Causes and consequences of errors in determining sorption capacity of coals for carbon dioxide at high pressure

Recent comparisons of CO₂ sorption by coals at high pressures have shown major differences between the results obtained by different laboratories. These need to be resolved for laboratory estimation of CO₂ sequestration in coal seams to be useful. A compilation of potential sources of error in determination of sorption characteristics and their impact on sorption measurements is provided here. A series of tests is also provided that can be used to identify and reduce such errors in measurement. For example, an error in temperature produces a characteristic distortion of the sorption curve for carbon dioxide, which can be corrected to some extent. A negative value for excess sorption at high pressure is almost certainly diagnostic of either a cell volume that has been overestimated or that some part of the substrate that is inaccessible to the gas is accessible to helium. The major source of variation between results from the different laboratories that supplied the closest sorption values was found to be variations in the assumed free space volume, which could be due to discrepancies in determined helium density or measured cell volume. Including a term in the sorption model that is proportional to gas density will markedly reduce the influence of such errors in estimating sorption capacity or heats of sorption. The influence of swelling and moisture on sorption isotherms is also quantified here. Correction for swelling of coals in carbon dioxide changes the estimated sorption capacity by less than 1%, if a term that is proportional to gas density is included as a free parameter in the model fitting the isotherm.     

Fluvial Fluxes of Water, Suspended Particulate Matter, and Nutrients and Potential Impacts on Tropical Coastal Water Biogeochemistry: Oahu, Hawai‘i

Baseflow and storm runoff fluxes of water, suspended particulate matter (SPM), and nutrients (N and P) were assessed in conservation, urban, and agricultural streams discharging to coastal waters around the tropical island of Oahu, Hawai‘i. Despite unusually low storm frequency and intensity during the study, storms accounted for 8–77% (median 30%) of discharge, 57–99% (median 93%) of SPM fluxes, 11–79% (median 36%) of dissolved nutrient fluxes and 52–99% (median 85%) of particulate nutrient fluxes to coastal waters. Fluvial nutrient concentrations varied with hydrologic conditions and land use; land use also affected water and particulate fluxes at some sites. Reactive dissolved N:P ratios typically were ≥16 (the ‘Redfield ratio’ for marine phytoplankton), indicating that inputs could support new production by coastal phytoplankton, but uptake of dissolved nutrients is probably inefficient due to rapid dilution and export of fluvial dissolved inputs. Particulate N and P fluxes were similar to or larger than dissolved fluxes at all sites (median 49% of total nitrogen, range 22–82%; median 69% of total phosphorus, range 49–93%). Impacts of particulate nutrients on coastal ecosystems will depend on how efficiently SPM is retained in nearshore areas, and on the timing and degree of transformation to reactive dissolved forms. Nevertheless, the magnitude of particulate nutrient fluxes suggests that they represent a significant nutrient source for many coastal ecosystems over relatively long time scales (weeks–years), and that reductions in particulate nutrient loading actually may have negative impacts on some coastal ecosystems.     

Residential preferences in Sydney's inner suburbs: a study in diversity

The revitalization of inner suburban areas is attracting a good deal of attention throughout the Western world, not least because it frequently involves a process of gentrification whereby middle-class individuals move into and renovate formerly working-class dwellings. Evidence from Sydney suggests that this process of revitalization is spatially very selective and as a result it is overly simplistic to talk about the inner suburbs as a whole, because within inner city areas there exists a very considerable mix of both land use and building quality. Moreover the socio-economic characteristics of residents and their attitudes towards the issues of preservation, rebuilding, and high-rise, tend to vary between the different types of residential environment. Consequently there can exist no single planning prognosis for all inner suburban areas. What seems to be needed is a blend of preservation and redevelopment that avoids forcing middle-class aesthetic values on working-class residents, for whom considerations of accessibility to central area employment and facilities appear dominant.     

Some airborne observations of condensation nucleus concentration

Summary The measurement of condensation nucleus concentration from an aircraft is considered and preliminary observations made with a photo-electric condensation nucleus counter discussed. It is concluded that at heights up to 6000 ft concentrations of condensation nuclei vary, from 200 cm^–3 in clean maritime air to 5 × 10³ cm^–3 generally over large industrial areas and 35 × 10³ cm^–3 downwind of specific industrial sources. It appears that sea spray makes a contribution to the nucleus population.Mr. G. J.Day, B. Sc., Meteorological Research Flight, Royal Aircraft Establishment,Farnborough, Hants. (Great Britain).     

Molecular parameters of maturation in the Toarcian shales,Paris Basin,France—I. Changes in the configurations of acyclic isoprenoid alkanes,steranes and triterpanes

The changes in configuration at a number of chiral centres in certain acyclic isoprenoid alkanes, steranes, rearranged steranes and triterpanes of the hopane type in a suite of fourteen Toarcian shales (Paris Basin) have been determined by gas chromatography and combined gas chromatography-mass spectrometry. A sequence of changes in the ratios of various stereoisomers occurs both with increasing maximum depth of burial and in a North-South direction for shallow samples (maximum burial depth < 1000m). These changes cover the full range of maturity shown by the samples. The presence of 5α(H), 14β(H), 17β(H)-steranes in immature samples indicates the presence of a reworked component. The extent of epimerisation at a number of the chiral centres suggests that it relates to the extent of steric hindrance at the centres.     

Atmospheric trace metals: global cycles and assessment of man's impact

Global data are presented for sources of atmospheric input for 20 trace metals, and the relative importance of natural and anthropogenic sources is assessed. Interference factors are calculated as (total anthropogenic emissions/total natural emissions) × 100. For lithophile metals such as Fe and Mn, interference factors are small. In contrast, the atmophile metals, such as As, Se and Hg, exhibit large interference factors. A significant degree of correlation exists between interference factors and enrichment factors, where enrichment factor is defined as the metal/Al ratio in atmospheric particulates divided by the metal/Al ratio in soils. For many of the trace metals, enrichment factors are of the same order of magnitude at high latitudes in both the Northern and Southern Hemispheres, and are larger at high latitude than at mid latitude.A simple mathematical model is used to calculate present-day enrichment factors in both hemispheres based on natural and anthropogenic influxes, effluxes, and transfer between hemispheres. The calculated enrichment factors are in good agreement with the observed enrichment factors for lithophile metals at both mid and high latitude, and for atmophile metals at mid latitude. However, calculated enrichment factors for atmophile metals are lower than observed enrichment factors at high latitude. To explain these results, we propose that for Hg, As and Se, and perhaps for other atmophile metals, there are significant fluxes from the sea surface to the atmosphere. If the estimated low-temperature fluxes of As, Se and Hg from the land and sea surfaces are included in the interference factor calculations for these metals, the factors are reduced to less than 100%.     

Rock hardness and landform development in the Gunong Mulu National Park,Sarawak, E. Malaysia

Rock hardness, measured by the Schmidt Test Hammer, is an important factor in explaining some of the sharp contrasts in relief and wide variety of landforms in The Gunong Mulu National Park. It is also useful in consideration of contemporary geomorphological processes, such as landsliding.     

The morphology and hydrology of some Jamaican karst depressions

An area of shallow karst depressions in St. Ann parish, Jamaica is examined. Shallow, ‘temperate’ forms such as these are common in tropical karst areas. Depressions are analyzed morphometrically and a considerable degree of structural control appears to be exhibited. Some morphometric parameters, in particular the depth/diameter ratio, which have been used to postulate depression origin, are examined. Depression hydrology is investigated. Depressions appear to exhibit characteristics of small drainage basins. The occurrence of sporadic flood events is suggested as an important element in the development of surface channel networks. The integration of the depressions into the regional drainage system is investigated by water tracing of ‘underground flow sections’. Chemical analysis of waters in various parts of the drainage system reveals variations which point to the importance of solutional activity at the soil-bedrock interface. The influence of a soil cover in promoting solutional activity is indicated.