Seismic imaging of deep hydrocarbon reservoirs

This paper examines those aspects of reflection seismology which require special consideration when imaging deeper hydrocarbon reservoirs, including the constraints imposed by vertical resolution, lateral resolution, and velocity analysis. We derive quantitative expressions relating the uncertainties in stacking velocities and in interval velocities derived from stacking velocities to acquisition parameters, as well as expressions for the lateral resolution which can theoretically be achieved for migrated seismic images. This analysis shows that the most significant limitations of seismic imaging at depth involve the finite lateral resolution of the seismic method, and the proper lateral positioning of seismic images. These difficulties are overcome in large measure through the proper migration of a seismic dataset, which becomes more critical as deeper horizons are imaged. If these horizons are suspected of having significant 3-D structure, a strong argument may be made for acquiring a 3-D seismic survey over the prospect. Migration of this dataset will then generate an image of the subsurface with good lateral resolution in both the X and Y directions.     

STATISTICAL TECHNIQUES APPLIED TO BOREHOLE GEOPHYSICAL DATA IN GOLD EXPLORATION1

Gold, as a trace element, is not directly detectable by geophysical borehole logging techniques. Geophysical logging methods have therefore been used to infer the presence of structural features and alteration processes associated with gold. Since these features and processes differ with the style of gold mineralization, a unique relation between geophysical anomalies and gold cannot be established. However, in a particular environment, such an association can be established. We examined geophysical log data (self potential, induced polarization, resistivity, gamma, temperature, and temperature gradient) and drill core from the Barber-Larder property in NE Ontario. The geophysically detectable alteration processes associated with gold were identified as sericitization and pyritization, by means of factor analysis. A linear discriminant function was constructed which allowed the zones of economic mineralization (nominally 0.05 oz/ton or 1.5 ppm) to be identified with a 75% success rate based on geophysical log data alone. This rate was achieved without sophisticated non-linear data transformations.     

Spatial and seasonal distribution of bacterial physiological groups in two reservoirs with different trophic levels

The spatial and seasonal distribution of the viable heterotrophic population and three heterotrophic physiological groups, i.e. ammonifyers, nitrate reducers and sulphate reducers, were studied in two reservoirs in the province of Vizcaya (Spain). Using indicative parameters, both reservoirs were classified as warm monomictics, one hypereutrophic and the other mesotrophic. A direct relation between the size of the bacterial populations and the trophic levels of the reservoirs was observed. Likewise, the distributions of the bacterial populations in the water column are basically different. In the hypereutrophic lake there is a direct relationship between the bacterial distribution and the physical-chemical environment of the reservoir that cannot be observed in the mesotrophic lake.     

Vergleichende Untersuchungen über das Phosphataufnahmevermögen ausgewählter Bakterienarten

The P-uptake by Acinetobacter calcoaceticus, Pseudomonas aeruginosa and Escherichia coli is determined in batch culture with peptone/glucose/sodium chloride or peptone/acetate/sodium chloride as substrate at 60 to 120 mg/1 orthophosphate for 20 h with cell densities of 2 · 10⁷/ml (Acinetobacter) or 1.2 · 10⁹. The measurements were carried out by means of an Na₂HPO₄ (³²P) addition of 95 to 420 kBq. During the stationary phase the bacteria achieved the following P-contents in the biomass in fg/g bacterium: Acinetobacter 6 to 13, Pseudomonas 0.2 to 0.6, Escherichia 0.04 to 0.09; during the phase of growth Acinetobacter achieved 40 to 100 fg/bacterium. Acetate as the substrate did not result in any increase of the P-uptake. The maximum accumulation with Acinetobacter was 13 % P in the dry substance.     

Dynamical stability of convection cells in the upper mantle

Summary A two-dimensional flow model of an incompressible fluid with constant viscosity has been used to study the changes in the large-scale flow pattern (aspect ratio 4). Implications for convection in the Earth's mantle are discussed.

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Attenuation of compressional waves in peridotite measured as a function of temperature at 200 MPa

A technique has been developed to determine attenuation in rocks at high temperature using a gas-media, high-pressure apparatus. A pulse transmission technique and a spectral ratio method are used to study compressional seismic properties of rocks. Seismic waves are transmitted to and from the sample through buffer rods of mullite. The effect of seismic wave reflections within the sample assembly are cancelled out by taking ratios of the spectra measured at different temperatures. In order to obtain good signal-to-noise ratio for resolving the attenuation at high pressure and temperature, special care is taken in the sample assembly and the ultrasonic coupling between the sample, buffer rods and transducers. A very tight connection of the sample-buffer rod-transducer is essential for obtaining high frequency signals (>300 kHz) at high temperature. A small mass is attached to each outside end of the transducer to drive low frequency signals (<250 kHz) into the sample. Before attenuation measurements, the sample and the buffer rods are tightly compacted in a platinum tube at high pressure and room temperature to ensure pressure seal of the sample assembly. The frequency range of measurement covers 50 to 450 kHz for the sample. Attenuation is very small in the buffer rod compared to the sample for the entire temperature range of the study. Because of the small attenuation, a wide frequency band of 50 kHz to 3.2 MHz can be covered for investigating the attenuation in the buffer rod. The technique has been used to measure attenuation at high confining pressure, and temperatures including sub- and hyper-solidus of upper mantle rocks. Therefore, effects of partial melting on attenuation can be studied.The method is applied to the attenuation measurement in a peridotite as a function of temperature to 1225°C at 200 MPa confining pressure. At high temperature, signal amplitude decays more rapidly at high frequency than at low frequency, from which attenuation (andQ) can be determined using a spectral ratio method. No frequency dependence ofQ is resolved for both the sample and the buffer rod over the entire temperature and frequency ranges of the measurement. The results show thatQ decreases rapidly with increasing temperature even in the temperature range below the solidus of peridotites. Such temperature sensitivity ofQ is probably more useful to probe thermal structure in the upper mantle than that of conductivity at temperatures below the solidus. The results in this study are compared with available seismic velocity, electrical conductivity and solidus data for peridotites, suggesting that there is no discontinuous change in both mechanical and electrical properties of peridotites at the solidus temperature. Even at hypersolidus temperatures, it appears that velocity drops and conductivity increases continuously (not abruptly) with increasing melt fraction. This implies that mechanical and electrical properties of the upper mantle will gradually change at the boundary where the geotherm crosses the solidus.     

Physico-chemical environment of pedogenic carbonate formation in Devonian vertic palaeosols, central Appalachians, USA

The morphology and geochemistry of pedogenic carbonate found in vertic claystone palaeosols in the Devonian Catskill Formation in central Pennsylvania preserve a record of the physical and chemical environment of carbonate precipitation. The carbonate is characterized by three distinct petrographic generations. Pedogenic rhizoliths and nodules are the earliest precipitated generation, and typically consist of dull red-brown luminescent micrite. Clear, equant calcite spar cement fills voids in the centres of rhizoliths, as well as circumgranular cracks and septarian voids in nodules. Early spar cements are non-luminescent to dull luminescent, whereas later spar cements exhibit bright yellow-orange luminescence. Late stage pedogenic fractures are always occluded with very bright yellow-orange luminescent spar cements. The incorporation of progressively higher concentrations of Mn (up to 34000 ppm) into successively younger calcite spar cements, without concomitant increases in Fe, suggests carbonate precipitation from an evolving meteoric water in which Mn²⁺ became increasingly mobile over time. The increased mobility is possibly due to decreasing Eh, resulting from oxidation of organic matter after rapid soil burial on the floodplain. The amount of Fe²⁺ available for incorporation into calcite was limited because most iron was immobile, having been earlier oxidized and bound to the palaeosol clay matrix as a poorly crystallized ferric oxide or oxyhydroxide mineral. Carbon isotope compositions of pedogenic carbonate correlate with the inferred depth of carbonate precipitation. Rhizoliths preserved below the lowest stratigraphic occurrences of pedogenic slickensides are consistently depleted in ¹³C relative to nodules, which formed stratigraphically higher, within the zone of active soil shrink and swell processes. Nodular carbonate, precipitated in proximity to deep cracks in the soil, is enriched due to increased gas exchange with isotopically heavy atmospheric CO₂. Accordingly, rhizolith compositions will most accurately estimate palaeoatmospheric levels of CO₂; the use of nodule compositions may result in overestimation of P_CO2 by as much as 30%.     

MULTI-ELEMENT ANALYSIS OF COASTAL MARINE SEDIMENT, AN IAEA PROPOSED REFERENCE MATERIAL (IAEA-356)

Proposed standard reference material, coastal marine sediment (IAEA-356) recently released under the IAEA Analytical Quality Control Services programme, has been analysed by instrumental neutron activation analysis technique. Up to 32 elements have been measured using the multi-element analysis approach. The precision of measurements varied from 1.3 to 12.5% with median value of 4.9%. The quality control of the data has been validated by analysing IAEA reference material of similar matrix which shows excellent agreement with IAEA values.