Green clinopyroxenes and associated phases in a potassium-rich lava from the Leucite Hills,Wyoming

Green, salitic pyroxenes occur as megacrysts and as cores in diopsidic pyroxene phenocrysts and microphenocrysts in a wyomingite lava from Hatcher Mesa, Leucite Hills, Wyoming. Al-rich phlogopite (16–21% Al₂O₃), apatite, Fe-Ti-oxide, Mg-rich olivine (Fo₉₃) and orthopyroxene (En₆₁) also occur as megacrysts or as inclusions in diopside phenocrysts. All of these phases are found in ultramafic xenoliths in the host lava, and petrographic and chemical evidence is presented that the megacrysts originate by the disaggregation of the xenoliths. It is concluded that the latter are accidental fragments of the wall rocks traversed by the wyomingite magma and it is suggested that the clinopyroxene-rich xenoliths, from which the green pyroxenes are derived, formed in the upper mantle as a result of local metasomatism or by crystallization from magmas of unknown composition during an earlier igneous event. The precise role of the clinopyroxene-rich xenoliths (which also contain apatite, Fe-Ti-oxide and amphibole) in the genesis of the Leucite Hills magmas cannot be elucidated on the basis of the available data, but it is unlikely that they represent the source material from which these magmas are derived.     

Assessing tectonic and climatic causal mechanisms in foreland‐basin stratal architecture: insights from the Alborz Mountains,northern Iran

The southern foreland basin of the Alborz Mountains of northern Iran is characterized by an approximately 7.3‐km‐thick sequence of Miocene sedimentary rocks, constituting three basin‐wde coarsening‐upward units spanning a period of 10⁶ years. We assess available magnetostratigraphy, paleoclimatic reconstructions, stratal architecture, records of depositional environments, and sediment‐provenance data to characterize the relationships between tectonically‐generated accommodation space (A) and sediment supply (S). Our analysis allows an inversion of the stratigraphy for particular forcing mechanisms, documenting causal relationships, and providing a basis to decipher the relative contributions of tectonics and climate (inferred changes in precipitation) in controlling sediment supply to the foreland basin. Specifically, A/S > 1, typical of each basal unit (17.5–16.0, 13.8–13.1 and 10.3–9.6 Ma), is associated with sharp facies retrogradation and reflects substantial tectonic subsidence. Within these time intervals, arid climatic conditions, changes in sediment provenance, and accelerated exhumation in the orogen suggest that sediment supply was most likely driven by high uplift rates. Conversely, A/S < 1 (13.8 and 13.8–11 Ma, units 1, and 2) reflects facies progradation during a sharp decline in tectonic subsidence caused by localized intra‐basinal uplift. During these time intervals, climate continued to be arid and exhumation active, suggesting that sediment supply was again controlled by tectonics. A/S < 1, at 11–10.3 Ma and 9‐6–7.6 Ma (and possibly 6.2; top of units 2 and 3), is also associated with two episodes of extensive progradation, but during wetter phases. The first episode appears to have been linked to a pulse in sediment supply driven by an increase in precipitation. The second episode reflects a balance between a climatically‐induced increase in sediment supply and a reduction of subsidence through the incorporation of the proximal foreland into the orogenic wedge. This in turn caused an expansion of the catchment and a consequent further increase in sediment supply. Copyright © 2013 John Wiley & Sons, Ltd.     

Geochemical characterisation of organic matter in Keg River Formation (Elk point group, Middle Devonian), La Crete Basin, Western Canada

Carbonates from the Keg River Formation, La Crete Basin, Alberta, western Canada were examined in order to define: (a) oil source rock potential; (b) bulk maceral composition; (c) extract yield; and finally (d) facies variations using PY-GC-MS. Thirty samples from 6 different wells were examined from the lower Keg River member and 4 from the upper Keg River member using conventional geochemical methods. As maturity differences are absent within the sample set, variations in TOC, T_max, hydrogen index, organic petrography and extract yields are caused by variability in organic matter input, which is revealed by molecular characterisation using PY-GC-MS. Lower Keg River member bituminous wackestones are excellent potential source rocks containing Types I–II and Type II organic matter. Types I–II organic matter contains large well preserved (up to 200μm in diameter) thick-walled Tasmanites (10–15% of sample) and akinete algal cells indicative of algal blooms within an amorphous bituminite. Type II organic matter contains a higher proportion of degraded alginites/bituminite relative to well-preserved alginites. Extract yields (mg/g TOC) were seen to increase from Types I–II to Type II organic matter. PY-GC-MS revealed that 1,2,3,4-tetramethylbenzene was a major peak in most samples. This is a pyrolysis product arising from β-cleavage of C₄₀ diaromatic carotenoids incorporated within the kerogen during diagenesis. The source of this compound is thought to be from an unknown diaromatic compound with a 2,3,6-/3,4,5-trimethyl substitution pattern and isorenieratene, which is specific to photosynthetic green sulphur bacteria (Chlorobiaceae) suggesting that the photic zone was at least partially anoxic during deposition of these samples. The relative abundance of this compound/n-C11-alkene and organic sulphur (calculated from the thiophene ratio) both increase from Types I–II to Type II organic matter. This trend was grossly similar to the trend seen in the variability of extract yield with hydrogen index. A similar trend for HI and T_max indicates samples containing a higher proportion of degraded alginites/bituminite relative to well-preserved alginite are more labile than Type I–II organic matter. Upper Keg River member marls contain Type II organic matter, which is characterised by heavily degraded algal material within a bituminous groundmass. Pyrolysates of two of the marl samples contain only low amounts of 1,2,3,4-tetramethylbenzene, in contrast to the bituminous wackestones, indicating that the depositional environment/source input was different during deposition of the marl samples. Although both marls contain similar organic matter, their pyrolysates were significantly different. One marl (1141.9 m) was highly paraffinic containing dominantly short-chain alkene/alkane doublets, while the other marl (1137.6 m) contained a bimodal n-alkane/alkene distribution and high amounts of alkylphenols, which may be derived from preservation of resistant algal polyphenolic molecules or suggest a terrestrial input.     

Assessing climate change impacts in the European north

Global climate change and its regional manifestation will result in significant impacts in the European North. However, in order to determine the consequences of such impacts, a holistic, integrated assessment is needed. This paper sets the stage for the remainder of this volume by describing an attempt to derive such an assessment for the Barents Sea Region through the EU-funded BALANCE project. The paper explains some of the major methodologies employed in the study. It also provides insight into major results obtained and attempts to answer a number of overarching questions. It will be shown that climate change does present a significant threat to environmental and societal integrity in the study region. However, it will also be shown that stakeholders regard other drivers of future changes (economical, political developments) at least as equally important for their personal lives.     

Plate tectonics and intracratonic mountain ranges in Morocco - The mesozoic-cenozoic development of the Central High Atlas and the Middle Atlas

Plate tectonic processes in the Atlantic and western Tethyan realm directed the post-Variscan sedimentary and structural evolution of the High Atlas and Middle Atlas intracontinental mountain ranges of Morocco. Plate movements caused a reactivation of an inherited pan-African or Hercynian fault pattern by the variation of stress regimes through time. This resulted in strike-slip as well as vertical tectonics. During times of relative tectonic quiescence eustatic sea-level changes governed the sedimentary development. The most important, often interacting, global tectonic determinants are: taphrogenesis of the NW-African continental margin lasting until the Early Cretaceous (Triassic rifting and subsequent mid-Atlantic spreading), strike-slip-faulting at the Newfoundland-Gibraltar fault zone (Liassic — earliest Eocene), and continental convergence between Europe (Iberia) and Africa which started in the Late Cretaceous and reached its acme in the Neogene. In the realm of the Central High Atlas and the Middle Atlas the interaction of these processes triggered continental rifting (Triassic) and subsequent marine flooding of the intergrown riftgrabens prograding from the Tethys realm (Early Jurassic — earliest Middle Jurassic). After its abortion, the former Atlas rift was filled up with marine sediments (Bajocian — Bathonian), followed by continental redbeds and final uplift (late Mid Jurassic — late Early Cretaceous). Eustatic sea-level changes mostly governed the sedimentary evolution from Aptian to latest Mid Eocene. After a first weak uplift of the central High Atlas during the Senonian major uplift of the intracontinental chains commenced at the Mid/ Late Eocene transition. Diastrophism of the Atlas ranges during the Miocene and Pliocene coincided with the main orogenic movements of the Betico-Rifean arc.

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Zusammenfassung Die post-variskische sedimentäre und strukturelle Entwicklung der intrakontinentalen Gebirgsketten des Hohen und des Mittleren Atlas wurde durch plattentektonische Prozesse im atlantischen und westmediterranen Raum gesteuert, die auf ein ererbtes panafrikanisches bzw. variskisches Störungsmuster einwirkten. Zu Zeiten relativer tektonischer Ruhe bestimmten eustatische Meeresspiegelschwankungen die sedimentäre Entwicklung. Die von horizontaler und vertikaler Bruchtektonik beherrschte Atlas-Tektonik wurde durch in der Zeit wechselnde Streßfelder bestimmt. Wichtigste großtektonische, oft zusammenwirkende Steuerungsfaktoren waren: die bis in die Unterkreide wirkende Taphrogenese im Bereich des NW-afrikanischen Kontinentalrandes (triadisches Rifting und anschließendes Spreading im Atlantik), Transform-Bewegungen an der Neufundland-Gibraltar-Störungszone zwischen Lias und ältestem Eozän sowie die Konvergenz zwischen Europa (Iberia) und Afrika, welche nach ihrem Beginn in der späten Kreide ihren Höhepunkt im Neogen erreichte. Das Zusammenspiel dieser Faktoren bewirkte im zentralen Hohen Atlas und im Mittleren Atlas die Entstehung kontinentaler Riftgräben während der Trias, die von der Tethys ausgehende Flutung der zusammengewachsenen Riftgräben im Lias und untersten Dogger (Sinemurium — Aalenium) sowie die zuerst marine (Bajocium — Bathonium), dann kontinentale Füllung und Heraushebung der stillgelegten Riftzone zwischen spätem Mitteljura und später Unterkreide. Zwischen Apt und Ende des Mitteleozän kontrollierten vor allem eustatische Meeresspiegelschwankungen die sedimentäre Entwicklung. Nach ersten Hebungen im zentralen Hohen Atlas während des Senon begann die eigentliche Heraushebung der intrakontinentalen Ketten an der Wende Mittel-/Obereozän. Die mio-/pliozäne Hauptphase der Atlas-Tektogenese war zeitgleich mit der Orogenese im Betico-Rif-Bogen.

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Résumé L'évolution sédimentaire et structurale postvarisque des chaînes intracontinentales du Haut et du Moyen Atlas a été régie par les processus de la tectonique des plaques qui se déroulaient dans l'Atlantique et dans la Méditerrannée occidentale. Ces mouvements de plaques ont réactivé un ensemble de failles héritées des phases pan-africaine et hercynienne, en y produisant des déplacements verticaux et horizontaux en réponse aux fluctuations temporelles des champs de contraintes. Au cours des périodes de calme tectonique relatif, les changements eustatiques du niveau de la mer ont déterminé le régime de la sédimentation. Les facteurs de la tectonique les plus importants, à action d'ailleurs souvent combinée, ont été: la traphrogenèse, active jusqu'au Crétacé inférieur, de la marge nord-ouest du continent africain (rifting triasique et ouverture subséquente de l'Atlantique), les mouvements de décrochement le long de la zone transformante de Terre Neuve-Gibraltar depuis le Lias jusqu'au début de l'Eocène, ainis que la convergence entre l'Europe (Ibérie) et l'Afrique qui débuta au Crétacé supérieur pour culminer au Néogène. Dans le Haut Atlas central et dans le Moyen Atlas, le jeu combiné de ces facteurs a provoqué la formation de grabens continentaux (Trias) puis leur envahissement par la mer à partir de la Téthys (Lias-Dogger inférieur). Après la fin de son activité, le rift atlasique a été comblé par des sédiments, d'abord marins (Bajocien-Bathonien), puis continentaux jusqu'au soulèvement final (fin du Jurassique moyen — fin du Crétacé inférieur). De l'Aptien à la fin de l'Eocène moyen, l'évolution sédimentaire a été régie par les changements eustatiques du niveau de la mer. Après un premier soulèvement modéré du Haut Atlas central au cours du Sénonien, le soulèvement majeur des chaînes intracontinentales débuta à la limite Eocène moyen-Eocène supérieur. Le diastrophisme de l'Atlas au cours du Mio-Pliocène a coïncidé avec les mouvements orogéniques de l'arc bético-rifain.

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Scientific detector workshop 2022 on-sky performance verification of near-infrared e−APD technology for wavefront sensing and demonstration of e−APD pixel performance to improve the sensitivity of large science focal planes

Near-infrared adaptive optics as well as fringe tracking for coherent beam combination in optical interferometry require the development of high-speed sensors. Because of the high speed, a large analog bandwidth is required. The short exposure times result in small signal levels which require noiseless detection. Both requirements cannot be met by state-of-the-art conventional CMOS technology of near-infrared arrays as has been attempted previously. A total of five near-infrared SAPHIRA 320 × 256 pixel HgCdTe e⁻APD arrays have been deployed in the wavefront sensors and in the fringe tracker of the VLTI instrument GRAVITY. The current limiting magnitude for coherent exposures with GRAVITY is m_k = 19, which is made possible with ADP technology. New avalanche photo-diode array (APD) developments since GRAVITY include the extension of the spectral sensitivity to the wavelength range from 0.8 to 2.5 μm. After GRAVITY a larger format array with 512 × 512 pixels has been developed for both AO applications at the ELT and for long integration times. Since dark currents of <10⁻³ e⁻/s have been demonstrated with 1Kx1K e⁻APD arrays and 2Kx2K e⁻APD arrays have already been developed, the possibilities and adaptations of e⁻APD technology to provide noiseless large-format science-grade arrays for long integration times are also discussed.