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11.
Shane M. Ohline Malcolm R. Reid Shamus L.G. Husheer Kim I. Currie Keith A. Hunter 《Marine Chemistry》2007
Accurate measurement of seawater pH has long been sought by marine chemists (for example: [Dickson, A.G. 1993a. The measurement of sea water pH. Marine Chemistry, 44, 131–142, Dickson, A.G. 1993b. pH buffers for sea water media based on the total hydrogen ion concentration scale. Deep-Sea Research, 40, 107–118; Zhang, 1996; Tapp, M., Hunter, K.A., Currie, K. and Macaskill, B. 2000. Apparatus of continuous-flow underway spectrophotometric measurement of surface water pH. Marine Chemistry 72(2–4), 193–202; Friis, K., Koetzinger, A., Wallace, D.W.R. 2004. Spectrophotometric pH measurement in the ocean: Requirements, design and testing of an autonomous charge-coupled device detector system. Limnology and Oceanography: Methods 2, 126–136]. Recently, such attempts have taken on greater significance as anthropogenic carbon dioxide emissions may create rapidly changing oceanic pH. Spectrophotometric techniques have been accepted generally as the best for determination of seawater pH. Here we report a new technique using thymol blue as the indicator dye and fitting the entire spectrum from 400 to 900 nm rather than measuring the absorbance values at only two or three points in the spectrum. This full-spectrum modelling enables a reduction in signal to noise over other techniques. In the laboratory, we find with seawater samples a pH precision increase of five-fold “within” a sample and seven-fold “between” samples when comparing the full spectrum to the three-point method of analysis [Zhang, H., Byrne, R.H. 1996. Spectrophotometric pH measurements of surface seawater at in-situ conditions: absorbance and protonation behaviour of thymol blue. Marine Chemistry 52, 17–25]. 相似文献
12.
Classification of artificial (man-made) ground 总被引:1,自引:0,他引:1
M. S. Rosenbaum A. A. McMillan J. H. Powell A. H. Cooper M. G. Culshaw K. J. Northmore 《Engineering Geology》2003,69(3-4):399-409
The legacy inherited from anthropogenic processes needs to be addressed in order to provide reliable and up-to-date ground information relevant to development and regeneration in the urban environment. The legacy includes voids as well as anthropogenic deposits (artificial ground). Their characteristics derive from former quarrying and mining activities industrial processes creating derelict ground, variably consolidated made ground, and contaminated groundwater and soils. All need to be systematically assessed to inform the planning process and provide the basis for engineering solutions. Site-specific investigation needs to be conducted on the back of good quality geoscientific data. This comes from ‘field’ survey, remotely sensed data interpretation, historical maps, soil geochemical sampling, and geotechnical investigation. Three-dimensional and, in the future, four dimensional, characterization of superficial deposits is required to reach an understanding of the potential spatial lithological variability of artificial ground and the geometry of important surfaces, i.e. the boundary conditions. The classification scheme for artificial ground outlined in this paper and adopted by the British Geological Survey, will help in achieving this understanding. 相似文献
13.
14.
Chantal Alibert Les Kinsley Malcolm T. McCulloch Felicity McAllister 《Geochimica et cosmochimica acta》2003,67(2):231-246
Massive corals in the Great Barrier Reef, analyzed at high-resolution for Sr/Ca (thermal ionization mass spectrometry) and trace elements such as Ba and Mn (laser ablation inductively coupled plasma mass spectrometry), can provide continuous proxy records of dissolved seawater concentrations, as well as sea surface temperature (SST). A 10-yr record (1989 to 1998) from Pandora Reef, an inshore reef regularly impacted by the freshwater plumes of the Burdekin River, is compared with an overlapping record from a midshelf reef, away from runoff influences. Surface seawater samples, taken away from river plumes, show little variability for Sr/Ca (8484 ± 10 μmol/mol) and Ba (33.7 ± 0.7 nmol/kg). Discrete Ba/Ca peaks in the inshore coral coincide with flood events. The magnitude of this Ba/Ca enrichment is most likely controlled by the amount of suspended sediments delivered to the estuary, which remains difficult to monitor. The maximum flow rate at peak river discharge is used here as a proxy for the sediment load and is shown to be strongly correlated with coral Ba/Ca (r = 0.97). After the wet summer of 1991, the coral Ba/Ca flood peak is followed by a plateau that lingers for several months after dissipation of plume waters, signifying an additional flux of Ba that may originate from submarine groundwater seeps and/or mangrove reservoirs. Both Mn and Y are enriched by a factor of ∼5 in inshore relative to midshelf corals. Mn/Ca ratios show a seasonal cycle that follows SST (r = 0.7), not river discharge, with an additional high variability in summer suggesting a link with biological activity. P and Cd show no significant seasonal variation and are at a low level at both inshore and midreef locations. However, leaching experiments suggest that part of the coral P is not lattice bound. 相似文献
15.
16.
Resolution Sensitivity and Scaling of Large-Eddy Simulations of the Stable Boundary Layer 总被引:1,自引:5,他引:1
Large-eddy simulations (LES) of the continuously turbulent quasi-equilibrium stable boundary layer (SBL) are conducted with grid lengths in the range of 12.5 m to 2 m, in order to explore resolution sensitivity, and determine at what point grid convergence occurs. The structure of the mean potential temperature, winds, and turbulent fluxes varies significantly over this resolution range. The highest resolution simulations show a significant degree of convergence. The dimensionless momentum diffusivity asymptotes to a value of 0.06, corresponding to a limiting flux Richardson number of 0.15.Using the converged simulations, some scaling hypotheses underpinning first-order and second-order closure models are revisited. The effective Richardson number stability functions of the LES are compared with the forms often used in numerical weather prediction (NWP). The mixing implied by the LES is less than that used in NWP. The commonly used similarity profiles for heat and momentum fluxes, and the scalings for dissipation and pressure covariances are compared with the LES. This information could provide guidance for the next generation of SBL parametrization schemes. 相似文献
17.
Rob Westaway Malcolm Pringle Sema Yurtmen Tuncer Demir David Bridgland George Rowbotham Darrel Maddy 《Tectonophysics》2004,391(1-4):121
Along the upper reaches of the Gediz River in western Turkey, in the eastern part of the Aegean extensional province, the land surface has uplifted by 400 m since the Middle Pliocene. This uplift is revealed by progressive gorge incision, and its rate can be established because river terraces are capped by basalt flows that have been K–Ar and Ar–Ar dated. At present, the local uplift rate is 0.2 mm a−1. Uplift at this rate began around the start of the Middle Pleistocene, following a span of time when the uplift was much slower. This was itself preceded by an earlier uplift phase, apparently in the late Late Pliocene and early Early Pleistocene, when the uplift rate was comparable to the present. The resulting regional uplift history resembles what is observed in other regions and is analogously interpreted as the isostatic response to changing rates of surface processes linked to global environmental change. We suggest that this present phase of surface uplift, amounting so far to 150 m, is being caused by the nonsteady-state thermal and isostatic response of the crust to erosion, following an increase in erosion rates in the late Early Pleistocene, most likely as a result of the first large northern-hemisphere glaciation during oxygen isotope stage 22 at 870 ka. We suggest that the earlier uplift phase, responsible for the initial 250 m of uplift, resulted from a similar increase in erosion rates caused by the deterioration in local climate at 3.1 Ma. This uplift thus has no direct relationship to the crustal extension occurring in western Turkey, the rate and sense of which are thought not to have changed significantly on this time scale. Our results thus suggest that the present, often deeply incised, landscape of western Turkey has largely developed from the Middle Pleistocene onwards, for reasons not directly related to the active normal faulting that is also occurring. The local isostatic consequences of this active faulting are instead superimposed onto this “background” of regional surface uplift. Modelling of this surface uplift indicates that the effective viscosity of the lower continental crust beneath this part of Turkey is of the order of 1019 Pa s, similar to a recent estimate for beneath central Greece. The lower uplift rates observed in western Turkey, compared with central Greece, result from the longer typical distances of fluvial sediment transport, which cause weaker coupling by lower-crustal flow between offshore depocentres and eroding onshore regions that provide the sediment source. 相似文献
18.
Philippe Gillet Claudine Biellmann Bruno Reynard Paul McMillan 《Physics and Chemistry of Minerals》1993,20(1):1-18
The room-temperature Raman spectra of aragonite, magnesite and dolomite have been recorded up to 30 GPa and 25 GPa, respectively and no phase changes were observed during compression, unlike calcite. The effect of temperature on the room-pressure Raman spectra of calcite, aragonite, magnesite and dolomite is reported up to 800–1100 K. The measured relative pressure and temperature-shifts of the Raman lines are greater for the lattice modes than for the internal modes of the CO3 groups. These shifts are used to calculate the mode anharmonic parameters of the observed Raman modes; they are negative and their absolute values are smaller (close to 0) for the internal CO3 modes than for the lattice modes (4–17 10?5 K?1). The temperature shifts of the lattice modes in calcite are considerably larger than those for dolomite and magnesite, and a marked non-linear increase in linewidth is observed above 400° C for calcite. This is consistent with an increasing relaxational component to the libration of the CO3 groups about their threefold axes, premonitory to the rotational order-disorder transition at higher temperature. This behaviour is not observed for the other calcite structured minerals in this study. We examine systematic variations in the lattice mode frequencies and linewidths with composition, to begin to understand these differences in their anharmonic behaviour. Finally, we have used a simple Debye-Waller model to calculate atomic displacements in calcite, magnesite and dolomite with increasing temperature from the vibrational frequency data, to provide a direct comparison with atomic positional data from high-temperature structure refinements. 相似文献
19.
Porites corals as recorders of mining and environmental impacts: Misima Island, Papua New Guinea 总被引:1,自引:0,他引:1
Stewart J. Fallon Jamie C. White†Malcolm T. McCulloch 《Geochimica et cosmochimica acta》2002,66(1):45-62
In 1989 open-cut gold mining commenced on Misima Island in Papua New Guinea (PNG). Open-cut mining by its nature causes a significant increase in sedimentation via the exposure of soils to the erosive forces of rain and runoff. This increased sedimentation affected the nearby fringing coral reef to varying degrees, ranging from coral mortality (smothering) to relatively minor short-term impacts. The sediment associated with the mining operation consists of weathered quartz feldspar, greenstone, and schist. These rocks have distinct chemical characteristics (rare earth element patterns and high abundances of manganese, zinc, and lead) and are entering the near-shore environment in considerably higher than normal concentrations. Using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), we analyzed eight colonies (two from high sedimentation, two transitional, two minor, and two unaffected control sites) for Y, La, Ce, Mn, Zn, and Pb. All sites show low steady background levels prior to the commencement of mining in 1988. Subsequently, all sites apart from the control show dramatic increases of Y, La, and Ce associated with the increased sedimentation as well as rapid decreases following the cessation of mining. The elements Zn and Pb exhibit a different behavior, increasing in concentration after 1989 when ore processing began and one year after initial mining operations. Elevated levels of Zn and Pb in corals has continued well after the cessation of mining, indicating ongoing transport into the reef of these metals via sulfate-rich waters. Rare earth element (REE) abundance patterns measured in two corals show significant differences compared to Coral Sea seawater. The corals display enrichments in the light and middle REEs while the heavy REEs are depleted relative to the seawater pattern. This suggests that the nearshore seawater REE pattern is dominated by island sedimentation. Trace element abundances of Misima Island corals clearly record the dramatic changes in the environmental conditions at this site and provide a basis for identifying anthropogenic influences on corals reefs. 相似文献
20.
Trace Metal Solid State Speciation in Aerosols of the Northern Levantine Basin,East Mediterranean 总被引:3,自引:0,他引:3
Mustafa Koçak Nilgun Kubilay Barak Herut Malcolm Nimmo 《Journal of Atmospheric Chemistry》2007,56(3):239-257
An established three stage sequential leach scheme was applied to a series of selected high volume aerosol samples (n = 35) collected from the Turkish Eastern Mediterranean coastline (Erdemli). Samples were selected according to their air
mass back trajectory history to reflect the contrasting mixtures of aerosol material present in the Eastern Mediterranean
marine aerosol. Two populations were adopted, those samples which were classed as “anthropogenic” and those which were “Saharan”
dominated aerosol populations. Applying the three stage leach it was possible to define the proportion for each of the considered
metals (Al, Fe, Cu, Pb, Cd, Zn and Mn) present in the (a) “exchangeable” (b) “carbonate / oxide” and (c) “refractory” phases,
representing novel solid state aerosol speciation data for this marine system. Clear trends were established, conforming with
data from previous studies with mainly crustal derived metals (Al and Fe) being present in the refractory phases (Al > 88%;
Fe > 84%) and those influenced by anthropogenic sources being dominating in the exchangeable phase, although for these metals
the variability was comparatively high (12–64%; 19–85%; 40–100% for Zn, Pb and Cd, respectively). For the majority, greater
exchangeable fractions were present the lower the crustal source contribution to the aerosol population, whereas the “refractory”
fraction exhibited contrasting behaviour. This was illustrated by the novel application of the mixing diagram, presenting
each of the three speciation stages against the corresponding percent anthropogenic contribution to each collected sample.
Zn, Pb and Cd all illustrated progressive decrease in the percent exchangeable with increasing crustal contribution to the
aerosol population. The percent exchangeable was discussed in terms of its use to represent the upper limit of the bioavailable
fraction of metal associated with the aerosol, post deposition. The mixing diagram approach enabled the prediction of the
residual fractions for Cd, Pb and Zn (41 ± 4%; 62 ± 4% and 82 ± 5%, respectively,) in Saharan end-member material. 相似文献