Distributions of polycyclic aromatic hydrocarbons and alkylated polycyclic aromatic hydrocarbons in Osaka Bay,Japan

Contaminations in sediments by polycyclic aromatic hydrocarbons (PAHs) and alkylated PAHs were investigated at 44 sites in Osaka Bay, Japan. Concentrations of total PAHs and alkylated PAHs were in the range 6.40–7800 ng/g dry weights and 13.7–1700 ng/g dry weights, respectively. The PAH concentrations tended to be higher along the shoreline in the vicinities of big ports, industrialized areas, and densely populated regions such as the cities of Osaka and Kobe. The major sources appeared to be pyrogenic or both pyrogenic and petrogenic at most of the sites. PAH concentrations were remarkably high at a site near Kobe, where the concentrations of dibenzo(a,h)anthracene and benzo(g,h,i)perylene exceeded the effects-range-medium concentration and eight PAHs were above the corresponding effects-range-low concentrations. Those PAHs may have been derived from the great fire associated with the large earthquake in 1995.     

Atmospheric gravity waves identified by ground-based observations of the intensity and rotational temperature of OH airglow

Spectroscopic observations of OH airglow undertaken on May 2, 2006 at Uji, Japan reveal variations in intensity and rotational temperature related to the passage of an atmospheric gravity wave. The variations exhibit a period of approximately 1 h and magnitudes of 2–6% in intensity and 0.5–2% in rotational temperature. The vertical wavelength and intrinsic frequency of the atmospheric gravity wave were determined from the horizontal wavelength derived by an OH airglow imager, the background horizontal wind velocity obtained by the middle and upper atmosphere (MU) radar, and the dispersion relationship. The observed variations are consistent with the values calculated using the model of Liu, A.Z., Swenson, G.R. [2003. A modeling study of O₂ and OH airglow perturbations induced by atmospheric gravity waves. J. Geophys. Res. 108 (No. D4), 4151. doi:10.1029/2002JD002474].     

Dewatering Behaviour of a Uranium Ore Slurry Containing Clays

The main objective of this paper was to investigate the dewatering behaviour of a clayey uranium ore slurry. The slurry (containing 28% clay size) exhibited moderate water adsorption (w _l  = 83% and w _p  = 30%). Primarily composed of muscovite (46%) and quartz (30%), the clay minerals included illite (8%), chlorite (5%) and kaolinite (2%) alongside a CEC of 41 (cmol(+)/kg) with Ca²⁺ and Mg²⁺ as the dominant cations. Likewise, the high EC (17,600 μS/cm) and ionic strength (1.15 mol/L) indicated a flocculated microstructure due to the presence of SO₄ ^2? (22,600 mg/L) and Mg²⁺ (1340 mg/L) in the slurry water. Settling included sedimentation and consolidation at low initial solids condition (25–35%) whereas only consolidation was observed at high initial solids contents (40–50%). The average k reduced from 1.2 × 10^?6 m/s (initial s = 25%) to 5.3 × 10^?8 m/s (initial s = 50%) along with a void ratio reduction from 7.4 to 2.6. Due to thixotropic strength, volume compressibility during consolidation showed apparent pre-consolidation at low effective stress (0.3–2 kPa) with a reduction in void ratio from 2.6 to 2.5. The e _s was found to be 2.46 at σ′ = 2 kPa and was followed by a steeper slope with the void ratio reducing to 2.1 at σ′ = 31 kPa. Likewise, the hydraulic conductivity during consolidation decreased from 2.6 × 10^?9 m/s (at e = 2.6) to 2.0 × 10^?10 m/s (at e = 2.1).     

SAR- and gravity change-based characterization of the distribution pattern of pyroclastic flow deposits at Mt. Merapi during the past 10 years

Mt. Merapi, Indonesia, is one of the most active and dangerous volcanoes in the Torrid Zone. This volcano has erupted frequently and has produced pyroclastic flows following the collapse of the summit lava dome. We used Synthetic Aperture Radar (SAR) data acquired by JERS-1 and RADARSAT-1 satellites from April 1996 to July 2006 to clarify the distribution patterns of the pyroclastic flow deposits. The extent of the deposits, termed P-zones, was accurately extracted by ratio operation and low-level feature extraction from SAR intensity images. These images highlighted temporal changes of the distribution area, perimeter, flow distance, included angle, and collapse direction. To validate the image-processing results, reflectance spectra of the rock samples collected after the eruption in June 2006 were measured in a laboratory. The reflectance spectra of all samples showed similar characteristics to the reference spectra, which were derived from atmospheric correction of Hyperion sensor image data covering the lava dome at the summit. Therefore, P-zones were confirmed to be the pyroclastic flow deposits originating from destruction of the lava dome at the summit. The image-processing results clarified that the extent of the distribution areas, perimeter, flow distances, and included angle of the P-zones were variable among the eruptions, while the collapse direction had a constant pattern. The collapse pattern followed a clockwise change from the south toward the west. By comparing the ratio maps of Bouguer gravity anomaly data in two periods, the change was interpreted to originate from the inclination of the conduit and the formation of shallow and deep magma reservoirs.     

Temporal variations in channel patterns and facies architecture in a gravelly fluvial system: The Paleogene Iwaki Formation on the Joban Coalfield,a forearc basin in Northeast Japan

This paper examined sequence‐stratigraphic features of a gravelly fluvial system of the Iwaki Formation, which developed in a forearc‐basin setting in Northeast Japan during the Eocene through Oligocene. On the basis of three‐dimensional architectural element analysis, we discriminated three major cycles of channel complexes, which contain ten component channel deposits in total in the fluvial succession. Component channel deposits in the uppermost part of each cycle are sandier and associated with overbank muddy deposits and coal beds as compared with those in the lower part of the cycle. Mean clast‐size also decreases upsection in the entire gravelly fluvial deposits. The fluvial succession is interpreted to have been deposited in response to an overall rise in relative sea level that was superimposed by three short‐term relative sea‐level rises on the basis of vertical stacking patterns and component lithofacies features of channel deposits, and of correlation of the fluvial succession with an age‐equivalent marine succession in an area about 50 km offshore. However, geometry and stacking patterns of the channel complexes do not exhibit any distinct temporal variation and amalgamated channel and bar deposits are dominant throughout the transgressive fluvial succession. On the other hand, an overall fining‐upward pattern of the entire Iwaki Formation fluvial deposits in association with three component fining‐upward patterns is distinct, and is interpreted to be consistent with the tenet of the standard fluvial sequence‐stratigraphic models. This indicates that the present example represents one type of variation in the standard fluvial sequence‐stratigraphic models, possibly reflecting the forearc‐basin setting, which is generally represented by higher valley slope, higher shedding of coarse‐grained sediments, and shorter longitudinal profiles to the coastal area as compared with a passive‐continental‐margin setting.     

Possible climate change/variability and human impacts,vulnerability of drought-prone regions,water resources and capacity building for Africa

ABSTRACT

This review article discusses the climate, water resources and historical droughts of Africa, drought indices, vulnerability, impact of global warming and land use for drought-prone regions in West, southern and the Greater Horn of Africa, which have suffered recurrent severe droughts in the past. Recent studies detected warming and drying trends in Africa since the mid 20th century. Based on the Fourth Assessment Report of the Intergovernmental Panel on Climate Change and the Coupled Model Intercomparison Project Phase 5 (CMIP5), both northern and southern Africa are projected to experience drying, such as decreasing precipitation, runoff and soil moisture in the 21st century and could become more vulnerable to the impact of droughts. The daily maximum temperature is projected to increase by up to 8°C (RCP8.5 of CMIP5), precipitation indices such as total wet day precipitation (PRCPTOT) and heavy precipitation days (R10 mm) could decrease, while warm spell duration (WSDI) and consecutive dry days (CDD) could increase. Uncertainties of the above long-term projections, teleconnections to climate anomalies such as ENSO and the Madden-Julian Oscillation, which could also affect the water resources of Africa, and capacity building in terms of physical infrastructure and non-structural solutions are also discussed. Given that traditional climate and hydrological data observed in Africa are generally limited, satellite data should also be exploited to fill the data gap for Africa in the future.

Editor D. Koutsoyiannis; Associate editor N. Ilich     

Bioaccumulation of nitroarenes in bivalves at Osaka Bay, Japan

This paper reports for the first time the detection and occurrence of nitroarenes (NPAHs) in marine organisms. Mussels and oysters collected from Osaka Bay, Japan, had total NPAHs concentrations that ranged from 2380 to 24,688 pg/g dry and 2672 to 25,961 pg/g dry, respectively. Relatively higher concentrations were detected in sampling sites located near the central district and suburbs of Osaka City implying that the most probable sources of NPAHs in the two bivalves are exhaust gases and smokes emitted by automobiles and industrial plants. Bivalves had relatively higher residues of 1-nitronaphthalene, 2-nitronaphthalene, 3-nitrophenanthrene, and 9-nitrophenanthrenes. Residues of 2-nitrofluorene, 1-nitropyrene, 4-nitropyrenes, and 6-nitrochrysene were much lower compared to nitronaphthalenes and nitrophenanthrenes. Inter-species differences was only observed for 2-nitronaphthalene with oysters exhibiting significantly higher residues than mussels.     

Mixing of magmatic CO2 into volcano groundwater flow at Aso volcano assessed combining carbon and water stable isotopes

To understand deep groundwater flow systems and their interaction with CO₂ emanated from magma at depth in a volcanic edifice, deep groundwater samples were collected from hot spring wells in the Aso volcanic area for hydrogen, oxygen and carbon isotope analyses and measurements of the stable carbon isotope ratios and concentrations of dissolved inorganic carbon (DIC). Relations between the stable carbon isotope ratio (δ¹³C_DIC) and DIC concentrations of the sampled waters show that magma-derived CO₂ mixed into the deep groundwater. Furthermore, groundwaters of deeper areas, except samples from fumarolic areas, show higher δ¹³C_DIC values. The waters' stable hydrogen and oxygen isotope ratios (δD and δ¹⁸O) reflect the meteoric-water origin of that region's deep groundwater. A negative correlation was found between the altitude of the well bottom and the altitude of groundwater recharge as calculated using the equation of the recharge-water line and δD value. This applies especially in the Aso-dani area, where deeper groundwater correlates with higher recharge. Groundwater recharged at high altitude has higher δ¹³C_DIC of than groundwater recharged at low altitude, strongly suggesting that magmatic CO₂ is present to a much greater degree in deeper groundwater. These results indicate that magmatic CO₂ mixes into deeper groundwater flowing nearer the magma conduit or chamber.     

Biogenic carbon flows through the planktonic food web of the Amundsen Gulf (Arctic Ocean): A synthesis of field measurements and inverse modeling analyses

Major pathways of biogenic carbon (C) flow are resolved for the planktonic food web of the flaw lead polynya system of the Amundsen Gulf (southeast Beaufort Sea, Arctic Ocean) in spring-summer 2008. This period was relevant to study the effect of climate change on Arctic marine ecosystems as it was characterized by unusually low ice cover and warm sea surface temperature. Our synthesis relied on a mass balance estimate of gross primary production (GPP) of 52.5 ± 12.5 g C m⁻² calculated using the drawdown of nitrate and dissolved inorganic C, and a seasonal f-ratio of 0.64. Based on chlorophyll a biomass, we estimated that GPP was dominated by phytoplankton (93.6%) over ice algae (6.4%) and by large cells (>5 μm, 67.6%) over small cells (<5 μm, 32.4%). Ancillary in situ data on bacterial production, zooplankton biomass and respiration, herbivory, bacterivory, vertical particle fluxes, pools of particulate and dissolved organic carbon (POC, DOC), net community production (NCP), as well as selected variables from the literature were used to evaluate the fate of size-fractionated GPP in the ecosystem. The structure and functioning of the planktonic food web was elucidated through inverse analysis using the mean GPP and the 95% confidence limits of every other field measurement as lower and upper constraints. The model computed a net primary production of 49.2 g C m⁻², which was directly channeled toward dominant calanoid copepods (i.e. Calanus hyperboreus 20%, Calanus glacialis 10%, and Metridia longa 10%), other mesozooplankton (12%), microzooplankton (14%), detrital POC (18%), and DOC (16%). Bacteria required 29.9 g C m⁻², a demand met entirely by the DOC derived from local biological activities. The ultimate C outflow comprised respiration fluxes (82% of the initial GPP), a small sedimentation (3%), and a modest residual C flow (15%) resulting from NCP, dilution and accumulation. The sinking C flux at the model limit depth (395 m) supplied 60% of the estimated benthic C demand (2.8 g C m⁻²), suggesting that the benthos relied partly on other C sources within the bottom boundary layer to fuel its activity. In summary, our results illustrate that the ongoing decline in Arctic sea ice promotes the growth of pelagic communities in the Amundsen Gulf, which benefited from a ∼80% increase in GPP in spring-summer 2008 when compared to 2004 – a year of average ice conditions and relatively low GPP. However, 53% of the secondary production was generated within the microbial food web, the net ecological efficiency of zooplankton populations was not particularly high (13.4%), and the quantity of biogenic C available for trophic export remained low (6.6 g C m⁻²). Hence it is unlikely that the increase in lower food web productivity, such as the one observed in our study, could support new harvestable fishery resources in the offshore Beaufort Sea domain.