Pt/十六烷基三甲基溴化铵纳米聚集体修饰玻碳电极促进析氢(英文)

A novel, cost-effective, and simple electrocatalyst based on a Pt-modified glassy carbon electrode(GCE), using cetyltrimethylammonium bromide(CTAB) as a cationic surfactant, is reported. Amphiphilic CTAB molecules were adsorbed on GCE by immersion in a CTAB solution. The positively charged hydrophilic layer, which consisted of small aggregates of average size less than 100 nm,was used for accumulation and complexation of [PtCl2. anions by immersing the electrode in Ksolution. The modified electrode was characterized using scanning electron microscopy,energy-dispersive X-ray spectroscopy, impedance spectroscopy, and electrochemical methods. The electrocatalytic activity of the Pt particles in the hydrogen evolution reaction(HER) was investigated.The results show that the CTAB surfactant enhances the electrocatalytic activity of the Pt particles in the HER in acidic solution.     

Driving behavior of stepped and tapered offshore piles due to hammer blows

Abstract

In this article, the drivability of stepped and tapered offshore piles with the same length and volume has been investigated under hammer blows. To justify the obtained results from field testing and numerical methods, this pile driving procedure has been analyzed and discussed with wave propagation mechanism. It will be shown that tapered pile can be confidently idealized as a number of prismatic segments connected rigidly to each other. This is an interesting finding that fully tapered or stepped piles have a better performance in pile driving and enable users to apply simple one dimensional numerical analysis for simulating pile drivability.     

On the development of ship anti-roll tanks

This paper reviews the development of ship anti-roll tanks from the 1880s to the present day including their modelling and control strategies. Mention is also made of other ship roll stabilization systems and the application of the technology to stabilization of other structures. The potential for the use of roll stabilization tanks on modern, high speed multi-hull craft which also have a low speed operational requirement is also discussed.     

Online GPS processing services: an initial study

There are a number of online Global Positioning System (GPS) processing services that provide GPS processing results to the user free of charge and with unlimited access. These services provide solutions for a user-submitted Receiver Independent Exchange Format (RINEX) file based on differential methods using reference stations or precise point positioning using precise GPS orbit and clock data. Different data sets varying in time and location were submitted to the online services and their results compared. Although the quality of results depends on many factors, in most cases the users can expect reliable online processing results for a 10-h data set made by a geodetic dual frequency receiver anywhere in the world.     

Watershed modeling of rainfall excess transformation into runoff

In this paper an attempt is made to present a distributed physiographic conceptual model that uses the principles of flow continuity and momentum. For this purpose, the watershed under study is divided into subwatersheds keeping in view the drainage patterns and characteristics. Then the main tributaries are identified and their drainage areas are delineated to form tributary subwatersheds. The main channel subwatersheds have taken care of the remaining area in the vicinity of the main channel. The kinematic wave theory is applied for the overland runoff computations from these subwatersheds. Further, the overland flows are superimposed onto the main channel. The dynamic wave theory is used to route the flows through the main channel to compute the watershed responses at the outlet. The proposed model is tested onto a natural watershed. The computations were performed for few storm events. Comparison of the significant parameters of the computed and the observed hydrographs shows that the maximum relative error in prediction is 5.8%. Thus, the results are satisfactory. Better results can be obtained when measured rainfall-excess data are available or a more realistic loss index is adopted for rainfall-excess separation.     

Nouvelles données structurales et datations 40K–40Ar sur les roches métamorphiques de la région de Neyriz (zone de Sanandaj–Sirjan,Iran méridional). Leur intérêt dans le cadre du domaine néo-téthysien du Moyen-Orient

The metamorphic rocks of the Neyriz area (Sanandaj–Sirjan zone) represent a Palaeozoic sequence, the upper part of which being palaeontologically dated from the Carboniferous and the Permian. Field structural analysis of the whole sequence, detailed in laboratory by microstructural one and ⁴⁰K–⁴⁰Ar dating carried on separated minerals, lead to establish that the whole sequence, from gneisses to Permian rocks, has suffered a unique synmetamorphic deformation, of variable intensity, marked by a foliation. Isotopic ages measured on extracted amphiboles and micas, clustered in four groups between 300 and 60 Ma, show the successive stages of their slow exhumation, which ended by the end of the Cretaceous. To cite this article: R. Sheikholeslami et al., C. R. Geoscience 335 (2003).     

Application of Geographic Information Systems to Analyses and Modeling of Hydrocarbons Anomaly in Yakla,North Tarim Basin,Xinjiang,China

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Mercury pollution of Mediterranean sediments around Alexandria,Egypt

Elemental mercury is associated with industrial wastes discharged through the main effluent pipe of the Chlorine-Alkali plant at El-Max area west of Alexandria. The minimal mercury value of 0.1 ppm dry weight is assumed to be the background level for uncontaminated sediments in the area. Mercury level ranged from 8.02 to 15.5 ppm in the beach sands from the polluted area beyond the plant, and from 0.14 to 1.4 ppm in the bottom sediments off Alexandria.The Chlorine-Alkali plant is obviously the major source of mercury pollution. The contribution of land drainage, agricultural and domestic wastes is insignificant.     

Identification of a hydrodynamic threshold in karst rocks from the Biscayne Aquifer, south Florida, USA

A hydrodynamic threshold between Darcian and non-Darcian flow conditions was found to occur in cubes of Key Largo Limestone from Florida, USA (one cube measuring 0.2 m on each side, the other 0.3 m) at an effective porosity of 33% and a hydraulic conductivity of 10 m/day. Below these values, flow was laminar and could be described as Darcian. Above these values, hydraulic conductivity increased greatly and flow was non-laminar. Reynolds numbers (Re) for these experiments ranged from <0.1 to 7. Non-laminar flow conditions observed in the hydraulic conductivity tests were observed at Re close to 1. Hydraulic conductivity was measured on all three axes in a permeameter designed specifically for samples of these sizes. Positive identification of vertical and horizontal axes as well as 100% recovery for each sample was achieved. Total porosity was determined by a drying and weighing method, while effective porosity was determined by a submersion method. Bulk density, total porosity and effective porosity of the Key Largo Limestone cubes averaged 1.5 g/cm³, 40 and 30%, respectively. Two regions of anisotropy were observed, one close to the ground surface, where vertical flow dominated, and the other associated with a dense-laminar layer, below which horizontal flow dominated.