Mixing induced reactive transport in fractured crystalline rocks

In this paper the solute retention properties of crystalline fractured rocks due to mixing-induced geochemical reactions are studied. While fractured media exhibit paths of fast flow and transport and thus short residence times for conservative solutes, at the same time they promote mixing and dilution due to strong heterogeneity, which leads to sharp concentration contrasts. Enhanced mixing and dilution have a double effect that favors crystalline fractured media as a possible host medium for nuclear waste disposal. Firstly, peak radionuclide concentrations are attenuated and, secondly, mixing-induced precipitation reactions are enhanced significantly, which leads to radionuclide immobilization. An integrated framework is presented for the effective modeling of these flow, transport and reaction phenomena, and the interaction between them. In a simple case study, the enhanced dilution and precipitation potential of fractured crystalline rocks are systematically studied and quantified and contrasted it to retention and attenuation in an equivalent homogeneous formation.     

Community level adaptation to climate change: The potential role of participatory community risk assessment

This paper explores the value of using community risk assessments (CRAs) for climate change adaptation. CRA refers to participatory methods to assess hazards, vulnerabilities and capacities in support of community-based disaster risk reduction, used by many NGOs, community-based organizations, and the Red Cross/Red Crescent. We review the evolution of climate change adaptation and community-based disaster risk reduction, and highlight the challenges of integrating global climate change into a bottom-up and place-based approach. Our analysis of CRAs carried out by various national Red Cross societies shows that CRAs can help address those challenges by fostering community engagement in climate risk reduction, particularly given that many strategies to deal with current climate risks also help to reduce vulnerability to climate change. Climate change can also be explicitly incorporated in CRAs by making better use of CRA tools to assess trends, and by addressing the notion of changing risks. However, a key challenge is to keep CRAs simple enough for wide application. This demands special attention in the modification of CRA tools; in the background materials and trainings for CRA facilitators; and in the guidance for interpretation of CRA outcomes. A second challenge is the application of a limited set of CRA results to guide risk reduction in other communities and to inform national and international adaptation policy. This requires specific attention for sampling and care in scaling up qualitative findings. Finally, stronger linkages are needed between organizations facilitating CRAs and suppliers of climate information, particularly addressing the translation of climate information to the community level.     

Fluvial braidplain to shallow marine transition in the early Neoproterozoic Morar Group,Fannich Mountains,northern Scotland

The early Neoproterozoic Morar Group in northern Scotland forms the lower part of the Moine Supergroup, deformed and metamorphosed within the Precambrian Knoydartian and Lower Palaeozoic orogenies. It has remained uncertain whether it was deposited in a shallow-marine ‘failed rift’ basin within Rodinia or a foreland basin on the margin of the Grenville orogen, which is important to determine for tectonic reconstructions. In that context, we assess the sedimentology, depositional environment and tectonic setting of the middle part of the Morar Group in the Fannich Mountains. A ca. 4–6 km thick fining-upward facies succession contains three psammite dominated lithofacies (LF): LF1, at the base, contains amalgamated and multi-storey sets of trough and tabular cross beds, which passes upwards into LF2 consisting of trough and tabular cross-bedded units arranged in coarsening and fining-upward sequences with minor pelitic rocks. The stratigraphically highest lithofacies, LF3, contains finer and more complex coarsening-upward packages of rhythmically interbedded pelite and psammite. Palaeoflow develops from broadly unimodal NW–NE flow in LF1, to weakly bimodal NW–SE flow in LF3. The data indicate that this part of the Morar Group records deposition in a distal fluvial braidplain to tidally influenced shallow-marine setting. All facies and palaeocurrent transitions are gradual and occur systematically over many hundreds of metres vertically; such characteristics are incompatible with a rift-basin setting. We suggest that, instead, deposition occurred in a transition between a foreland basin to the Grenville orogen and a marine basin associated with the Asgard Sea between Baltica and Laurentia.     

Sulfur isotope fractionation during the May 2003 eruption of Anatahan volcano, Mariana Islands: Implications for sulfur sources and plume processes

Sulfur isotope compositions of pumice and adsorbed volatiles on ash from the first historical eruption of Anatahan volcano (Mariana arc) are presented in order to constrain the sources of sulfur erupted during the period 10-21 May, 2003. The isotopic composition of S extracted from erupted pumice has a narrow range, from δ³⁴S_V-CDT +2.6‰ to +3.2‰, while the composition of sulfur adsorbed onto ash has a larger range (+2.8‰ to +5.3‰). Fractionation modeling for closed and open system scenarios suggests that degassing of SO₂ raised the δ³⁴S_V-CDT value of S dissolved in the melt from an initial composition of between +1.6‰ and +2.6‰ for closed-system degassing, or between −0.5‰ and +1.5‰ for open-system degassing, however closed-system degassing is the preferred model. The calculated values for the initial composition of the magma represent a MORB-like (δ³⁴S_V-CDT ∼ 0‰) mantle source with limited contamination by subducted seawater sulfate (δ³⁴S_V-CDT +21‰). Modeling also suggests that the δ³⁴S_V-CDT value of SO₂ gas in closed-system equilibrium with the degassed magma was between +0.9‰ and +2.5‰. The δ³⁴S_V-CDT value of sulfate adsorbed onto ash in the eruption plume (+2.8‰ to +5.1‰) is consistent with sulfate formation by oxidation of magmatic SO₂ in the eruption column. The sulfur isotope composition of sulfate adsorbed to ash changes from lower δ³⁴S values for ash erupted early in the eruption to higher δ³⁴S values for ash erupted later in the eruption. We interpret the temporal/stratigraphic change in sulfate isotopic composition to primarily reflect a change in the isotopic composition of magmatic SO₂ released from the progressively degassing magma and is attributed to the expulsion of an accumulated gas phase at the beginning of the eruption. More efficient oxidation of magmatic SO₂ gas to sulfate in the early water-rich eruption plume probably contributed to the change in S isotope compositions observed in the ash leachates.     

Helgoland Roads,North Sea: 45 Years of Change

The Helgoland Roads time series is one of the richest temporal marine data sets available. Running since 1962, it documents changes for phytoplankton, salinity, Secchi disc depths and macronutrients. Uniquely, the data have been carefully quality controlled and linked to relevant meta-data, and the pelagic time series is further augmented by zooplankton, intertidal macroalgae, macro-zoobenthos and bacterioplankton data. Data analyses have shown changes in hydrography and biota around Helgoland. In the late 1970s, water inflows from the south-west to the German Bight increased with a corresponding increase in flushing rates. Salinity and annual mean temperature have also increased since 1962 and the latter by an average of 1.67°C. This has influenced seasonal phytoplankton growth causing significant shifts in diatom densities and the numbers of large diatoms (e. g. Coscinodiscus wailesii). Changes in zooplankton diversity have included the appearance of the ctenophore Mnemiopsis leidyi. The macroalgal community also showed an increase in green algal and a decrease in brown algal species after 1959. Over 30 benthic macrofaunal species have been newly recorded at Helgoland over the last 20 years, with a distinct shift towards southern species. These detailed data provide the basis for long-term analyses of changes on many trophic levels at Helgoland Roads.     

Non-energy use of fossil fuels and resulting carbon dioxide emissions: bottom–up estimates for the world as a whole and for major developing countries

We present and apply a simple bottom–up model for estimating non-energy use of fossil fuels and resulting CO₂ (carbon dioxide) emissions. We apply this model for the year 2000: (1) to the world as a whole, (2) to the aggregate of Annex I countries and non-Annex I countries, and (3) to the ten non-Annex I countries with the highest consumption of fossil fuels for non-energy purposes. We find that worldwide non-energy use is equivalent to 1,670 ± 120 Mt (megatonnes) CO₂ and leads to 700 ± 90 Mt CO₂ emissions. Around 75% of non-energy use emissions is related to industrial processes. The remainder is attributed to the emission source categories of solvent and other product use, agriculture, and waste. Annex I countries account for 51% (360 ± 50 Mt CO₂) and non-Annex I countries for 49% (340 ± 70 Mt CO₂) of worldwide non-energy use emissions. Among non-Annex I countries, China is by far the largest emitter of non-energy use emissions (122 ± 18 Mt CO₂). Our research deepens the understanding of non-energy use and related CO₂ emissions in countries for which detailed emission inventories do not yet exist. Despite existing model uncertainties, we recommend NEAT-SIMP to inventory experts for preparing correct and complete non-energy use emission estimates for any country in the world.     

Changes in Vascular Plant Biodiversity in the Netherlands in the 20th Century Explained by their Climatic and other Environmental Characteristics

In the Netherlands nation-wide databases are available with about 10 million records of occurrences of vascular plant species in the 20th century on a scale of approximately 1 km². These data were analysed with a view to identifying relationships between changes in botanical biodiversity and climatic and other environmental factors. Prior to analysis the data were corrected for several major forms of survey bias. The records were broken down into three periods: 1902–1949, 1975–1984 and 1985–1999. Using multiple regression analysis, differences between successive periods were related to plant functional characteristics as explanatory variables. Between the periods 1902–1949 and 1975–1984 there were small but significant increases in the presence of both thermophilic (‘warm’) and psychrophilic (‘cold’) species. However, in the final decades of the 20th century there was a marked increase in thermophilic species only, coinciding with the marked increase in ambient temperature observed during this period, evidence at least of a rapid response of Dutch flora to climate change. Urbanisation was also examined as an alternative explanation for the increase in thermophilic plant species and was found to explain only 50% of the increased presence of such species in the final decades of the 20th century. Besides temperature-related effects, the most important change during the 20th century was a strong decline in oligotrophic and a marked increase in eutrophic plant species.     

Politicization of research and the relevance of geography: some experiences and reflections for an ongoing debate

In this paper we address the revival of interest in recent years in the relevance of geographical research and highlight problems of politicization faced by researchers through cases of policy-oriented research in the UK and Belgium. We argue that geographers should be aware of the possibilities and constraints for critical engagement in the context of policy-oriented research. We identify at least two important opportunities for researchers to avoid clientelistic relationships with contractors and enhance their political relevance. First, researchers can stick to letter of the contract and maintain academic standards while at the same time interpreting their tasks according to their own ethical and political judgements. Second, relevance can be increased by forming alliances within and beyond the formal hierarchies of the state and the academy. The identification and utilization of these 'spaces of relevance' can be seen as the first step towards an approach that strategically seeks a balance between societal engagement on the one hand and contractual obligations, policy relevance and academic standards on the other.     

Genetically meaningful decomposition of grain-size distributions

All spatio-temporal grain-size patterns in sediments can be characterized by a mathematical representation of (un)mixing. This implies that an inverse model of (un)mixing would be ideally suited to obtain genetically meaningful interpretations of observed grain-size distributions (GSDs). GSDs are therefore often decomposed into theoretical end members by parametric curve-fitting procedures. Many researchers have been tempted to use goodness-of-fit measures as a means of justifying such decompositions in the absence of generic process-based models of end-member GSDs. A critical examination of parametric curve fitting through a series of numerical experiments shows that the goodness-of-fit of an approximation may be a poor guide to its genetic significance. The genetic interpretation of GSDs is a poorly constrained problem that cannot be solved without taking into account the geological context of GSDs, which may be captured by the covariance structure of grain-size classes across a series of GSDs sampled in a contiguous area. Curve-fitting methods cannot exploit this geological context, which explains why the geological relevance of curve-fitting results obtained in black-box mode is questionable. The desired genetic interpretation of GSDs can be obtained by applying the end-member-modelling algorithm EMMA to a series of GSDs simultaneously. Many end-member GSDs estimated by EMMA do not conform to one of the popular theoretical GSD models. Consequently, parametric curve fitting with theoretical distributions is more likely to obscure than to reveal the existence of genetically significant grain-size populations in sediments, especially if such populations are present in small proportions.