The detection of interstellar methylcyanoacetylene

A new interstellar molecule, methylcyanoacetylene (CH3C3N), has been detected in the molecular cloud TMC-1. The J = 8 --> 7, J = 7 --> 6, J = 6 --> 5, and J = 5 --> 4 transitions have been observed. For the first three of these, both the K = 0 and K = 1 components are present, while for J = 5 --> 4, only the K = 0 line has been detected. The observed frequencies were calculated by assuming a value of radial velocity VLSR = 5.8 km s-1 for TMC-1, typical of other molecules in the cloud. All observed frequencies are within 10 kHz of the calculated frequencies, which are based on the 1982 laboratory constants of Moises et al., so the identification is secure. The lines are broadened by hyperfine splitting, and the J = 5 --> 4, K = 0 transition shows incipient resolution into three hyperfine components. The rotational temperature determined for these observations is quite low, with 2.7 K < or = Trot < or = 4 K. the total column density is approximately 5 x 10(12) cm-2.     

New age estimates and climatostratigraphic correlations for the Borrobol and Penifiler Tephras: evidence from Abernethy Forest,Scotland

The emerging tephrostratigraphy of NW Europe spanning the last termination (ca. 15–9 ka) provides the potential for synchronizing marine, ice‐core and terrestrial records, but is currently compromised by stratigraphic complications, geochemical ambiguity and imprecise age estimates for some layers. Here we present new tephrostratigraphic, radiocarbon and chironomid‐based palaeotemperature data from Abernethy Forest, Scotland, that refine the ages and stratigraphic positions of the Borrobol and Penifiler tephras. The Borrobol Tephra (14.14–13.95 cal ka BP) was deposited in a relatively warm period equated with Greenland Interstadial sub‐stage GI‐1e. The younger Penifiler Tephra (14.09–13.65 cal ka BP) is closely associated with a cold oscillation equated with GI‐1d. We also present evidence for a previously undescribed tephra layer that has a major‐element chemical signature identical to the Vedde Ash. It is associated with the warming trend at the end of the Younger Dryas, and dates between 11.79 and 11.20 cal ka BP. Copyright © 2011 John Wiley & Sons, Ltd.