Mass balance of major elements in relation to weathering in soils developed on igneous rocks in a semiarid region, northwestern Iran

This study was conducted to evaluate the weathering intensity of the major soils developed on igneous rocks in semiarid region of northwestern Iran.Eight parent materials were selected including monzodiorite,alkali granite,granodiorite,syenite,pyroxene diorite,hornblende andesite,pyroxene andesite,and dacite.Representative soil profiles were described and soil samples were collected and analyzed for selected chemical and physical properties and total concentrations of major elements and Zr,V,Ti and Y.Bulk densities as well as Ti,Zr and V concentrations were used to estimate the strain factors and mass balance equations were used to quantify the net result of pedogenic weathering,i.e.elemental loss and gain.The results of clay content and pedogenic iron variability as well as index of compositional variability(ICV),chemical index of alteration(CIA) and,A-CN-K and MFW ternary plots showed that the soils developed on volcanic rocks(hornblende andesite> pyroxene andesite> dacite) were more weathered than those on the plutonic parent rocks(alkali granite,granodiorite,monzodiorite,syenite,pyroxene diorite).The results of mass balance calculations based on the strain factors revealed that the Ca and Na depleted during weathering progress mostly from plagioclase grains.In the semiarid regions Ca is precipitated as pedogenic calcite in the soil horizons.K and Mg depletion is less than Ca and Na especially in the profiles on the hornblende andesite with the highest clay and LOI content.The results of this study clearly suggest that the behavior of K and Mg during the weathering cannot only be explained by the disintegration of the primary minerals,since they are fixed on the secondary clay minerals.Iron did not change in the soils compared to the parent material and was precipitated as the pedogenic iron and conserved in the soil horizons.Overall,the results on the weathering indicators and major elements mass balance enrichment/depletion in the study area confirmed that the soil profiles developed on volcanic rocks are more weathered than those on the plutonic igneous rocks.     

Relationships between soil depth and terrain attributes in a semi arid hilly region in western Iran

Soil depth generally varies in mountainous regions in rather complex ways.Conventional soil survey methods for evaluating the soil depth in mountainous and hilly regions require a lot of time,effort and consequently relatively large budget to perform.This study was conducted to explore the relationships between soil depth and topographic attributes in a hilly region in western Iran.For this,one hundred sampling points were selected using randomly stratified methodology,and considering all geomorphic surfaces including summit,shoulder,backslope,footslope and toeslope;and soil depth was actually measured.Eleven primary and secondary topographic attributes were derived from the digital elevation model(DEM) at the study area.The result of multiple linear regression indicated that slope,wetness index,catchment area and sediment transport index,which were included in the model,could explain about 76 % of total variability in soil depth at the selected site.This proposed approach may be applicable to other hilly regions in the semi-arid areas at a larger scale.     

FIAs(Foliation Intersection/Inflection Axes) Preserved in Porphyroblasts,the DNA of Deformation:A Solution to the Puzzle of Deformation and Metamorphism in the Colorado,Rocky Mountains,USA

Abstract: FIAs have been used extensively for more than a decade to unravel deformation and metamorphic puzzles. Orogenic processes developing early during the history or orogenesis challenge scientists because compositional layering in rocks always reactivates where multiple deformations have occurred, leaving little evidence of the history of foliation development preserved in the matrix. The foothills of the Rocky Mountains in Colorado, USA contain a succession of four FIA sets (trends) that would not have been distinguishable if porphyroblasts had not grown during the multiple deformation events that affected these rocks or if they had rotated as these events took place. They reveal that both the partitioning of deformation and the location of isograds changed significantly as the deformation proceeded.     

Dark energy from “extended modified gravity” and Gauss–Bonnet invariant term

We investigate the cosmological dynamics of a four-dimensional Friedmann–Robertson–Walker homogenous and isotropic universe from Gauss–Bonnet higher-order curvature corrections, together with nonminimal coupling and with an infrared effective action of gravity based on a second-order gauge formulation for the Lorentz group. We study the evolution of the universe in such a model, identifying its key properties. Many new interesting features are revealed and discussed in some detail.     

Effects of a low-radiotoxicity uranium salt (uranyl acetate) on biochemical and hematological parameters of the catfish, <Emphasis Type="Italic">Clarias gariepinus</Emphasis>

Specimens of Clarias gariepinus were treated with lethal (70, 75, 80, 85, 90, and 95 mg/L) and sub-lethal concentrations (8, 12 and 16 mg/L) of uranyl acetate, a low-radiotoxicity uranium salt. The LC 50 value was registered as 81.45 mg/L. The protein and glycogen concentrations in liver and muscles were decreased in the fish exposed to sub-lethal concentrations. The red blood cell (RBC) and white blood cell (WBC) counts, haemoglobin (Hb) concentration and haematocrit (Hct) values were decreased. Different blood indices like mean corpuscular volume (MCV), mean corpuscular haemoglobin (MCH) and mean corpuscular haemoglobin concentration (MCHC) were negatively affected. Level of plasma glucose was elevated whereas protein was decreased. The level of calcium concentration (Ca) was declined in the blood of exposed fish whereas magnesium (Mg) remains unchanged. The activity level of glutamic-oxaloacetic transaminase (GOT) and glutamic-pyruvic transaminase (GPT) was elevated in exposed fish. These effects were more pronounced in the last period of exposure and in higher concentrations. Results of the present study indicate that uranyl acetate has adverse effects on Clarias gariepinus and causes changes in the biochemical and hematological parameters of the fish.     

Spatio-temporal variation of land surface temperature and temperature lapse rate over mountainous Kashmir Himalaya

In this study, Land Surface Temperature(LST) and its lapse rate over the mountainous Kashmir Himalaya was estimated using MODIS data and correlated with the observed in-situ air temperature(Tair) data. Comparison between the MODIS LST and Tair showed a close agreement with the maximum error of the estimate ±1°C and the correlation coefficient 0.90. Analysis of the LST data from 2002-2012 showed an increasing trend at all the selected locations except at a site located in the southeastern part of Kashmir valley. Using the GTOPO30 DEM, MODIS LST data was used to estimate the actual temperature lapse rate(ATLR) along various transects across Kashmir Himalaya, which showed significant variations in space and time ranging from 0.3°C to 1.2°C per 100 m altitude change. This observation is at variance with the standard temperature lapse rate(STLR) of 0.65°C used universally in most of the hydrological and other land surface models. Snowmelt Runoff Model(SRM) was used to determine the efficacy of using the ATLR for simulating the stream flows in one of the glaciated and snow-covered watersheds in Kashmir. The use of ATLR in the SRM model improved the R2 between the observed and predicted streamflows from 0.92 to 0.97.It is hoped that the operational use of satellite-derived LST and ATLR shall improve the understanding and quantification of various processes related to climate, hydrology and ecosystem in the mountainous and data-scarce Himalaya where the use of temperature and ATLR are critical parameters for understanding various land surface and climate processes.     

Whistler observations of magnetospheric electric field in the night side plasma-sphere at low latitude

Whistlers recorded at low latitude ground stations of Gulmarg, Nainital and Varanasi were used to infer the east-west component of electric field on the nightside plasmasphere atL=1.2, 1.12, and 1.07 during magnetic storm periods. The method of measuring electric field from the observed cross-L motions of whistler ducts within the plasma-sphere, indicated by changes in nose frequency of whistlers has been outlined. The nose frequencies of the non-nose whistlers under consideration have been deduced from Dowden-Allocock linear Q-technique. The results show eastward electric fields of 0.7 mVm^–1 in the equatorial plane of Gulmarg and 0.3 mVm^–1 in the equatorial plane of Nainital in the premidnight local time sector. Near midnight, there is a sharp transition from eastward field to a westward electric field of 0.2–0.7 mV m^–1 for Gulmarg, 0.3–0.5 mV m^–1 for Nainital and 0.1–0.3 mVm^–1 for Varanasi.     

Assessing Lateral Continuity within the Yammama Reservoir in the Foroozan Oilfield, Offshore Iran: An Integrated Study

Located in Iranian sector of the Persian Gulf, Foroozan Oilfield has been producing hydrocarbons via seven different reservoirs since the 1970s. However, understanding fluid interactions and horizontal continuity within each reservoir has proved complicated in this field. This study aims to determine the degree of intra-reservoir compartmentalization using gas geochemistry, light hydrocarbon components, and petroleum bulk properties, comparing the results with those obtained from reservoir engineering indicators. For this purpose, a total of 11 samples of oil and associated gas taken from different producing wells in from the Yammama Reservoir were selected. Clear distinctions, in terms of gas isotopic signature and composition, between the wells located in northern and southern parts of the reservoir (i.e. lighter δ13C1, lower methane concentration, and negative sulfur isotope in the southern part) and light hydrocarbon ratios (e.g. nC7/toluene, 2,6-dmC7/1,1,3-tmcyC5 and m-xylene/4-mC8) in different oil samples indicated two separate compartments. Gradual variations in a number of petroleum bulk properties (API gravity, V/Ni ratios and asphaltene concentration) provided additional evidence on the reservoir-filling direction, signifying that a horizontal equilibrium between reservoir fluids across the Yammama Reservoir is yet to be achieved. Finally, differences in water-oil contacts and reservoir types further confirmed the compartmentalization of the reservoir into two separate compartments.     

Hydrological behaviour of a drained agricultural peat catchment in the tropics. 1: Rainfall,runoff and water table relationships

Abstract

Hydrological data of a drained tropical peat catchment have been analysed through conventional quantitative hydrological approaches to characterize its hydrological behaviours and changes due to continuous drainage for a long period. The results show that the hydrology of the catchment is extremely dynamic and the catchment is flashy in nature. A decreasing trend in peak flow amount and an increasing trend in baseflow amount was observed in the catchment, indicating that continuous drainage has reduced the risk of both flooding and water scarcity in the catchment. Correlation analysis among rainfall, runoff and groundwater table reveals that saturation excess-near surface flow is the dominant mechanism responsible for rapid runoff generation in the catchment. Therefore, any physical alterations or disturbances to the upper part of the peat profile would definitely affect the overall hydrological behaviour of the peat catchment.

Editor Z.W. Kundzewicz; Associate editor D. Hughes

Citation Katimon, A., Shahid, S., Abd Wahab, A.K., and Ali, M.H., 2013. Hydrological behaviour of a drained agricultural peat catchment in the tropics. Part 1: Rainfall, runoff and water table relationships. Hydrological Sciences Journal, 58 (6), 1297–1309.