Oxygen isotopic composition of Central Sierra Nevada precipitation, I. Identification of ice-phase water capture regions in winter storms

Measurements of the stable isotopic ratios of oxygen and simultaneously observed ice crystal structure in freshly fallen snow, have been used to estimate the weighted mean altitudes of ice-phase precipitation formation in winter clouds over the Central Sierra Nevada.Observations of dominant, diffusionally grown ice-crystal habits were used to estimate relatively narrow ranges of temperatures of initial formation of the precipitation particles using the Nakaya (1954) ice-crystal classification techniques. The mean oxygen isotope ratio ¹⁸O/¹⁶O for each snow sample, together with local upper air soundings, were used to estimate ranges of temperature-altitude within the clouds where the precipitating particles had captured their ice-phase water. For this initial study, snow samples were collected each five (5) to ten (10) minutes during three snowfall periods on 27 January, 26 February and 28 February, 1983.For the 27 January case, the ice formation mechanism was predominantly vapor deposition and hence the narrow range of temperatures determined by the ice-crystal habits was directly relatable to the mean δ¹⁸O value.The 26 and 28 February cases were more complicated because the solid-phase precipitation was formed by vapor deposition and by freezing of drops and droplets (which occurs without isotopic fractionation). In these cases, the oxygen isotopic composition of the snow reaching the ground was representative of solid phase precipitation which had formed at warmer temperatures than those corresponding to the primary ice-crystal habits alone. There was no apparent relationship between δ¹⁸O values and surface temperature at the sampling site.If relationships between ¹⁸O/¹⁶O and temperature-altitude are established for this geograpic region for winter snowfall conditions, this crystal habit—isotopic composition technique can provide knowledge about the regions of the clouds in which the ice-phase precipitation is forming over the Central Sierra Nevada.     

Pacific decadal oscillation impact on East China precipitation and its imprint in new geological documents

This paper briefly introduces the history of the study of the Pacific decadal oscillation (PDO) and explores the relationship between the PDO and sediment grain size from two typical sediment cores from the lower Changjiang (Yangtze River) and Huanghe (Yellow River) estuaries. It is found that the median grain sizes of both cores exhibit relatively high correlation with the PDO. This is because the PDO causes interdecadal variability of precipitation in the East Asia Monsoon region, thus changing the hydrodynamics in both the Changjiang and Huanghe catchments, eventually resulting in variation of sediment grain size. Our analysis also revealed that during different phases of the PDO, the sediment grain size of the Changjiang and Huanghe estuaries showed different variations in cold and warm PDO phases. This is related to movement of the precipitation center driven by the shift in different PDO phases. Moreover, we compared more high resolution geological proxies with the PDO, including stalagmites and tree rings, in East China over the past century. The results indicate that variations of studied geological proxies are generally well correlated with the PDO but have some differences. Finally, longer variations of sediment grain sizes in the Changjiang and Huanghe estuaries are compared with a reconstructed PDO over the last 200 years; sediment grain sizes were still correlated with the PDO, implying that sediment grain size may be used as a new proxy for studying the long-term behavior of the PDO. This result supports previous knowledge of the PDO impact on East China climate evolution and offers a new proxy for further PDO study. Our study will improve paleoenvironment reconstruction in East China on a decadal time scale and benefit future climatic predictions.     

Carbon pools and fluxes in the China Seas and adjacent oceans

The China Seas include the South China Sea, East China Sea, Yellow Sea, and Bohai Sea. Located off the Northwestern Pacific margin, covering 4700000 km~2 from tropical to northern temperate zones, and including a variety of continental margins/basins and depths, the China Seas provide typical cases for carbon budget studies. The South China Sea being a deep basin and part of the Western Pacific Warm Pool is characterized by oceanic features; the East China Sea with a wide continental shelf, enormous terrestrial discharges and open margins to the West Pacific, is featured by strong cross-shelf materials transport; the Yellow Sea is featured by the confluence of cold and warm waters; and the Bohai Sea is a shallow semiclosed gulf with strong impacts of human activities. Three large rivers, the Yangtze River, Yellow River, and Pearl River, flow into the East China Sea, the Bohai Sea, and the South China Sea, respectively. The Kuroshio Current at the outer margin of the Chinese continental shelf is one of the two major western boundary currents of the world oceans and its strength and position directly affect the regional climate of China. These characteristics make the China Seas a typical case of marginal seas to study carbon storage and fluxes. This paper systematically analyzes the literature data on the carbon pools and fluxes of the Bohai Sea,Yellow Sea, East China Sea, and South China Sea, including different interfaces(land-sea, sea-air, sediment-water, and marginal sea-open ocean) and different ecosystems(mangroves, wetland, seagrass beds, macroalgae mariculture, coral reefs, euphotic zones, and water column). Among the four seas, the Bohai Sea and South China Sea are acting as CO_2 sources, releasing about0.22 and 13.86–33.60 Tg C yr~(-1) into the atmosphere, respectively, whereas the Yellow Sea and East China Sea are acting as carbon sinks, absorbing about 1.15 and 6.92–23.30 Tg C yr~(-1) of atmospheric CO_2, respectively. Overall, if only the CO_2 exchange at the sea-air interface is considered, the Chinese marginal seas appear to be a source of atmospheric CO_2, with a net release of 6.01–9.33 Tg C yr~(-1), mainly from the inputs of rivers and adjacent oceans. The riverine dissolved inorganic carbon (DIC) input into the Bohai Sea and Yellow Sea, East China Sea, and South China Sea are 5.04, 14.60, and 40.14 Tg C yr~(-1),respectively. The DIC input from adjacent oceans is as high as 144.81 Tg C yr~(-1), significantly exceeding the carbon released from the seas to the atmosphere. In terms of output, the depositional fluxes of organic carbon in the Bohai Sea, Yellow Sea, East China Sea, and South China Sea are 2.00, 3.60, 7.40, and 5.92 Tg C yr~(-1), respectively. The fluxes of organic carbon from the East China Sea and South China Sea to the adjacent oceans are 15.25–36.70 and 43.93 Tg C yr~(-1), respectively. The annual carbon storage of mangroves, wetlands, and seagrass in Chinese coastal waters is 0.36–1.75 Tg C yr~(-1), with a dissolved organic carbon(DOC) output from seagrass beds of up to 0.59 Tg C yr~(-1). Removable organic carbon flux by Chinese macroalgae mariculture account for 0.68 Tg C yr~(-1) and the associated POC depositional and DOC releasing fluxes are 0.14 and 0.82 Tg C yr~(-1), respectively. Thus, in total, the annual output of organic carbon, which is mainly DOC, in the China Seas is 81.72–104.56 Tg C yr~(-1). The DOC efflux from the East China Sea to the adjacent oceans is 15.00–35.00 Tg C yr~(-1). The DOC efflux from the South China Sea is 31.39 Tg C yr~(-1). Although the marginal China Seas seem to be a source of atmospheric CO_2 based on the CO_2 flux at the sea-air interface, the combined effects of the riverine input in the area, oceanic input, depositional export,and microbial carbon pump(DOC conversion and output) indicate that the China Seas represent an important carbon storage area.     

Enhanced red fluorescence emission in the oxygen minimum zone of the Arabian Sea

 Depth profiles of fluorescence at several excitation and emission wavelengths were measured along with CTD data during the cruise So119 of RV Sonne in the Arabian Sea from 12 May to 10 June 1997. In addition to chlorophyll fluorescence from phytoplankton in the near-surface layer, the profiles in the oxygen minimum region well below the euphotic zone show enhanced red fluorescence. Red fluorescence intensity is inversely related to the oxygen concentration in intermediate and deep waters. A relationship to characteristic water masses of the region cannot be found in the data, and this holds also with chemical data such as DOC. Absorbance spectra of water samples taken in the oxygen minimum zone show an absorption band at 420 nm wavelength with about 50 nm bandwidth, much weaker than gelbstoff absorbance in the same wavelength range. The absorption band remains stable after sample filtration with 0.45 μm glass fibre filters. Hence, the size of the absorbing matter is in the range of dissolved molecules or particles much smaller than 1 μm. Fluorescence spectra of unfiltered samples with 420 nm excitation show a weak emission band at 600 nm and a more pronounced one at 660 nm wavelength. The trailing edge of the 660 nm band falls into the range of chlorophyll emission, thus giving rise to the observed depth profiles of red fluorescence in the oxygen minimum zone. Red fluorescence measured on samples remain stable during a few hours after sampling even in the presence of oxygen. It is not detectable after several weeks of sample storage in the dark and cannot be reproduced even after depletion of dissolved oxygen. Received: 22 May 2002 / Accepted: 18 February 2003 Responsible Editor: Andreas Oschlies Acknowledgements. This work was supported by a grant from the Federal Minister of Education and Technology, Bonn, within the frame work of the JGOFS Arabian Sea program. We are grateful to the captain and the crew of RV Sonne for their support. We are indebted to Mrs. Kirsten Neumann from the Institute of Marine Chemistry and Biogeochemistry of the University of Hamburg for providing the oxygen data, and to Mr. Nikolai Delling from the same institute for making the DOC and chlorophyll data available to us.     

Impact of anthropogenic drivers on subaqueous topographical change in the Datong to Xuliujing reach of the Yangtze River

Changes of subaqueous topography in shallow offshore water pose safety risks for embankments,navigation,and ports.This study conducted measurements of subaqueous topography between Datong and Xuliujing in the Yangtze River using a Sea Bat 7125 multi-beam echo sounder,and the channel change from 1998 to 2013 was calculated using historical bathymetry data.The study revealed several important results:(1)the overall pattern of changes through the studied stretch of the river was erosion–deposition–erosion.Erosion with a volume 700×10~6m~3occurred in the upper reach,deposition of about 204×10~6m~3occurred in the middle reach,and erosion of about 602×10~6m~3occurred in the lower reach.(2)Dunes are the most common microtopographic feature,accounting for 64.3%of the Datong to Xuliujing reach,followed by erosional topography and flat river topography,accounting for 27.6%and 6.6%,respectively.(3)Human activities have a direct impact on the development of the microtopography.For instance,the mining of sand formed holes on the surface of dunes with lengths of 20–35 m and depths of 3–5 m.We concluded that the overall trend of erosion(net erosion volume of 468×10~6m~3)occurred in the study area mainly because of the decreased sediment discharge following the closure of the Three Gorges Dam.However,other human activities were also impact factors of topographic change.Use of embankments and channel management reduced channel width,restricted river meandering,and exacerbated the erosion phenomenon.     

Sensitivity study of the seasonal mean circulation in the northern South China Sea

A study of the circulation in the northern South China Sea （SCS） is carried out with the aid of a three-dimensional, high-resolution regional ocean model. One control and two sensitivity experiments are performed to qualitatively investigate the effects of surface wind forcing, Kuroshio intrusion, and bottom topographic influence on the circulation in the northern SCS. The model results show that a branch of the Kuroshio in the upper layer can intrude into the SCS and have direct influence on the circulation over the continental shelf break in the northern SCS. There are strong southward pressure gradients along a zonal belt largely seaward of the continental slope. The pressure gradients are opposite in the southern and northern parts of the Luzon Strait, indicating inflow and outflow through the strait, respectively. The sensitivity experiments suggest that the Kuroshio intrusion is responsible for generating the imposed pressure head along the shelf break and has no obvious seasonal variations. The lateral forcing through the Luzon Strait and Taiwan Strait can induce the southwestward slope current and the northeastward SCS Warm Current in the northern SCS. Without the lateral forcing, there is the continental slope. The wind forcing mainly causes the The wind-induced water pile-up results in the southward no high-pressure-gradient zonal belt seaward of seasonal variation of the circulation in the SCS. high pressure gradient along the northwestern boundary of the basin. Without the blocking of the plateau around Dongsha Islands, the intruded Kuroshio tends to extend northwest and the SCS branch of the Kuroshio becomes wider and stronger. The analyses presented here are qualitative in nature but should lead to a better understanding of the oceanic responses in the northern SCS to these external influence factors.     

Some Insights into Topographic,Elastic and Self-gravitation Interaction in Modelling Ground Deformation and Gravity Changes in Active Volcanic Areas

Surface displacements and gravity changes due to volcanic sources are influenced by medium properties. We investigate topographic, elastic and self-gravitation interaction in order to outline the major factors that are significant in data modelling. While elastic-gravitational models can provide a suitable approximation to problems of volcanic loading in areas where topographic relief is negligible, for prominent volcanoes the rough topography could affect deformation and gravity changes to a greater extent than self-gravitation. This fact requires the selection, depending on local relief, of a suitable model for use in the interpretation of surface precursors of volcanic activity. We use the three-dimensional Indirect Boundary Element Method to examine the effects of topography on deformation and gravity changes in models of magma chamber inflation/deflation. Topography has a significant effect on predicted surface deformation and gravity changes. Both the magnitude and pattern of the geodetic signals are significantly different compared to half-space solutions. Thus, failure to account for topographic effects in areas of prominent relief can bias the estimate of volcanic source parameters, since the magnitude and pattern of deformation and gravity changes depend on such effects.     

System parameters of soil foundations for time domain dynamic analysis

Soil-structure interaction analysis is usually carried out in the frequency domain, because the compliance functions of the half-space are known only in the frequency domain. Since non-linear analysis cannot be carried out in the frequency domain, a system with frequency independent parameters is used to represent the half-space soil medium so that a nonlinear analysis in the time domain becomes possible. The objective of this paper is to propose a system with lumped parameters, which are independent of frequency, to represent the half-space soil medium. The proposed frequency independent system consists of a number of real discrete structure elements; thus the existing dynamic analysis programs may be adoptable with little modification. In this paper, the parameters are found by minimizing the sum of the squares of deviations between the steady-state responses of the theoretical half-space model and those of the lumped parameter system over a specified frequency range. Once the parameters have been found, the lumped parameter system can be used in practical applications for time domain dynamic analysis of either linear or non-linear structures. In comparison with the dynamic response of the theoretical half-space model, the lumped parameter system yields satisfactory results.     

Organic structure and possible origin of ancient charred paddies at Chuodun Site in southern China

A number of ancient charred paddies with a ¹⁴C dating of about 5900 a BP were recovered in the sixth excavation at Chuodun Site and are assigned to the Majiabang culture (7–6 ka BP). To understand their formation mechanism, the ancient charred paddies were compared to modern paddies using FT-IR spectrum and thermaogravimetric analysis. At the same time, modern charred paddies were made in helium by the laboratory method, and the structural characteristics of them and the ancient ones were revealed using CP/MAS-¹³C-NMR. Our results show there are more aromatic moieties in ancient charred paddies compared to modern paddies. The aliphatic components of modern charred paddies decrease continuously, accompanied by the accumulation of aromatic components, when the duration and temperature of oxidation increase, and the structure buildings of modern charred paddies are more similar to ancient ones. Given the planting manner of paddies during Majiabang culture period, these ancient charred paddies might be a result of the original farming mode involving fire. Supported by the National Natural Science Foundation of China (Grant No. 40571088)     

Absorption properties of urban/suburban aerosols in China

The broadband diffuse radiation method is improved to retrieve the aerosol refractive index imaginary part （AIP） and broadband （400-1000 nm mean） single scattering albedo （SSA）. In this method, four sets of SSA selection criteria are proposed for quality control. The method is used to retrieve AIP, SSA and absorptive optical thickness （AbOT） from routine hourly-exposed pyrheliometer and paranometer measurements over 11 sites （meteorological observatories） in China during 1998-2003. Apart from one suburban site （Ejin Qi）, the other urban sites are all located around big or medium cities. As shown in the retrieval results, annual mean SSA during 1998-2003 changes from 0.941 （Wuhan） to 0.849 （Lanzhou）, and AIP from 0.0054 to 0.0203. The 11-site average annual mean SSA and AIP are 0.898 and 0.0119, respectively. SSA during winter is smaller for most sites. There is an evidently positive correlation between SSA and aerosol optical thickness （AOT） for all sites. There is also a positive correlation between SSA and relative humidity for most sites, but a negative correlation for a few sites, such as Kashi and ǚrǚmqi in Northwest China.