Sub‐Permil Interlaboratory Consistency for Solution‐Based Boron Isotope Analyses on Marine Carbonates

Boron isotopes in marine carbonates are increasingly used to reconstruct seawater pH and atmospheric pCO₂ through Earth’s history. While isotope ratio measurements from individual laboratories are often of high quality, it is important that records generated in different laboratories can equally be compared. Within this Boron Isotope Intercomparison Project (BIIP), we characterised the boron isotopic composition (commonly expressed in δ¹¹B) of two marine carbonates: Geological Survey of Japan carbonate reference materials JCp‐1 (coral Porites) and JCt‐1 (giant clam Tridacna gigas). Our study has three foci: (a) to assess the extent to which oxidative pre‐treatment, aimed at removing organic material from carbonate, can influence the resulting δ¹¹B; (b) to determine to what degree the chosen analytical approach may affect the resultant δ¹¹B; and (c) to provide well‐constrained consensus δ¹¹B values for JCp‐1 and JCt‐1. The resultant robust mean and associated robust standard deviation (s*) for un‐oxidised JCp‐1 is 24.36 ± 0.45‰ (2s*), compared with 24.25 ± 0.22‰ (2s*) for the same oxidised material. For un‐oxidised JCt‐1, respective compositions are 16.39 ± 0.60‰ (2s*; un‐oxidised) and 16.24 ± 0.38‰ (2s*; oxidised). The consistency between laboratories is generally better if carbonate powders were oxidatively cleaned prior to purification and measurement.     

Comparison of groundwater recharge estimation techniques in an alluvial aquifer system with an intermittent/ephemeral stream (Queensland,Australia)

This study demonstrates the importance of the conceptual hydrogeological model for the estimation of groundwater recharge rates in an alluvial system interconnected with an ephemeral or intermittent stream in south-east Queensland, Australia. The losing/gaining condition of these streams is typically subject to temporal and spatial variability, and knowledge of these hydrological processes is critical for the interpretation of recharge estimates. Recharge rate estimates of 76–182 mm/year were determined using the water budget method. The water budget method provides useful broad approximations of recharge and discharge fluxes. The chloride mass balance (CMB) method and the tritium method were used on 17 and 13 sites respectively, yielding recharge rates of 1–43 mm/year (CMB) and 4–553 mm/year (tritium method). However, the conceptual hydrogeological model confirms that the results from the CMB method at some sites are not applicable in this setting because of overland flow and channel leakage. The tritium method was appropriate here and could be applied to other alluvial systems, provided that channel leakage and diffuse infiltration of rainfall can be accurately estimated. The water-table fluctuation (WTF) method was also applied to data from 16 bores; recharge estimates ranged from 0 to 721 mm/year. The WTF method was not suitable where bank storage processes occurred.     

Petrology and Fe–Ti oxide reequilibration of the 1991 Mount Unzen mixed magma

A dacitic magma (64.5 wt.% SiO₂), a mixture of phenocryst-rich rhyodacite and an aphyric mafic magma, was erupted during the recent 1991–1995 Mount Unzen eruptive cycle. The experimental and analytical results of this study reveal additional details about conditions in the premixing and postmixing magmas, and the nature of the mixing process. The preeruption rhyodacitic magma was at a temperature of 790±20°C according to Fe–Ti oxide phenocryst cores, and at a depth of 6 to 7 km (160 MPa) according to Al-in-hornblende geobarometry. The mafic magma that mixed with the rhyodacite is found as andesitic (54 to 62 wt.% SiO₂) enclaves in the erupted magma and was essentially aphyric when intruded. Phase equilibria indicate that an aphyric andesite at 160 MPa is >1030°C (H₂O-saturated) and possibly as high as 1130°C (2 wt.% H₂O). The composition of the rhyodacite which was mixed with the andesite is estimated to lie between 67 and 69 wt.% SiO₂. Using these compositions and temperatures, the temperature of the Unzen magma after mixing is estimated to be at least 850° to 870°C. The groundmass Fe–Ti oxide microphenocrysts and those in pargasite-bearing reaction zones around biotite phenocrysts both give 890±20°C temperatures; the oxide–oxide contacts give temperatures of 910±20°C. The 900±30°C postmixing temperatures are consistent with phase-equilibria experiments which show that the magma was not above 930°C at 160 MPa. Our Fe–Ti oxide reequilibration experiments suggest that the mixing of the two magmas began within a few weeks of the eruption, which is a shorter time than is calculated using available diffusion data. There is also evidence that some mixing took place much closer to the time of extrusion based on the presence of unrimmed biotite phenocrysts in the magma.     

Test of sediment initial-motion theories using irregular-wave field data

Sediment initial-motion theories predict the flow conditions that coincide with onset of sediment motion, but usually the most that can be determined from burst-sampled field data is whether or not sediment was in motion. Furthermore, initial-motion theories are usually based on regular-wave laboratory data, with little or no guidance given on how such theories are to be transferred to the real world of irregular waves. A field dataset obtained from the zone of wave shoaling beyond the surfzone is used to compare the performance of three initial-motion theories in a way that takes explicit account of wave irregularity and the limitations of burst sampling. The dataset comprises video images of the seabed and measurements of waves, currents and suspended sediment. The initial-motion theories tested were Komar & Miller's (1975 , J. Sedim. Petrol ., 45, 362–367) 'wave-orbital-speed' theory, a 'wave-stress' theory, and a 'wave-plus-current-stress' theory. Fourteen transitions from no sediment motion to sediment motion were observed, but not all of those represented a challenging test of theory. Using the criterion that the best theory is the one that minimizes errors in classifying bursts as 'no sediment motion' or 'sediment in motion', Komar & Miller's (1975 ) theory was found to perform the best when waves were characterized by significant wave height and mean spectral period, both of which can be estimated directly from pressure data alone. Komar and Miller's theory was better at predicting the onset of extended transport events, which occurred during confused seas, rather than the transition back to moribund seabed under clean swell at the end of such events. The conclusion regarding best theory is dependent on the choice of scales used to characterize wave motion. The way forward therefore is to standardize and define terms precisely.     

Regional effects of climate change on reindeer: a case study of the Muotkatunturi region in Finnish Lapland

Few studies have investigated current climate changes for high latitude regions, and the impact of such changes on reindeer and indigenous people. Previous work by other authors has identified snow and ice conditions in winter as being critical in determining the availability of forage for reindeer. Deep snow makes it difficult to access food. Lack of food weakens the herd and can reduce the allocation of nutrients to the development of the foetus in the female deer. Climate data for Lapland, northern Finland, and Karasjok, northern Norway, are examined, together with reindeer calf numbers for the period 1977 to 1994 for the Muotkatunturi region (68°N 25°30'E). Between 1883 and 1993, precipitation increased but temperatures showed no clear warming or cooling trend. However, since the late 1980s, temperatures have increased. A regression analysis on the climate and reindeer data found that the warmer the winter prior to the rut, the fewer the live calves recorded the following year (r = 0.529, p < 0.05). Also, the wetter the winter prior to the rut, the fewer the calves recorded (r = 0.427, p < 0.10). In contrast, the warmer the autumn prior to their birth, the greater the number of calves recorded (r = 0.474, p < 0.10). These results suggest that as climate changes and winters become warmer and wetter with increased snowfall, calf numbers will decline. These findings have important implications for the Saami people who are heavily dependent on the reindeer for their livelihood.     

Modeling a Large-Scale Historic Aquifer Test: Insight into the Hydrogeology of a Regional Fault Zone

Faults can act as flow barriers or conduits to groundwater flow by introducing heterogeneity in permeability. We examine the hydrogeology of the Sandwich Fault Zone, a 137 km long zone of high-angle faults in northern Illinois, using a large-scale historic aquifer test. The fault zone is poorly understood at depth due to the majority of the faults being buried by glacial deposits and its near-vertical orientation which limits geologic sampling across faults. The aquifer test—perhaps one of the largest in terms of overall withdrawal in North American history—was conducted in 1942 at a facility adjacent to the fault zone. More than 34,000 m³/day was pumped for 37 days from nine multiaquifer wells open to the stratified Cambrian-Ordovician sandstone aquifer system. We modeled the aquifer test using a transient MODFLOW-USG model and simulated pumping wells with the CLN package. We tested numerous fault core/damage zone conceptualizations and calibrated to drawdown values recorded at production and observation wells. Our analysis indicates that the fault zone is a low-permeability feature that inhibits lateral movement of groundwater and that there is at least an order of magnitude decrease in horizontal hydraulic conductivity in the fault core compared to the undeformed sandstone. Large head declines have occurred north of the fault zone (over 300 m since predevelopment conditions) and modifying fault zone parameters significantly affects calibration to regional drawdown on a decadal scale. The flow-barrier behavior of the fault zone has important implications for future groundwater availability in this highly stressed region.     

Intertidal boulder transport: A proposed methodology adopting Radio Frequency Identification (RFID) technology to quantify storm induced boulder mobility

Boulder transport is an area of growing interest to coastal scientists as a means of improving our understanding of the complex interactions between extreme wave activity and the evolution of rocky coasts. However, our knowledge of the response of intertidal boulder deposits to contemporary storm events remains limited due to a lack of quantifiable field-based evidence. We address this by presenting a methodology incorporating Radio Frequency Identification (RFID) tagging and Differential Global Positioning Navigation Satellite System (DGNSS) technology to monitor and accurately quantify the displacement of RFID tagged boulders resulting from storm wave activity. Based on preliminary findings we highlight the suitability of the technology and methodology to better understand the spatial and temporal response of intertidal boulders to contemporary storm events. We inserted RFID tags in 104 limestone boulders (intermediate axes from 0.27 to 2.85 m) across a range of morphogenic settings at two sites on the intertidal shore platforms at Bembridge, Isle of Wight (UK). Fifteen topographic surveys were conducted between July 2015 and May 2017 to relocate and record tagged boulder locations (tag recovery rate: 91%). The relocated boulder coordinate data from both sites identified 164 individual transport events in 63% of the tagged boulder array amounting to 184.6 m of transport, including the displacement of a boulder weighing more than 10 tonnes. Incidents of boulder quarrying and overturning during transport were also recorded, demonstrating that despite the relatively sheltered location, intertidal boulders are created and regularly transported under moderate storm conditions. This suggests that contemporary storm events have a greater propensity to mobilise boulders in the intertidal range than has previously been realised. Consequently, by documenting our methodology we provide guidance to others and promote further use of RFID technology to enable new hypotheses on boulder transport to be tested in a range of field settings and wave regimes. © 2018 John Wiley & Sons, Ltd.     

Biomarkers and environmental risk assessment: guiding principles from the human health field

Although the potential use of biomarkers within environmental risk assessment (ERA) has long been recognised their routine use is less advanced compared with clinical human health risk assessment, where a number of familiar biomarkers (such as blood pressure and serum cholesterol) are in common usage. We have examined how biomarkers are incorporated into human health risk assessment and have identified several 'required elements'. These include identification of the (clinical) assessment endpoint at the outset, rational selection of the biomarker(s) (the measurement endpoint), biomarker 'validation' (e.g. QA/QC) and biomarker 'qualification' (evidence linking the measurement and assessment endpoints). We discuss these elements in detail and propose that their adoption will facilitate the routine use of biomarkers in environmental risk assessment. Furthermore, our analysis highlights the need for cooperation between those working with biomarkers within human and environmental risk assessment to exchange best practice between common disciplines for mutual advantage.