Stratigraphy, chemistry, and eruptive dynamics of the 12.4 ka plinian eruption of Apoyeque volcano, Managua, Nicaragua

Apoyeque volcano, located 9 km northwest of Managua city, erupted explosively at 12.4 ka. The Plinian eruption deposited a widespread pumice fall deposit known as the Upper Apoyeque Tephra (UAq). The UAq is massive, reversely graded, and consists of white juvenile pumice (~78 vol.%), a variety of cognate lithics and accidental altered lithics. The whole-rock pumice composition is rhyodacitic (SiO₂?=?66.9–68.5 wt.%) with a mineral paragenesis of plagioclase, orthopyroxene, clinopyroxene, amphibole, titanomagnetite, and ilmenite in a rhyolitic glass groundmass (SiO₂?=?74.4?±?0.6 wt.%). The deposit’s dispersal axis is to the south, with the deposit covering a minimum area of 877 km² within the 50 cm isopach and has a total volume of 3 km³ (dense rock equivalent, 1.15 km³). The eruption column reached a maximum height of ca.28 km. The eruption ejected a total mass of 3?×?10¹² kg at an average rate of 2?×?10⁸ kg/s, and based on available models, we infer duration of almost 4 h. Petrographic and geochemical characteristics suggest that the eruption was triggered by magma mixing.     

A comparative analysis of two methodologies to estimate well protection zones for transport of viruses from septic tanks in volcanic aquifers in Costa Rica

High groundwater demand in the Great Metropolitan Area (GMA) of Costa Rica, combined with the presence of many septic systems, imposes the necessity to define adequate dimensions for setback distances or protection zones around wellheads to prevent contamination of aquifers by pathogenic organisms. Numerical 3-D simulations of transport of viruses under natural hydrogeological conditions of the northwest section of GMA were performed, considering both porous and fractured porous media with variable saturation. Based on the sensitivity analysis, principal transport parameters for the conditions in the study area are injection concentration, hydraulic conductivity, inactivation rate and attachment rate. Furthermore, a comparative analysis of the arrival of viruses to the water table and the modeling domain’s boundary was carried out using two approaches: maximum permissible concentration criteria and travel time criteria (TT) of 100 days frequently applied in Costa Rica for fractured rocks aquifers. The analysis indicates that under conditions of low mobility and high removal rates (typical for soils of volcanic origin), the TT approach overestimates the dimension of the protection zone. On the other hand, when conditions of high mobility and low removal rate are considered, the TT approach usually underestimates that dimension. It is recommended to perform more field and laboratory studies to obtain better representative parameters for soils of volcanic origin.     

Paleomagnetic determination of emplacement temperatures of pyroclastic deposits: an under-utilized tool

Paleomagnetic data from lithic clasts collected from Mt. St. Helens, USA, Volcán Láscar, Chile, Volcán de Colima, Mexico and Vesuvius, Italy have been used to determine the emplacement temperature of pyroclastic deposits at these localities and to highlight the usefulness of the paleomagnetic method for determining emplacement temperatures. At Mt. St. Helens, the temperature of the deposits (T _dep ) at three sites from the June 12, 1980 eruption was found to be ≥532°C, ≥509°C, and 510–570°C, respectively. One site emplaced on July 22, 1980 was emplaced at ≥577°C. These new paleomagnetic temperatures are in good agreement with previously published direct temperature measurements and paleomagnetic estimates. Lithic clasts from pyroclastic deposits from the 1993 eruption of Láscar were fully remagnetized above the respective Curie temperatures, which yielded a minimum T _dep of 397°C. Samples were also collected from deposits thought to be pyroclastics from the 1913, 2004 and 2005 eruptions of Colima. At Colima, the sampled clasts were emplaced cold. This is consistent with the sampled clasts being from lahar deposits, which are common in the area, and illustrates the usefulness of the paleomagnetic method for distinguishing different types of deposit. T _dep of the lower section of the lithic rich pyroclastic flow (LRPF) from the 472 A.D. deposits of Vesuvius was ~280–340°C. This is in agreement with other, recently published paleomagnetic measurements. In contrast, the upper section of the LRPF was emplaced at higher temperatures, with T _dep ~520°C. This temperature difference is inferred to be the result of different sources of lithic clasts between the upper and lower sections, with the upper section containing a greater proportion of vent-derived material that was initially hot. Our studies of four historical pyroclastic deposits demonstrates the usefulness of paleomagnetism for emplacement temperature estimation.     

Small angle X-ray scattering mapping and kinetics study of sub-critical CO2 sorption by two Australian coals

Time- and position-resolved synchrotron small angle X-ray scattering data were acquired from samples of two Australian coal seams: Bulli seam (Bulli 4, R_o = 1.42%, Sydney Basin), which naturally contains CO₂ and Baralaba seam (R_o = 0.67%, Bowen Basin), a potential candidate for sequestering CO₂. This experimental approach has provided unique, pore-size-specific insights into the kinetics of CO₂ sorption in the micro- and small mesopores (diameter 5 to 175 Å) and the density of the sorbed CO₂ at reservoir-like conditions of temperature and hydrostatic pressure.For both samples, at pressures above 5 bar, the density of CO₂ confined in pores was found to be uniform, with no densification in near-wall regions. In the Bulli 4 sample, CO₂ first flooded the slit pores between polyaromatic sheets. In the pore-size range analysed, the confined CO₂ density was close to that of the free CO₂. The kinetics data are too noisy for reliable quantitative analysis, but qualitatively indicate faster kinetics in mineral-matter-rich regions.In the Baralaba sample, CO₂ preferentially invaded the smallest micropores and the confined CO₂ density was up to five times that of the free CO₂. Faster CO₂ sorption kinetics was found to be correlated with higher mineral matter content but, the mineral-matter-rich regions had lower-density CO₂ confined in their pores. Remarkably, the kinetics was pore-size dependent, being faster for smaller pores.These results suggest that injection into the permeable section of an interbedded coal-clastic sequence could provide a viable combination of reasonable injectivity and high sorption capacity.     

基于越南遥感时间序列数据的湄公河三角洲土地利用及河岸变化检测研究

通过采用先进的遥感技术,基于光学和雷达时间序列卫星影像（陆地卫星,SPOT和雷达卫星）,本文对金瓯半岛（位于湄公河三角洲南部）土地覆被变化及湄公河河岸侵蚀情况进行了检测研究。鉴于金瓯半岛典型的土地覆被类型为红树林,通过对1973-2008年红树林遥感影像分析发现,近年来红树林林地面积急剧下降,超过一半的红树林已经转变为虾养殖场。与此同时,检测发现湄公河河岸已经被严重侵蚀,且侵蚀趋势正加速恶化。具体而言,田河和口河的左右两岸被认为是遭受严重侵蚀的热点区域。本文以1966-1968年地形图作为基准线数据,与1989-2009年卫星影像数据进行比照分析,此外采用数字海岸线分析系统（DSAS）模型对未来变化趋势进行了预测。     

The Decay of Supersonic and Super-Alfvénic Turbulence in Star-Forming Clouds

Supersonic and super-Alfvénic turbulent motions generate an intricate pattern of shock waves through which the turbulence decays. We here illustrate the spatial structure during shock formation and decay. This revised version was published online in July 2006 with corrections to the Cover Date.     

Supersonic Ambipolar Diffusion: Estimating the Magnetic Field Strength in Protostellar Outflows

The magnetic field plays a crucial role in star formation. It is involved in rotational braking, collapse braking, outflow formation and jet collimation. Direct observations of the field are difficult. However, the field can be indirectly estimated through the field-cushioned C-shocks which produce strong infrared molecular emission lines. In particular, a high field in the outflows will generate the ‘shock absorber’ signature: very broad H₂lines. Such lines are indeed observed. Here we summarise recent progress in C-shock formation and stability. We demonstrate numerically that the Shock Absorbers are evolutionary and stable. The widths of H₂lines then limit the magnetic field strength. A field of 6 mG is suggested for HH 212. This revised version was published online in July 2006 with corrections to the Cover Date.     

Lethality of increasing CO2 levels on deep-sea copepods in the western North Pacific

The first CO₂ exposure experiments on several species of pelagic copepods inhabiting surface and deep layers in the western North Pacific were conducted. Living organisms were collected from two layers between the surface and 1,500 m between latitudes of 11 and 44°N, and they were exposed aboard ship to various pCO₂ up to about 98,000 μatm. Mortality of copepods from both shallow and deep layers in subarctic to subtropical regions increased with increasing pCO₂ and exposure time. Deep-living copepods showed higher tolerance to pCO₂ than shallow-living copepods. Furthermore, deep-living copepods from subarctic and transitional regions had higher tolerances than the subtropical copepods. The higher tolerances of the deep-living copepods from subarctic and transitional regions may be due to the adaptation to the natural pCO₂ conditions in the subarctic ocean.     

Latitudinal Differences in the Planktonic Biomass and Community Structure Down to the Greater Depths in the Western North Pacific

As part of the research program WEST-COSMIC Phase I (1997–2001), vertical profiles down to the greater depths (0–2000 m or 5800 m) of the plankton community structure composed of heterotrophic bacteria, phytoplankton, protozooplankton and metazooplankton were studied at one station in each subarctic (44°N) and in transitional region (39°N), and two stations in subtropical region (30°N and 25°N); all in 137–155°E in the western North Pacific Ocean. The biomass of all four taxonomic groups decreased rapidly with increasing depths at all stations, although the magnitude of depth-related decrease differed among the groups. As plankton community structure, metazooplankton biomass and bacterial biomass occupied >50% of the total in 0–2000 and 2000–4000 or 5000 m strata, respectively, at subarctic and transitional stations, while bacterial biomass contributed to >50% of the total consistently from 0 through 4800 or 5800 m at subtropical stations. Metazooplankton biomass integrated over the greater depths exhibited a clear latitudinal pattern (high north and low south), but this was not the case for those of the other taxonomic groups. As a component of metazooplankton, an appreciable contribution of diapausing copepods to the metazooplankton was noted at subarctic and transitional stations, but they were few or nil at subtropical stations. As protozooplankton assemblages, heterotrophic microflagellates (HMF) and dinoflagellates were two major components at subarctic and transitional stations, but were only HMF predominated at subtropical stations. From biomass ratios between heterotrophic bacteria, HMF and dinoflagellates, “sinking POC-DOC-heterotrophic bacteria-HMF-heterotrophic dinoflagellates” link was proposed as a microbial food chain operative in the deep layer of the western North Pacific. All results are discussed in the light of latitudinal differences in the structure and functioning of plankton community contributing to the ‘biological pump’ in the western North Pacific Ocean. This revised version was published online in July 2006 with corrections to the Cover Date.     

Netplankton Chlorophyll Biomass along 175°E in the Pacific Ocean

An analysis is presented of data on chlorophyll a concentrations of the total and the netplankton (>10 μm), determined either in April to June or in August to September from 48°N to 15°S along 175°E in the Pacific Ocean during 6 years by the NOPACCS (Northwest Pacific Carbon Cycle Study). Particular attention was given to the variability of absolute concentrations of the netplankton chlorophyll a and their percentage shares of the total chlorophyll a concentration. Below 0.2 μg l⁻¹ of surface total chlorophyll a, the netplankton chlorophyll a showed low percentage shares (such as 12.7% on average) with a large variation, but above 0.2 μg l⁻¹ it was 35.9% on average with less variation, showing an accelerated increase at high total chlorophyll a concentrations. High netplankton chlorophyll a concentrations in surface waters were observed at high latitudes, in waters having high chlorophyll a concentrations at sub-surface depth, and in equatorial upwelling. The percentage shares of netplankton in the total chlorophyll a in the euphotic zone were 8.5% and 25.9% above and below 0.2 μg l⁻¹, respectively, although the data points scattered over a wide range (from 7.2% to 53.8%) depending on differences in water masses, depths and seasons. High chlorophyll a concentrations and high percentage shares of netplankton corresponded to high ambient nitrate plus nitrite concentrations. Integrated netplankton chlorophyll a concentrations in the euphotic zone varied from 0.7 to 19.5 mg m⁻² in waters below 0.2 μg l⁻¹ of surface total chlorophyll a, and from 2.0 to 29.5 mg m⁻² above 0.2 μg l⁻¹, and the percentage shares of netplankton for the former were 7.4% on average and 23.7% for the latter. This revised version was published online in July 2006 with corrections to the Cover Date.