热液成因有色金属矿多维异常体系:以马头斑岩型钼铜矿为例

从深部矿地球化学勘查实际需求出发,根据近年来20余个矿床研究结果,总结提出了热液成因有色金属矿床矿致异常规律--多维异常体系。多维异常体系是指产出在特定成矿地质时期地质体中,空间有序共存、形成机理各异、成矿指向递进的多属性地球化学异常体系,将在斑岩型、矽卡岩型、热液型以及沉积改造型等与热液作用有关的有色金属矿产深部矿预测和评价中发挥重要作用。以安徽马头斑岩型钼铜矿为例,对该矿床多维异常体系进行了探讨。结果表明: 在该矿床中,存在着以Na₂O为代表的负异常体系、以S为代表的矿化剂元素异常体系、矿化剂元素S与Fe和成矿元素间协同平衡体系、成矿及其伴生元素异常体系等,这些异常体系对成矿的指示作用是递进的,从而证实了多维异常体系的存在。对应用多维异常体系思路预测和评价深部矿进行了说明。     

Model for the formation of arsenic contamination in groundwater. 1. Datong Basin,China

Mineral equilibria were analyzed in the system As-bearing rock-meteoric water. It was shown that carbonate rocks are the most probable source of As and Sr in the waters of the Datong Basin (People's Republic of China). The reason for groundwater enrichment in As is the shift of the equilibrium FeCO₃ (siderite) + H₂O = FeOOH(goethite) + CO₂(g) + H₂(g) to the left (toward siderite formation) owing to organic matter oxidation by atmospheric oxygen and an increase in the equilibrium partial pressure of CO₂, while the Eh of the system remains below ?0.30 ± 0.06 V.     

基于长时间序列(1975—2020年)生态耗水的岱海动态生态需水分析

生态需水是湖泊生态系统的重要指标,维持着湖泊生态系统的良性循环.以内蒙古中部半干旱湖泊岱海为研究对象,对湖泊动态生态需水进行分析.本研究在遥感和气象数据的基础上,获得1975-2020年长时间序列高精度水文要素数据,分析岱海水文要素时空演变规律;通过天然生态水深分析法、水深经验频率分析法和湖泊形态分析法分析岱海的水深随面积变化的关键水深;构建基于生态耗水规律的湖泊生态需水模型,计算自然状态下岱海生态需水动态变化范围.研究结果如下:岱海地区6-9月为丰水期,10月至次年5月为枯水期;45 a以来岱海水面面积呈显著下降趋势,近年来下降速率减缓;枯水期岱海适宜生态水深为8.72~9.92 m,丰水期为9.40~10.69 m,适宜生态需水量为5.62亿~7.71亿m³,适宜湖面面积为70.92~84.77 km².本文构建了长时间序列气候水文数据库,确定岱海动态生态需水范围可以实现对湖泊生态健康的实时监测,为相关规划与管理提供科学依据及可操作性指导,从而为岱海湖泊治理提供理论参考.     

南黄海沉积物中活性铁氧化物对有机碳的保存作用

土壤和沉积物中活性铁对有机质的吸附对有机质具有长期稳定和保存作用,从而在地质时间尺度上缓冲大气CO₂浓度。本文利用连二亚硫酸钠还原性溶解提取活性铁氧化物（FeR）及与之结合的有机碳（Fe-OC）,定量研究了南黄海沉积物中FeR与OC之间的结合方式以及FeR对OC的保存作用,讨论了深度增加对二者相互作用的影响。结果表明,南黄海沉积物中Fe-OC占沉积物总有机碳的份数（f_Fe-OC）为（13.2±7.47）%,即活性铁对OC的年吸附量为0.72 Mt,占全球边缘海沉积物TOC年埋藏通量的0.44%。Fe-OC的平均OC:Fe为4.50±2.61,表明共沉淀作用对有机质的保存起重要作用,且其比值随海源有机质含量增加而增加。Fe-OC稳定碳同位素（δ13C_Fe-OC）结果表明,FeR优先保存活性有机质,但这种选择性随OC:Fe增大而减弱。随深度增加,f_Fe-OC和δ13C_Fe-OC均未表现出显著变化,这与该海域沉积物中有机质活性较低、铁还原作用较弱有关。     

钾长石粉酸浸除铁的实验研究

在利用钾长石粉合成沸石分子筛和制取碳酸钾技术中，铁的存在会降低沸石的白度。对北京平谷、天津蓟县、内蒙白云鄂博三地钾长石粉进行硫酸酸浸除铁实验，获得最大铁浸出率分别为88．6％、93．2％和64．6％，且前两地钾长石粉中铁的浸出行为相似，酸浸除铁效果均优于白云鄂博钾长石粉。采用正交实验法研究硫酸浓度、酸浸温度和时间对除铁效果的影响，表明三者对不同地区钾长石粉酸浸除铁效果的影响程度各不相同。钾长石酸浸除铁反应开始时，铁的溶解极快，反应速率主要由化学反应控制；其后溶解相对缓慢，反应速率则由扩散作用控制。     

京津冀周边秸秆燃烧对PM2.5无机组分影响

华北平原是我国主要农作物产区,田间秸秆焚烧现象普遍存在,选取秋收季节（2014年10月）分析了秸秆燃烧的排放特征,利用区域化学传输模型WRF-Chem模拟研究了燃烧排放对气态前体物及其氧化产物的影响,以及最终导致的PM_2.5中硫酸盐、硝酸盐和铵盐的变化。研究表明:2014年秋收季节,河南和山东等省份的秸秆燃烧排放会在东南风的输送作用下影响京津冀地区;秸秆燃烧排放大量挥发性有机物（VOCs）,导致火点源及周边地区大气中主要氧化剂浓度上升,提升了区域大气氧化能力;当携带大量VOCs的秸秆燃烧烟羽与以化石燃料排放为主的城市气团相混合时,大气氧化性增强会加速城市地区人为源排放的NO_x和SO₂等气态前体物的氧化过程,提高硫酸盐和硝酸盐的形成速率、促进二次无机气溶胶的生成。     

New orthorhombic phases on the join NiAl2O4 (spinel analog)-Ni2SiO4 (olivine analog): Stability and implications to mantle mineralogy

Three new crystalline phases differing in Si/Al ratio have been synthesized from compositions along the join NiAl₂O₄-Ni₂SiO₄. Four reversible univariant equilibria involving these new phases plus Ni₂SiO₄ (olivine) have been located within the P-T region studied (1 atm–40 kb, 1000–1700° C); an invariant point occurs near 22 kb, 1150°C.All three new phases are orthorhombic. Precession photographs and electron microprobe analyses yield the following information:Phase I: 5NiO·3Al₂O₃·SiO₂ = 3NiAl₂O₄·Ni₂SiO₄, Pmma, a=5.67, b=11.51, c=8.10 (Å)Phase II: 7NiO·3Al₂O₃·2SiO₂ = 3NiAl₂O₄· 2Ni₂SiO₄, Imma, a=5.66, b=17.32, c=8.11Phase III: 3NiO· Al₂O₃· SiO₂ = NiAl₂O₄·Ni₂SiO₄, Imma, a=5.68, b=11.49, c=8.12Comparison with known structures suggests that these three phases plus NiAl₂O₄ spinel and high pressure Ni₂SiO₄ spinel belong to a homologous series based on a cubic close oxygen packing of the formula: M_2n O _n}-1 (T _n O_3n+1) where M and T are octahedrally and tetrahedrally coordinated cations, respectively. When n=1 the formula for spinel is obtained; n = 2 for phase I and phase III, both similar to the beta-phase of orthosilicates; and n = 3 for phase II which is related to the manganostibite structure.Similar phase equilibria and structural relations may occur on other joins of the aluminateorthosilicate type. Furthermore, the occurrence of such structural modifications between the spinel (aluminate) and olivine (orthosilicate) compositions suggests that there could be a corresponding polymorphic series between the olivine and spinel forms of orthosilicates.     

21世纪中国主要粮食产区的空间格局特征

Grain production is an important issue for the national economy and the livelihood of the Chinese people. It serves as the foundation of national development and social stability. China is a major grain producer as well as a major grain consumer. The grai…     

基于背景噪声的宁夏及邻区瑞利波层析成像

In this article,the vertical components of the continuous waveform data of 90 seismic stations in Ningxia and its adjacent regions recorded from January 2012 to December 2013 are used to obtain the Rayleigh surface wave group velocity dispersion images in the study area( 101°- 112°E,31°-42°N) according to the method of noise imaging,with period between 6s - 50s and resolution of 0.5°. The Yinchuan basin in the 6s - 26 s period obviously shows a low velocity anomaly,which is not uniform and has a tendency to gradually weaken; the Guanzhong Basin in 6 s-22s shows a strip of low velocity anomaly and demonstrates a transverse inhomogeneity,where velocity in the southeast is slightly faster than that in the northwest. In the 30s - 50s period it shows that in the Yinchuan graben basin and its southern area,there is a large low velocity anomaly area,which moves from northeast to southwest. It shows that between the main active tectonic zones,like mountains and basins,there are obvious geomorphologic boundaries. For example,the deep fault near Liupan Mountain is the dividing line between two large tectonic units of eastern and western of China. The inversion results have good correlation with the geological structure and the stratigraphic landform. The results are consistent with the results of artificial seismic section tomography across the basin. It provides an important basis for the dynamics of active tectonic zones and the mechanism of earthquake occurrence in this area.     

SUSTAINABLE RURAL LIVELIHOOD AND ECOLOGICAL SHELTER CONSTRUCTION IN UPPER REACHES OF CHANGJIANG RIVER ——Case Study of Zhaotong of Yunnan Province

1INTRODUCTION Ecological shelter construction (ESC) in the upper reaches of the Changjiang (Yangtze) River has been an important component of Development Program of West- ern China. In recent years, most of the literatures dis- cussing the meanings and goals of ESC have been fo- cused on the macro-level, and the scholars have concep- tualized it as a comprehensive strategy to promote the sustainable development of regional economy, society and environment, in which forestry's construc…