The photoelectron spectra of some Tl-Sb sulphosalts

The results of X-ray induced photoelectron spectroscopy (XPS) experiments on several phases of the ternary system Tl-Sb-S are reported. The binding energies of the inner S, Sb and Tl electrons increase with increasing quantities of Sb and decreasing amounts of Tl in these compounds. This is explained by the influences of the proportions of the bonded metals on the effective electron affinity of S. The higher proportions of the more electronegative element bonded to S cause the increase of its effective electron affinity. The results for Tl₂S (carlinite), Tl₃SbS₃, TlSbS₂ (weissbergite), TlAsS₂ (lorandite) and Sb₂S₃ (antimonite) can be interpreted in this way. The results for Tl₄S₃ suggest a predominantly covalent character of bonding for both Tl(III) and Tl(I), which are present in this sulfide. From comparison with Tl₃SbS₄ it could be supposed that Tl(III)-S bond has a more covalent character than Sb(V)-S bond. The results for Tl₃SbS₄ are in agreement with crystal structure data and the results of Moessbauer spectroscopy. For AsS (realgar) the binding energies of the inner electrons of As and S significantly increase, showing that the electrons in molecular orbitals are less strongly bonded to individual atoms, as compared to pure elements. The results for the amorphous TlSb₅S₈ (corresponding in composition to parapierrotite) suggest that in amorphous compound the Tl-S bonding is stronger and the coordination of Tl more regular than in a crystalline one.     

Polish forest ecosystems: The influence of changes in the economic system on the carbon balance

In order to study the effects of a change in the economic system on carbon balance at a national scale, a balance of the carbon influx and effluxes was prepared for forest ecosystems in Poland for 1988, and was repeated for 1990. The year 1988 was the first year of drastic economic changes (and severe crises) in Poland. Two entirely different approaches were used to estimate the carbon influx into a forest ecosystem. The forest inventory approach was based on data from conventional measurements of merchantable timber in forests, whereas the carbon flux and allocation approach was based on the estimate of net photosynthetic productivity of forest ecosystems to calculate the carbon influx. Results from both approaches were within the range 1.17 to 5.77t C/ha/yr which most likely defined lower and upper limits for the carbon influx into forest ecosystems in Poland. On the national scale, the carbon influx into Polish forest ecosystems was estimated by the forest inventory approach to be about 12.8 Mt C/yr. This result was similar for both years. Efflux of carbon from Polish forest ecosystems resulted almost entirely from the decay of logging residues. The efflux in 1990 (3.82 Mt C/yr) was about 26% lower than that in 1988. Storage of the carbon in Polish forest ecosystems (including an estimate of the carbon pool in forest soils) was 1.8% greater in 1990 (2518 Mt C) than in 1988, when it equalled 2473 Mt C.     

Possible influences of solar radiation variations on the atmospheric circulation in the northern hemisphere of the earth

The strength of the circumpolar zonal circulation of the atmosphere in the northern hemisphere, expressed by an index calculated from the air pressure gradient between 35° N and 65°N, shows a remarkable secular change in this century in the years 1935 to 1938, and probably again in the years after 1970. A contemporary change and parallel course with a high positive correlation can be found in a solar radiation index calculated by means of sunspot numbers and solar faculae areas. A good correlation was also found between this solar radiation index and a series of UV measurements on Mt. Wilson. The possible mechanism of action in the atmosphere will be discussed, and it is shown that this solar radiation index is also correlated with circulation parameters in the troposphere and stratosphere over Europe. There are indications of a decrease of the action from the upper to the lower atmosphere. The consequences of this secular change of circulation for the climatic history in the 20th century in Europe are presented and from that a hypothetical retrospective view of the European climatic history before the 20th century, based on the total series of sunspot numbers, is briefly discussed. In a general view with smoothed data it can be concluded that the sun seems to determine the basic structure of the north hemispheric circulation in middle latitudes, if a strong influence of sunspots and solar faculae on the solar radiation is assumed.     

Correlation of the Quaternary terrace sequence in the Lower Rhine valley and northern Alpine foothills of central Europe

Thirteen glacial terraces are known from the western part of the northern Alpine foothills between the Lech and Iller Rivers. In the Lower Rhine region of West Germany, a similar number of terraces are capped by interglacial floodloams and soils. Whereas the environment during individual interglaciations did not differ substantially, the glaciations were progressively more severe. The Main Terrace system of the Rhine may be an exception. The duration of the Quaternary, starting at the base of Praetiglian, is estimated at approximately 2 million yr by paleomagnetic dating. The major cold-warm climatic cycles of the earliest Pleistocene lasted approximately 100,000 yr, the same as those of the Brunhes Chron. The intervening Main Terrace system has not yet been climatically subdivided. Correlation with the Netherlands is possible because of an abundance of paleobotanic and paleomagnetic evidence. In the Alpine foothills, stratigraphically useful indicators of warm climates are missing, but analogies in terrace development permit comparison with the Lower Rhine and Danube. The terrace sequence in the Alpine foothills is incomplete, as are those along most of the other rivers in Europe. Some of the older terraces may have been eroded.     

Earthquakes in Switzerland and surrounding regions during 2006

This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during 2006. During this period, 572 earthquakes and 91 quarry blasts were detected and located in the region under consideration. Of these earthquakes, two occurred in conjunction with the construction of the new Gotthard railway tunnel and 165 were induced artificially by the stimulation of a proposed geothermal reservoir beneath the city of Basel. With 20 events with M _L ≥ 2.5, five of which were artificially induced, the seismic activity in the year 2006 was far below the average over the previous 31 years. Nevertheless, six events were felt by the public, most prominently the strongest of the induced Basel events (M _L 3.4), which caused some non-structural building damage. Noteworthy are also the two earthquakes near Cortaillod (M _L 3.2), on the shore of Lake Neuchatel, and in Val Mora (M _L 3.5), between the Engadin and Val Müstair, as well as the 42 aftershocks of the M _L 4.9 Vallorcine earthquake, between Martigny and Chamonix, of September 2005. Editorial handling: Stefan Bucher     

Continuous,Direct Gas-Geochemical Monitoring in Hydrothermal Vents: Installation and Long-Term Operation on Nisyros Island (Greece)

In this paper the installation and long-term operation of a system for continuous monitoring of fumarolic gases is described. Several physicochemical and gas-geochemical parameters such as the concentration of CO₂, H₂S and CO in the fumarolic emissions, as well as the temperatures of the hydrothermal steam and soil in close vicinity of the fumarole and steam pressure are measured in short-time intervals (typically 15 seconds). Data are logged on-site and in parallel transferred to a remote station by digital telemetry. Specially developed software enables the real-time observation of the local conditions in the crater and full bidirectional control of the monitoring system. Fluctuations in the monitored parameters are also reported. From the data presented it can be concluded that environmental conditions (direction and strength of wind, precipitation) will interact with some of the parameters monitored. These influences can only be revealed by continuously operated monitoring systems.     

Conceptualising State‐Controlled Resort Islands for an Environment‐Friendly Development of Tourism: The Maldivian Experience

The Maldives host a sophisticated and competitive international tourist industry which has replaced fishing as the dominant economic activity. With their rich tropical reef ecosystems and the abundant biodiversity of their marine environment, a total of 86 uninhabited islands had been converted into Resort Islands by the end of 2000. Resort Islands are equipped with comprehensive facilities for accommodation, food, recreation and leisure. They are also strictly reserved for foreign tourists and guarantee complete privacy. This gives the benefit of averting conflicts of acculturation with local islanders. In the arena of impacts on the physical environment, however, the consumptive leisure lifestyle of the tourists has been harmful to the Resort Islands as seen in sewage, garbage and waste pollution, as well as reef destruction and beach erosion. While the government of the Maldives takes great effort to harmonise tourism and the environment, the growth of mass tourism in the last 20 years has engendered grave environmental impacts. For future sustainable development of the Resort Islands, the tourists' environmental awareness must be increased to promote greater responsibility for the protection of the fragile coral and reef ecosystems of the Maldives.     

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