数空间变异性的"点估计-有限元"分析方法为基础,结合节理分析时自身存在几何模型、网格划分等特性,扩展了该方法在节理分布空间变异性分析方面的适用性,明确了具体的研究步骤与方法。以某抽水蓄能水电站为例,通过分析节理空间变异性对围岩变形与塑性区的影响,验证了扩展后该方法的准确性和合理性。对工程案例开挖揭露的1400余条节理进行概率统计,建立了节理空间变异性的有限元分析模型;采用扩展后的概率分析方法,研究了节理分布对地下洞室群围岩开挖稳定性的影响。研究结果表明:(1)对比概率分析得到的围岩变形概率分布与现场监测结果,发现剔除变形异常点后监测变形量值大部分位于得到的位移概率分布范围内,说明节理的空间变异性是导致监测变形波动的主要影响因素;(2)围岩变形概率分布的标准差能有效识别出围岩开挖变形受节理空间变异性的影响程度,对于所给出的案例依次为:机窝>边墙>顶拱;(3)围岩塑性区的概率分区能合理判断地下洞室群开挖时受节理影响较大的区域和范围,为工程施工的支护设计提供依据。     

U-Pb Zircon and Re-Os Molybdenite Geochronology of theW-Mo Mineralized Region of South Qinling,China, andtheir Tectonic Implications

A W-Mo mineralized region is located along the northern margin of the South Qinling tectonic belt of China. WMo mineralization occurs mainly in Cambrian–Ordovician clastic and carbonate rocks, and the ore bodies are structurally controlled by NW–SE-and NNE–SSW-striking faults. Evidence for magmatism in the area is widespread and is dominated by intermediate–felsic intrusives or apophyses, such as the Dongjiangkou, Yanzhiba, Lanbandeng, and Sihaiping granitic bodies. Quartz-vein-type mineralization and fault-controlled skarn-type mineralization dominate the ore systems, with additional enrichment in residual deposits. At present, there are few or insufficient studies on(1) the age of mineralization,(2) the relationship between intermediate–felsic granite and W-Mo mineralization,(3) the source of ore-forming materials,and(4) the metallogenic and tectonic setting of the mineralized area. In this paper, we present geochronology results for numerous intrusive granitic bodies in the South Qinling tectonic belt. U-Pb zircon geochronology of the Lanbandeng monzogranite and Wangjiaping biotite monzogranite yields ages of 222.7 ± 2.3 and 201.9 ± 1.8 Ma, respectively. In contrast to the Late Triassic age of the Lanbandeng monzogranite, the age of the newly discovered Wangjiaping biotite monzogranite places it at the Triassic–Jurassic boundary. Re-Os molybdenite geochronology on the Qipangou W-Mo deposit yielded a model age of 199.7 ± 3.9 Ma, indicating the deposit formed in the early Yanshanian period of the Early Jurassic. Granitoid intrusions in the mineralized area are characterized by composite granite bodies that crystallized at ca.240–190 Ma. While there were multiple stages of intrusion, most occurred at 210–220 Ma, with waning magmatic activity at 200–190 Ma. The Re-Os age of molybdenite in the region is ca. 200–190 Ma, which may represent a newly discovered period of W-Mo metallogenesis that occurred during the final stages of magmatism. The heat associated with this magmatism drove ore formation and might have provided additional ore-forming components for metallogenesis(represented by the Wangjiaping biotite monzogranite). Ore materials in the mineralized area were derived from mixed crustal and mantle sources. Enrichment of the region occurred during intracontinental orogenesis in the late Indosinian–Yanshanian, subsequent to the main Indosinian collision. At this time, the tectonic environment was dominated by extension and strike-slip motion.