Distribution patterns of some heavy metals in the surface sediment fractions at northern Safaga Bay, Red Sea, Egypt

The distribution patterns, the index of geo-accumulations (MI_geo), and the enrichment ratios (ER _n ) of the contaminant metals: Fe, Mn, Zn, Cu, Pb, and Ni were studied in gravel, sand, mud, coarse, medium, and fine sediment fractions of the uppermost layer of the bottom sediments collected from 12 stations covering the northern part of Safaga Bay. The distribution levels of these metals were increasing with grain size decreasing toward the central axis of the bay that extends NE–SW and southward to Safaga Harbour indicating that these metals concentrated mainly in the fine, very fine, and particulate fractions of sediments and to many anthropogenic sources. The geo-accumulation factor of Zn was more significant (MI_geo?≈?0.62–4.23) relative to the other metals. The bay was classified as moderately to strongly polluted by Zn while it is unpolluted to moderately polluted with the other metals with accumulation sequence of: Zn>Ni>Cu>Mn≥Pb. Zn and Ni recorded the highest enrichment ratios (average ER_Zn?≈?3.07 to 8.89; average ER_Ni?≈?0.84 to 3.63) in the different sediment fractions relative the other metals. These enrichment ratios classified the bay as minimal enrichment, suggestive of no or minimal pollution, to significant enrichment, suggestive of a significant pollution signals with metals sequence of: Zn>Ni>Cu>Pb>Mn.     

Electrochemical Treatment of Dye Solution by Oxalate Catalyzed Photoelectro‐Fenton Process Using a Carbon Nanotube‐PTFE Cathode: Optimization by Central Composite Design

Decolorization of C.I. Basic Blue 3 (BB3) by oxalate catalyzed photoelectro‐Fenton process based on carbon nanotube‐polytetrafluoroethylene (CNT‐PTFE) electrode as cathode under visible light was studied. A comparison of electro‐Fenton, photoelectro‐Fenton, and photoelectro‐Fenton/oxalate processes for decolorization of the solution containing BB3 has been performed. The results showed that color removal follows the decreasing order: photoelectro‐Fenton/oxalate > photoelectro‐Fenton > electro‐Fenton. Response surface methodology (RSM) was employed to assess individual and interactive effects of the four main independent parameters on the decolorization efficiency. A central composite design (CCD) was employed for optimization of photoelectro‐Fenton/oxalate treatment of BB3. The analysis of variance (ANOVA) showed a high coefficient of determination value (R² = 0.958) and satisfactory prediction second‐order regression. This study clearly showed that RSM was one of the suitable methods to optimize the operating conditions.     

Solid‐Phase Removal of Dissolved Organic Species from Water and Identification by GC–MS

A method is described for the detection and identification of dissolved organic compounds (DOCs) in various water samples. Acid treated active silica gel sorbent (pH 3) was packed into a micro‐column and used as a solid‐phase extraction medium for adsorption of DOCs. Silica particles‐adsorbed‐organic species were then divided into equal portions followed by suspension into various organic solvents of different polarities such as methanol, acetone, ethyl acetate, and toluene. Suspended silica‐adsorbed‐organic species were shaken for 1 h at room temperature and the organic extracts were subjected to GC–MS analysis under temperature programming conditions for qualitative detection and identification of these species. Blank solvents and silica samples were also subjected to the same extraction procedures and GC–MS analysis for comparison. The mass spectrum of each eluted chromatographic peak was library searched or manually interpreted to identify the compound.     

Current motion and short-term deformations in the Suez–Sinai area from GPS observations

We analyze observations from eight GPS campaigns carried out between 1997 and 2005 on a network of 13 sites in the Suez–Sinai area, where separation between the African and the Arabian plates takes place. This is the key area to understand if and in which way Sinai behaves like a sub-plate of the African plate and the role played by seismic and geodetic (long-term) deformation release.Our analysis shows that, on average, the Suez–Sinai area motion, in terms of ITRF00 velocities, matches the African plate motion defined by the NNR-NUVEL-1A model.The horizontal principal strain rate axes estimated separately in the Gulf of Suez area and in the northern Sinai vary from compression across the Gulf (−2.2 ± 1.2) × 10⁻⁸ year⁻¹ to NE extension (1.0 ± 1.5) × 10⁻⁸ year⁻¹ in the North, showing the presence of two distinct domains, so that in our opinion Sinai cannot be considered simply a unique rigid block.The analysis of GPS baseline length variations shows short-term deformations across the Gulf of Suez, reaching up a maximum value of more than 1 cm in 8 years.Since current geodynamical models do not predict significant tectonic deformation in this area, we work under the hypothesis that a contribute may be expected by post-seismic relaxation effects. Under this hypothesis, we compare the baselines length variations with the post-seismic relaxation field associated with five major local earthquakes occurred in the area, testing two different viscoelastic models. Our results show that the detected short-term deformations are better modeled for viscosity values of 10¹⁸ Pa s in the lower crust and 10²⁰ Pa s in the asthenosphere. However, since the modeled post-seismic effect results modest and a certain amount of the detected deformation is not accounted for, we think that an improved modeling should take into account the lateral heterogeneities of crust and upper mantle structures.     

Statistical Relationship Between UVB(280-320nm) and Broadband Solar Radiation(295-2800nm) at a Subtropical Location(Qena,Egypt)

The present study quantifies the relationship between ultraviolet-B(UVB) and broadband solar radiation(G) at Qena,Egypt.Data from 10-year hourly integrated totals for both UVB and G on a horizontal surface were used to determine the best fit between the two radiation types.On the basis of the correlation of determination(r2),a second-order polynomial was determined to provide the best fit.For the purpose of developing an empirical model to estimate UVB,all of the cases of UVB and G from a nine-year study from 2001 to 2009 were introduced.Monthly and seasonal empirical models,as well as a general expression,were established for UVB as a function of G.The values of r2 ranged from 0.90 to 0.97.By using a new dataset of G,the estimated and the corresponding measured values of UVB were determined to be in good agreement whereby the values of r2 between the two ranged from 0.91 to 0.98.In addition,the significance and performance of the regression forms were evaluated with the aid of several statistical analysis procedures.The values of the index of modeling(d) and coefficient of modeling efficiency(ME) were close to one.Moreover,the values of RMSE,mean bias error(MBE),and mean absolute error(MAE) were lower than the experimental errors.On the basis of this analysis,it has been determined that the suggested regression forms can be used to estimate UVB when it difficult to obtain measurements or when measurements are available only for limited periods at the studied region.     

Elemental profile of black shales

A black shale sample collected from the Chimiari site(Tarbela) was analyzed for elemental contents.Inductively coupled plasma-optical emission spectrometry(ICP-OES) was employed to determine major and trace elements in the digests.Precise analysis was accomplished for the black shales,which was better than 2.0%.Result shows that the shales are very rich in Ca(25439 μg·g-1),Fe(13933 μg·g-1),Ti(6932 μg·g-1),Al(5993 μg·g-1) and K(2730 μg·g-1).     

Sorption of lead on Iranian bentonite and zeolite: kinetics and isotherms

This study deals with the use of the natural, low-cost sorbents bentonite and zeolite for the removal of lead from aqueous solutions. The mineral material is from large deposits of bentonite and zeolite that have been discovered recently in Iran. Experimental and modeling data from our kinetic and equilibrium investigations reveal that (1) the pseudo-second-order kinetic model gave the best fit, and (2) the Koble–Corrigan sorption model describes the interaction between Pb(II) and the two mineral materials better than the Freundlich and Langmuir models. However, the sorption of Pb(II) ions by zeolite and bentonite is complex and probably involves several mechanisms. The experimental data show that natural zeolite and bentonite used in this study exhibited a reasonable sorption capacity for Pb(II), and thus may be useful for the immobilization of Pb(II) from polluted sites.     

Characterization of Iranian Obsidian Artifacts by PIXE and Multivariate Statistical Analysis

It had long been thought that obsidian found in Iranian sites originated from Anatolia and Armenia, but new research has challenged this assumption. In this study, 68 samples of obsidian obtained from an archaeological survey of Nader‐Tepe Aslanduz were analyzed by Proton Induced X‐ray Emission (PIXE). Nader‐Tepe Aslanduz is a tell site west of the city of Aslanduz in the Parsabad county of the Ardebil province in northern Iran. The site was inhabited from the first millennium B.C. to A.D. 17, and its history may extend back to the third or fourth millennium B.C. Our chemical composition results have been combined with obsidian composition data from Turkey and Armenia and subjected to Principal Component Analysis (PCA). This analysis shows that obsidian from each location can be grouped into distinctive classes—the obsidian from Nader‐Tepe Aslanduz is therefore probably derived from volcanic outcrops of the Sahand and Sabalan region. This study has been unable to assign a known source from Anatolia and Armenia for the obsidian of Nader‐Tepe Aslanduz.     

Hydrogeochemistry of the Winder River and adjoining tributaries, Balochistan, Pakistan

Quantitative estimation of ground and stream waters draining through sedimentary rocks of the Pab and Mor ranges (Jurassic-Cretaceous) and the Bela ophiolite has been made. The degree of correspondence among cations and anions has been estimated in order to evaluate their mutual relationships. The abundance of major ions is interpreted to be related to bedrocks and climatic conditions, which may contribute to the genetic affiliation. The log TDS and Na/Na Ca ratio reflected supremacy of weathering of rocks with some influence of evaporation. Ionic relationship is exhibited in the form of Stiff diagrams. Patterns of ionic composition revealed high NaCl, medium Ca(HCO3)2 and low MgSO4. Piper diagram has been used to classify the hydrofacies. The important hydrogeochemical parameters have been estimated for assessment of groundwater quality for domestic purposes in accordance to WHO. Irrigation water qualities have been evaluated in terms of EC, SAR, RSC, ESP and pH.     

Imaging the Mariánské Lázně Fault (Czech Republic) by 3-D ground-penetrating radar and electric resistivity tomography

Geodynamic activity in the area of West Bohemia is typified by the occurrence of earthquake swarms, Quaternary volcanism and high flux of mantle-derived CO₂. The highest swarm activity occurs beneath the eastern edge of the Cheb basin, which is delineated by the NW-SE trending morphologically pronounced Mariánské Lázn?? Fault (MLF) controlling the formation of the basin. The previous trenching survey across the MLF zone has identified several fault strands with possible Quaternary activity. In this paper we present the results of the geophysical survey focused to trace the faults signatures in geophysical sections and to build an image of near surface tectonics. The method of electric resistivity tomography (ERT) along two profiles parallel to the trench identified a strong resistivity contrast between the bodies of sandy gravels in the middle and conductive clayey sands to the west and weathered crystalline basement to the east. The 2-D ground penetration radar (GPR) sections show direct correlation of reflections with lithological boundaries identified in the trench. As expected, the GPR signal amplitudes increase with the resistivities found in the ERT sections. Two of the four faults identified in the trench are indicated in the resistivity and GPR sections. A 3-D GPR measurement has identified a spot of high amplitudes elongated parallel to the MLF trend, which coincides with the high resistivity body. To improve the signal-to-noise ratio of the time slices we stacked the GPR time slices within vertically homogeneous blocks. This provided a contrast image of the sand-gravel body including its boundaries in three dimensions. The detailed analysis of the 3-D GPR cube revealed additional fault that limits the highly reflective sands and appears to be offset by another younger fault. Our results suggest a complex fault pattern in the studied area, which deserves a further study.