A neodymium,strontium, and oxygen isotopic study of the Cretaceous Samail ophiolite and implications for the petrogenesis and seawater-hydrothermal alteration of oceanic crust

In the Samail ophiolite,¹⁴⁷Sm-¹⁴³Nd,⁸⁷Rb-⁸⁷Sr, and¹⁸O/¹⁶O isotopic systems have been used to distinguish between sea-floor hydrothermal alteration and primary magmatic isotopic variations. The Rb-Sr and¹⁸O/¹⁶O isotopic systems clearly exhibit sensitivity to hydrothermal interactions with seawater while the Sm-Nd system appears essentially undisturbed. Internal isochrons have been determined by the¹⁴⁷Sm-¹⁴³Nd method using coexisting plagioclase and pyroxene and give crystallization ages of 130 ± 12m.y. from Ibra and 100 ± 20 m.y. from Wadi Fizh. These ages are interpreted as the time of formation of the Samail oceanic crust and are older than the inferred emplacement age of 65–85 m.y. The initial¹⁴³Nd/¹⁴⁴Nd ratios for a tectonized harzburgite, cumulate gabbros, plagiogranite, sheeted dikes and a basalt have a limited range in ε_Nd of from 7.5 to 8.6 for all lithologies, demonstrating a clear oceanic affinity and supporting earlier interpretations based on geologic observations and geochemistry. The⁸⁷Sr/⁸⁶Sr initial ratios on the same rocks have an extremely large range of from 0.70296 to 0.70650 (ε_Sr = ?19.7 to +30.5) and the δ¹⁸O values vary from 2.6 to 12.7. These large variations are clearly consistent with hydrothermal interaction of seawater with the oceanic crust. A model is presented for the closed system exchange of Sr and O, that in principle illustrates how the Sr isotopic data may be utilized to estimate the water/rock ratio and subsequently used to evaluate the temperature of equilibration between the water and silicates from the¹⁸O/¹⁶O water-rock fractionation.     

143Nd/144Nd,87Sr/86Sr and trace element constraints on the petrogenesis of Aleutian island arc magmas

¹⁴³Nd/¹⁴⁴Nd,⁸⁷Sr/⁸⁶Sr and trace element results are reported for volcanic and plutonic rocks of the Aleutian island arc. The Nd and Sr isotopic compositions plot within the mantle array with ε_Nd values of from 6.5 to 9.1 and⁸⁷Sr/⁸⁶Sr ratios of from 0.70289 to 0.70342. Basalts have mildly enriched light REE abundances but essentially unfractionated heavy REE abundances, while andesites exhibit a greater degree of light to heavy REE fractionation. Both the basalts and andesites have significant large ion lithophile element to light rare earth element (LILE/LREE) enrichments. Variations in the isotopic compositions of Nd and Sr are not related to the spatial distribution of volcanoes in the arc, nor are they related to temporal differences. ε_Nd and⁸⁷Sr/⁸⁶Sr do not correlate with major element compositions but do, however, correlate with certain LILE/LREE ratios (e.g. Ba_N/La_N). Plutonic rocks have isotropic and trace element characteristics identical to some of the volcanic rocks. Rocks that make up the tholeiitic, calc-alkaline and alkaline series in the Aleutians do not come from isotopically distinct sources, but do exhibit some differing LILE characteristics.Given these elemental and isotopic constraints it is shown that the Aleutian arc magmas could not have been derived directly from homogeneous MORB-type mantle, or fresh or altered MORB subducted beneath the arc. Mixtures of partially altered MORB with deep-sea sediment can in principle account for the isotopic characteristics and most of the observed LILE/LREE enrichments. However, some samples have exceedingly high LILE/LREE enrichments which cannot be accounted for by sediment contamination alone. For these samples a more complex scenario is considered whereby dehydration and partial melting of the subducted slab, containing less than 8% sediment, produces a LILE-enriched (relative to REE) metasomatic fluid which interacts with the overlying depleted mantle wedge. The isotopic and LILE characteristics of the mantle are extremely sensitive to metasomatism by small percentages of added fluid, whereas major elements are not substantially effected, Major element compositions of Aleutian magmas are dominantly controlled by the partial melting of this mantle and subsequent crystal fractionation; whereas isotopic and LILE characteristics are determined by localized mantle heterogeneities.     

Summit outgassing as indicated by radon, mercury and pH mapping, Kilauea volcano, Hawaii

Surface geochemical mapping of Rn, Hg and pH on the summit of Kilauea volcano, Hawaii, has shown some of the characteristics of outgassing. Rn concentrations measured in shallow ground gas are highest (10 to 155 units, i.e. up to 0.016 nCi/l²²²Rn) over deep structures associated with the summit caldera, low (1 to 5 units) over the upper rift zones (which are underlain by shallow intrusions) and low to negative (1 to -3 units) over most of the volcanically inactive peripheral areas. High Rn concentrations were measured over peripheral well-developed structures such as the Kaoiki and Koae fault systems (45 and 12 units, respectively). The pattern of Rn values broadly suggests the existence of a summit-wide convection system interrupted locally by specific permeable structures. The low pH (3.5 to 5.6) of soils over the caldera is suggested to be largely due to the sulfurous component of the ground gas. The low concentrations of Hg (5 to 80 ppb) in these soils are postulated as being partly a function of subsurface complexing of Hg with the abundant sulfur. The shallow intrusions below the upper rift zones appear to have outgassed much of their sulfur content, so soils in these areas are only slightly acid (5.6 to 6.2), allowing the accumulation of Hg to concentrations of several thousands of ppb. These conditions change during extrusive (and intrusive) events with the increases in shallow subsurface temperatures and volatiles in ground gas producing an increase in Rn concentration, and a decrease in soil Hg due to volatilization. After such events, Rn concentration decreases, and soil Hg increases significantly.     

A detailed palaeointensity and inclination record from drill core SOH1 on Hawaii

A new record of absolute palaeointensity was obtained from drill core Scientific Observation Hole 1 (SOH1) on Kilauea volcano, Hawaii. Kilauea’s high eruption rate resulted in a relatively continuous record and stratigraphic constraints preserved the chronological order. Three hundred and sixty samples were studied with the Thellier-Thellier technique, which gave 195 successful palaeointensity and 271 successful inclination determinations. Three geomagnetic excursions were observed, which exhibited intensity reductions of about 50%. Initial age control from K-Ar and Ar/Ar dating only constrained the total age between 20 and 120 ka. The final age model was obtained by stretching the SOH1 record relative to other Hawaiian palaeomagnetic data. This gave an age range of 0-45 ka for the flows and identified the excursions as the Hilina Pali, Mono Lake and Laschamp events. The SOH1 record of the Hilina Pali event is the most detailed ever, incorporating data from around 40 flows. This age model suggests that Kilauea had a burst of activity at the SOH1 site around 20 ka. All available data was combined to form a composite record of palaeointensity and inclination on Hawaii for 0-45 ka.     

Effects of cation disordering in a natural MgAl2O4 spinel observed by rectangular parallelepiped ultrasonic resonance and Raman measurements

At moderate temperatures, the elastic properties of natural MgAl₂O₄ spinel differ in several significant ways from properties of synthetic spinels. Below 1000 K, the ultrasonic resonant frequencies of an ordered natural spinel change significantly after heat treatment; at higher temperatures, both types of spinels have similar resonant responses. The temperature derivatives of the elastic constants of an ordered spinel also differ from those of disordered spinels at moderate temperatures; again, at higher temperatures, both types of spinels have similar behaviors. The Raman spectra also differ below 1000 K for ordered natural and disordered spinels and are similar at higher temperatures and after cooling to ambient temperature. We associate these changes in ultrasonic resonance and Raman spectra of spinel with cation disordering at high temperature which may be quenched by cooling. We deduce estimates of the inversion parameter from the relative intensities of the two A_1g Raman modes in very good agreement with estimates made from other measurements. We find thatC ₁₁ andC ₁₂ decrease by 4 and 8%, respectively, with 20% inversion in spinel;C ₄₄ is less sensitive to cation order. These results imply that previous measurements of the adiabatic elastic constants of spinels at ambient conditions have been affected by the state of cation disorder of the specimen.     

Modern analogues and the early history of microbial life

Revealing the geological history of microbial life is very challenging. Microbes rarely are preserved with morphological fidelity, and even when they are, morphology is a poor guide to phylogeny and metabolism. Biological studies of environments considered analogous to those of paleobiological interest on the ancient Earth can inform interpretations and suggest new approaches. This paper reviews recent advances in our understanding of the biological diversity of two environments relevant to Archean paleobiology: those of extreme acidity and temperature (the Mt. Hood and White Island volcanoes), and high salinity (living stromatolites in Shark Bay). The combination of traditional microbial isolation with the use of modern molecular techniques has revealed that the microbial communities in these environments are much more diverse than originally thought. Through the extraction of whole microbial community DNA, enzymatic amplification of evolutionarily conserved genes, and cloning and sequencing of these genes, more specific and informed inferences concerning functional complexity in these extreme environments have now been made. Studies of the modern stromatolites have demonstrated that they have a very diverse range of micoorganisms, and contrary to previous interpretations, cyanobacteria are not the most abundant microbes present. In addition, many of the microorganisms are unique with no known close relatives, and these microorganisms may also possess novel physiologies vital to the integrity and persistence of stromatolites through space and time. Microbes in the volcanoes studied are present ubiquitously and include geochemically significant sulfur- and iron-cycling taxa. The findings from the studies reviewed here suggest that the Archean biota may have been functionally diverse and much more complex than has yet been revealed. The importance of studying modern analogues is stressed in that the biogeochemical processes occurring in these communities leave morphological, mineralogical, lipid and isotopic signals that could be sought in the rock record.     

Behaviour of the geomagnetic field during the Matuyama–Brunhes polarity transition

The ability to derive Gauss coefficients, up to and including degree 3, and their variation through a geomagnetic polarity transition is studied using simulated palaeomagnetic data. It is concluded that for a specified distribution of palaeomagnetic sites reasonable estimates of the behaviour of the coefficients can be derived even when uncertainties in the data, and in the compilation of contemporaneous records, are considered. Published palaeomagnetic records of the Matuyama–Brunhes transition are then used as basis for deriving the variation of the Gauss coefficients over a 32 kyear period encompassing the reversal. Individual records are interpolated to uniform time intervals of 0.5 kyear and put on to a common time scale by correlating between sites the variation in the latitude of VGP's through the reversal. Relative palaeointensity data are scaled by the geocentric axial dipole field intensity for 2000 at each site, and the Gauss coefficients derived by a matrix inversion employing singular value decomposition. The derived variation with time of the Gauss coefficients suggests that, over the time span of the data, the dipole and non-dipole fields have approximately equal intensities. Plots of the variation of the surface vertical magnetic field through the reversal suggest that immediately prior to the reversal a large patch of reverse flux appears in the southern hemisphere. This may subsequently have been responsible for the weakening of the vertical field leading into the reversal. A similar patch of reverse flux is observed some 20–15 kyear prior to the actual reversal and may be associated with an observed excursion in VGPs at several sites.     

Eruption processes and deposit characteristics at the monogenetic Mt. Gambier Volcanic Complex, SE Australia: implications for alternating magmatic and phreatomagmatic activity

The ～5 ka Mt. Gambier Volcanic Complex in the Newer Volcanics Province, Australia is an extremely complex monogenetic, volcanic system that preserves at least 14 eruption points aligned along a fissure system. The complex stratigraphy can be subdivided into six main facies that record alternations between magmatic and phreatomagmatic eruption styles in a random manner. The facies are (1) coherent to vesicular fragmental alkali basalt (effusive/Hawaiian spatter and lava flows); (2) massive scoriaceous fine lapilli with coarse ash (Strombolian fallout); (3) bedded scoriaceous fine lapilli tuff (violent Strombolian fallout); (4) thin–medium bedded, undulating very fine lapilli in coarse ash (dry phreatomagmatic surge-modified fallout); (5) palagonite-altered, cross-bedded, medium lapilli to fine ash (wet phreatomagmatic base surges); and (6) massive, palagonite-altered, very poorly sorted tuff breccia and lapilli tuff (phreato-Vulcanian pyroclastic flows). Since most deposits are lithified, to quantify the grain size distributions (GSDs), image analysis was performed. The facies are distinct based on their GSDs and the fine ash to coarse+fine ash ratios. These provide insights into the fragmentation intensities and water–magma interaction efficiencies for each facies. The eruption chronology indicates a random spatial and temporal sequence of occurrence of eruption styles, except for a “magmatic horizon” of effusive activity occurring at both ends of the volcanic complex simultaneously. The eruption foci are located along NW–SE trending lineaments, indicating that the complex was fed by multiple dykes following the subsurface structures related to the Tartwaup Fault System. Possible factors causing vent migration along these dykes and changes in eruption styles include differences in magma ascent rates, viscosity, crystallinity, degassing and magma discharge rate, as well as hydrological parameters.     

Monitoring viscosity changes from time‐lapse seismic attenuation: case study from a heavy oil reservoir

Heating heavy oil reservoirs is a common method for reducing the high viscosity of heavy oil and thus increasing the recovery factor. Monitoring of these viscosity changes in the reservoir is essential for delineating the heated region and controlling production. In this study, we present an approach for estimating viscosity changes in a heavy oil reservoir. The approach consists of three steps: measuring seismic wave attenuation between reflections from above and below the reservoir, constructing time‐lapse Q and Q^?1 factor maps, and interpreting these maps using Kelvin–Voigt and Maxwell viscoelastic models. We use a 4D relative spectrum method to measure changes in attenuation. The method is tested with synthetic seismic data that are noise free and data with additive Gaussian noise to show the robustness and the accuracy of the estimates of the Q‐factor. The results of the application of the method to a field data set exhibit alignment of high attenuation zones along the steam‐injection wells, and indicate that temperature dependent viscosity changes in the heavy oil reservoir can be explained by the Kelvin–Voigt model.