Mineral chemical provenance of Neolithic pitchstone artefacts from Ballygalley,County Antrim,Northern Ireland

A large number of pitchstone fragments and artefacts have recently been discovered at a Neolithic settlement site in Ballygalley, Co. Antrim, Northern Ireland. They consist predominantly of flakes and un‐reworked lumps and cores, with only one complete tool being found. Since no sources of workable pitchstone exist in Ireland, the source must have been the abundant pitchstone volcanic rocks found on the Hebridean Islands of northwest Scotland. The composition of the glass from a number of artefacts is highly siliceous, indicating that they were derived from pitchstones on the Island of Arran; pitchstones from all other Scottish locations are less silica‐rich. In addition, analysis of pyroxene and amphibole microcrystallites within the pitchstone suggests that the Corriegills area of Arran is the most likely source of the Ballygalley artefacts, although the precise outcrop has proved elusive. These finds, and others across Ireland, show that raw materials were being transported and probably traded over considerable distances despite there being suitable alternative sources of material for making tools (flint, etc.) available in the local area. This suggests that the pitchstone had a very specialist use. © 2002 Wiley Periodicals, Inc.     

Equilibrium coexistence of three amphiboles

Electron probe and wet chemical analyses of amphibole pairs from the sillimanite zone of central Massachusetts and adjacent New Hampshire indicated that for a particular metamorphic grade there should be a restricted composition range in which three amphiboles can coexist stably. An unequivocal example of such an equilibrium three amphibole rock has been found in the sillimanite-orthoclase zone. It contains a colorless primitive clinoamphibole, space group P2₁/m, optically and chemically like cummingtonite with blue-green hornblende exsolution lamellae on (100) and (¯101) of the host; blue-green hornblende, space group C2/m, with primitive cummingtonite exsolution lamellae on (100) and (¯101) of the host; and pale pinkish tan anthophyllite, space group Pnma, that is free of visible exsolution lamellae but is a submicroscopic intergrowth of two orthorhombic amphiboles. Mutual contacts and coarse, oriented intergrowths of two and three host amphiboles indicate the three grew as an equilibrium assemblage prior to exsolution. Electron probe analyses at mutual three-amphibole contacts showed little variation in the composition of each amphibole. Analyses believed to represent most closely the primary amphibole compositions gave atomic proportions on the basis of 23 oxygens per formula unit as follows: for primitive cummingtonite (Na_0.02Ca_0.21 ^– Mn_0.06Fe²⁺ _2.28Mg_4.12Al_0.28) (Al_0.17Si_7.83), for hornblende (Na_0.35Ca_1.56Mn_0.02Fe_1.71Mg_2.85Al_0.92) (Al_1.37Si_6.63), and for anthophyllite (Na_0.10Ca_0.06Mn_0.06Fe_2.25Mg_4.11Al_0.47) (Al_0.47Si_7.53). The reflections violating C-symmetry, on X-ray single crystal photographs of the primitive cummingtonite, are weak and diffuse, and suggest a partial inversion from a C-centered to a primitive clinoamphibole. Single crystal photographs of the anthophyllite show split reflections indicating it is an intergrowth of about 80% anthophyllite and about 20% gedrite which differ in their b crystallographic dimensions. Split reflections are characteristic of all analyzed orthorhombic amphiboles so far examined from Massachusetts and New Hampshire except the most aluminous gedrites, and the relative intensity of the gedrite reflections is roughly proportional to the degree of Na and Al substitution. Thin sections of a few of these anthophyllite specimens show lamellae parallel to (010) that are just resolved with a high power objective.Publication approved by the Director, U.S. Geological Survey.     

Vulnerability of Aboriginal health systems in Canada to climate change

Climate change has been identified as potentially the biggest health threat of the 21st century. Canada in general has a well developed public health system and low burden of health which will moderate vulnerability. However, there is significant heterogeneity in health outcomes, and health inequality is particularly pronounced among Aboriginal Canadians. Intervention is needed to prevent, prepare for, and manage climate change effects on Aboriginal health but is constrained by a limited understanding of vulnerability and its determinants. Despite limited research on climate change and Aboriginal health, however, there is a well established literature on Aboriginal health outcomes, determinants, and trends in Canada; characteristics that will determine vulnerability to climate change. In this paper we systematically review this literature, using a vulnerability framework to identify the broad level factors constraining adaptive capacity and increasing sensitivity to climate change. Determinants identified include: poverty, technological capacity constraints, socio-political values and inequality, institutional capacity challenges, and information deficit. The magnitude and nature of these determinants will be distributed unevenly within and between Aboriginal populations necessitating place-based and regional level studies to examine how these broad factors will affect vulnerability at lower levels. The study also supports the need for collaboration across all sectors and levels of government, open and meaningful dialogue between policy makers, scientists, health professionals, and Aboriginal communities, and capacity building at a local level, to plan for climate change. Ultimately, however, efforts to reduce the vulnerability of Aboriginal Canadians to climate change and intervene to prevent, reduce, and manage climate-sensitive health outcomes, will fail unless the broader determinants of socio-economic and health inequality are addressed.     

Water movement within lac du bonnet batholith as revealed by detailed thermal studies of three closely-spaced boreholes

Successive temperature logs have been obtained over a period of two years in three closely-spaced boreholes in the Lac du Bonnet batholith of the Superior Province of the Canadian Shield. Two of the boreholes, of depth 450 m and 830 m, intersect a dipping fracture zone at 435–450 m. In both holes water is flowing from near the surface to the fracture zone at approximately 1.5–1.9·10⁻⁵ m³ s⁻¹, the flow being inferred from analysis of the temperature logs. Below 25 m, temperatures in these two holes are 0.22–0.28 K lower than those in the third, 145 m, hole.The temperature data have been combined with over 200 thermal conductivity measurements on core samples to produce heat flow values. In the deepest hole heat flow above the fracture zone is 16% higher than that below the zone. This indicates that water is flowing up the fracture zone. The flow rate is approximately 0.3 g s⁻¹ m⁻¹, and the flow has existed for thousands of years.Observation of thermal effects of water flow in massive, relatively unfractured plutons in a region having little topographic relief causes one to be concerned about the reliability of heat flow values measured in similar environments.The regional heat flow is taken to be 50 mW m⁻² after correction for glaciation effects. The average value of 24 determinations of radioactive heat generation in granitic core samples is 5.23 ± 1.11 μW m⁻³, which is more than three times higher than expected for such a heat flow in the Superior Province. This implies that the layer of high radioactive heat generation is thin, being not more than 4 km and probably about 1.3 km thick.     

Habitat characteristics and spatial arrangement affecting the diversity of fish and decapod assemblages of seagrass (Zostera marina) beds around the coast of Jersey (English Channel)

Recent research and management plans for seagrass habitats have called for landscape level approaches. The present study examines the spatial utilisation of subtidal seagrass beds by fish and decapods around the coast of Jersey (49°N 02° W). A hierarchical scale of landscape configuration and the plant characteristics of eight seagrass beds were measured and the contributions of these variables as predictors of the properties of the fish and decapod assemblages were evaluated using multiple linear regression models. The results indicated that total diversity had a negative relationship with transect heterogeneity and total species number had a weak negative association with increasing fragmentation. Both total diversity and total species number showed a positive relationship with depth. In fact, in all models of species number and densities, values were higher in deeper seagrass beds. Total decapod density increased with aggregation of seagrass patches within a landscape. In addition to landscape configuration, smaller-scale structural changes in both canopy height and epiphyte load appeared to influence densities of decapod crustaceans. At night, fewer patterns could be explained by the independent variables in the model.     

Trace Metal Solid State Speciation in Aerosols of the Northern Levantine Basin,East Mediterranean

An established three stage sequential leach scheme was applied to a series of selected high volume aerosol samples (n = 35) collected from the Turkish Eastern Mediterranean coastline (Erdemli). Samples were selected according to their air mass back trajectory history to reflect the contrasting mixtures of aerosol material present in the Eastern Mediterranean marine aerosol. Two populations were adopted, those samples which were classed as “anthropogenic” and those which were “Saharan” dominated aerosol populations. Applying the three stage leach it was possible to define the proportion for each of the considered metals (Al, Fe, Cu, Pb, Cd, Zn and Mn) present in the (a) “exchangeable” (b) “carbonate / oxide” and (c) “refractory” phases, representing novel solid state aerosol speciation data for this marine system. Clear trends were established, conforming with data from previous studies with mainly crustal derived metals (Al and Fe) being present in the refractory phases (Al > 88%; Fe > 84%) and those influenced by anthropogenic sources being dominating in the exchangeable phase, although for these metals the variability was comparatively high (12–64%; 19–85%; 40–100% for Zn, Pb and Cd, respectively). For the majority, greater exchangeable fractions were present the lower the crustal source contribution to the aerosol population, whereas the “refractory” fraction exhibited contrasting behaviour. This was illustrated by the novel application of the mixing diagram, presenting each of the three speciation stages against the corresponding percent anthropogenic contribution to each collected sample. Zn, Pb and Cd all illustrated progressive decrease in the percent exchangeable with increasing crustal contribution to the aerosol population. The percent exchangeable was discussed in terms of its use to represent the upper limit of the bioavailable fraction of metal associated with the aerosol, post deposition. The mixing diagram approach enabled the prediction of the residual fractions for Cd, Pb and Zn (41 ± 4%; 62 ± 4% and 82 ± 5%, respectively,) in Saharan end-member material.