Municipal Wastewater Treatment Using Moringa oleifera Seed and Press Cake Powder: A Comparative Analysis

Moringa oleifera (MO), also known as drumstick tree, has gained worldwide attention among researchers and policy makers, for showing its remarkable potential in environmental management. Recently, MO seed or press cake (a by-product of oil extraction industry) powder has also emerged as an alternative and promising coagulant for environmental remediation. In this view, attempts have been made in this study to evaluate the efficacy of MO seed and press cake powder (MSP & PCP) for the treatment of municipal wastewater. Both MSP and PCP are characterized by using swelling ratio, scanning and transmission electron microscopy analysis. The effect of various operational parameters such as coagulation–flocculation pH (2–10), coagulant dosage (0.1–1 g L⁻¹), and sedimentation time (0–180 min), etc., is investigated to understand the potential of MSP and PCP. At optimized operational conditions, sedimentation kinetics is also performed suggesting that the treatment process is being governed by the second-order kinetic model. The chemical and biological oxygen demand removals at optimized conditions are observed as follows: ≈38 and ≈73% for MSP and ≈47 and ≈85% for PCP. Overall, the results of the present study elucidated that PCP can be employed as a promising alternative of MSP for municipal wastewater with improved treatment efficiencies.     

An advanced numerical model of elastomeric seismic isolation bearings

The nuclear accident at Fukushima Daiichi in March 2011 has led the nuclear community to consider seismic isolation for new large light water and small modular reactors to withstand the effects of beyond design basis loadings, including extreme earthquakes. The United States Nuclear Regulatory Commission is sponsoring a research project that will quantify the response of low damping rubber (LDR) and lead rubber (LR) bearings under loadings associated with extreme earthquakes. Under design basis loadings, the response of an elastomeric bearing is not expected to deviate from well‐established numerical models, and bearings are not expected to experience net tension. However, under extended or beyond design basis shaking, elastomer shear strains may exceed 300% in regions of high seismic hazard, bearings may experience net tension, the compression and tension stiffness will be affected by isolator lateral displacement, and the properties of the lead core in LR bearings will degrade in the short‐term because of substantial energy dissipation. New mathematical models of LDR and LR bearings are presented for the analysis of base isolated structures under design and beyond design basis shaking, explicitly considering both the effects of lateral displacement and cyclic vertical and horizontal loading. These mathematical models extend the available formulations in shear and compression. Phenomenological models are presented to describe the behavior of elastomeric isolation bearings in tension, including the cavitation and post‐cavitation behavior. The elastic mechanical properties make use of the two‐spring model. Strength degradation of LR bearing under cyclic shear loading due to heating of lead core is incorporated. The bilinear area reduction method is used to include variation of critical buckling load capacity with lateral displacement. The numerical models are coded in OpenSees, and the results of numerical analysis are compared with test data. The effect of different parameters on the response is investigated through a series of analyses. Copyright © 2014 John Wiley & Sons, Ltd.     

Nutrient chemistry and salinity mapping of the Delhi aquifer,India: source identification perspective

Present study is an effort to distinguish between the contributions of natural weathering and anthropogenic inputs towards high salinity and nutrient concentrations in the groundwater of National Capital Territory (NCT) Delhi, India. Apart from the source identification, the aquifer of entire territory has been characterized and mapped on the basis of salinity in space and water suitability with its depth. Major element chemistry, conventional graphical plots and specific ionic ratio of Na⁺/Cl⁻, SO₄ ²⁻/Cl⁻, Mg²⁺/Ca²⁺ and Ca²⁺/(HCO₃ ⁻ + SO₄ ²⁻) are conjointly used to distinguish different salinization sources. Results suggest that leaching from the various unlined landfill sites and drains is the prime cause of NO₃ ⁻ contamination while study area is highly affected with inland salinity which is geogenic in origin. The seasonal water level fluctuation and rising water level increases nutrients concentration in groundwater. Mixing with old saline sub-surface groundwater and dissolution of surface salts in the salt affected soil areas were identified as the principle processes controlling groundwater salinity through comparison of ionic ratio. Only minor increase of salinity is the result of evaporation effect and pollution inflows. The entire territory has characterized into four groups as fresh, freshening, near freshening and saline with respect to salinity in groundwater. The salinity mapping suggests that in general, for drinking needs, groundwater in the fresh, freshening and near freshening zone is suitable up to a depth of 45, 20 and 12 m, respectively, while the saline zones are unsuitable for any domestic use. In the consideration of increasing demand of drinking water in the area; present study is vital and recommends further isotopic investigations and highlights the need of immediate management action for landfill sites and unlined drains.     

Fractal analysis of magnetite grains — implications for interpreting deformation mechanism

In the present study, the grain size (d) and shape of 225 magnetite grains, that crystallized at T>600°C in a syntectonic granite (Godhra Granite, India) are evaluated and implications of data to decipher deformation mechanism of magnetite are discussed. Fractal (ruler) dimension (D) analysis of magnetite grains is performed and it is demonstrated that they show fractal behaviour. Smaller magnetite grains tend to be more serrated than the larger ones, which is manifested in the higher fractal (ruler) dimension (D) of the former. Assuming a natural strain rate ranging between 10⁻¹⁰ s⁻¹ and 10⁻¹⁴ s⁻¹, the grain size data fall dominantly in the dislocation creep field of the existing deformation mechanism map of magnetite for 630°C. However, SEM-EBSD studies reveal that subgrains are absent in the magnetite grains and they did not undergo dislocation creep. Thus it is inferred that the shape of magnetite grains was not controlled by dislocation creep. It is concluded that the higher serration and increased fractal dimension of finer magnetite grains implies the importance of diffusion creep as an important deformation mechanism at high-T for magnetite in polymineralic rocks.     

Long-term changes in the within-season temporal profile of southwest monsoon over western India

This paper presents results of a study of long term trends in the characteristics of the within-season temporal profile of southwest monsoon rainfall over western India during the last five decades in relation to global warming induced regional climate change. In contrast to recent climate change analyses and projections, no significant long-term trends have been observed in this study. Slow decadal scale variations observed are analysed in relation to Pacific Decadal Oscillations (PDO). Daily variations in rainfall anomaly show opposite characteristics during negative and positive phases of PDO. The above-normal rainfall (>25%) is found during the starting phase of monsoon in negative PDO. Over the last decade, i.e., during 2000–2007, the seasonal rainfall amount, as well as seasonal span of southwest monsoon over western India is indicative of a gradual increase.     

Inter-decadal modulation of the impact of ENSO on Australia

 The success of an ENSO-based statistical rainfall prediction scheme and the influence of ENSO on Australia are shown to vary in association with a coherent, inter-decadal oscillation in surface temperature over the Pacific Ocean. When this Inter-decadal Pacific Oscillation (IPO) raises temperatures in the tropical Pacific Ocean, there is no robust relationship between year-to-year Australian climate variations and ENSO. When the IPO lowers temperature in the same region, on the other hand, year-to-year ENSO variability is closely associated with year-to-year variability in rainfall, surface temperature, river flow and the domestic wheat crop yield. The contrast in ENSO’s influence between the two phases of the IPO is quite remarkable. This highlights exciting new avenues for obtaining improved climate predictions. Received: 21 October 1998 / Accepted: 27 November 1998     

Discrimination between Babul plantations and Mustard crop using Polarimetric C- and L- band data

Radar sensors can be used for large-scale vegetation mapping and monitoring using backscattering coefficients in different polarizations and wavelength bands. C-band space borne SAR is widely used for the classification of agricultural crops, but can only perform a limited discrimination of various tree species. This paper presents the results of discrimination between mustard crop and babul plantation (Prosopis sp.) using quad polarisation Radarsat 2 and ALOS PALSAR data. Study area is comprised of dense babul plantation along the canal, mustard crop on one side of the canal and Fallow land near to Ramgarh village of Jaisalmer district. Three bands of Radarsat (HH, HV and VV) acquired during peak mustard crop growth stage were integrated with four polarizations (HH, HV, VH and VV) of ALOS PALSAR acquired when crop cover was absent. Using only Radarsat data Jefferies-Matusita (JM) separability between mustard crop and babul plantation was found to be poor (710). Where as in the seven band combination the separability was observed to be high (1374). Among the different polarizations three layer combination, highest separability was observed using cross polarizations (HV and VH) of L-band with any one of the Radarsat Polarisation (HH/HV/VV). This combination of C- and L-band resulted in easy separation of mustard and babul plantation which was otherwise difficult using only Radarsat data.