A modified analytical method for the shipboard determination of nanomolar concentrations of orthophosphate in seawater

A method for the determination of nanomolar concentrations of orthophosphate in oligotrophic seawater developed by Liang et al. (2007) has been modified to make it fully feasible for shipboard application and for faster sample throughput with minimized sample volume. The technique is based on the flow injection method with solid phase extraction on a Sep-Pak C18 cartridge and colorimetric detector. The Schlieren effect was minimized by rinsing the cartridge sequentially with 5 mL water and 2 mL 95% ethanol solution. With three micro pumps in parallel, savings of up to 80% in amount of reagents and 25% volume of seawater samples could be achieved in comparison to the previous method. Variation of stopped flow time and sample loading time gave 3 different standard curves, which corresponded to 3 linear ranges within 3.4 and 515 nM. The modified method permits the analysis of samples over a wide range of concentrations, and has been successfully applied to shipboard determination of trace orthophosphate in more than 200 seawater samples during a one-month cruise in the South China Sea. For seawater at concentrations of 20.6, 82.5, 206.2 nM orthophosphate, the relative standard deviations (RSD) (n = 6), determined daily for 6 days on board ship were 4.45%, 4.73% and 6.75%, respectively. Five seawater samples collected in the Station SEATS (South East Asia Time Series Station at 18°N, 116°E) were analyzed using the present method both on board and in a land-based laboratory, as well as with the magnesium hydroxide-induced coprecipitation (MAGIC) method, and showed no significant difference according to the statistical t-test.     

基于HJ-1A高光谱的黄河口碱蓬和柽柳盖度反演模型研究

碱蓬和柽柳是黄河口湿地典型的盐生植物类型,是多种保护珍禽的主要栖息地,具有景观尺度较小、分布广且多混生的特点。应用覆盖黄河口北部潮滩的HJ-1A高光谱遥感影像,基于现场测量的端元光谱和从遥感影像中使用顺序最大角凸锥法(SAMCC)自动提取的端元光谱,应用线性光谱分解法(LSU)、正交子空间投影法(OSP)、匹配滤波法(MF)、最小能量约束法(CEM)和自适应一致估计法(ACE)5种不同光谱解混方法进行混合像元光谱解混,对比两种方法得到的端元光谱分别对碱蓬和柽柳盖度的反演能力,并给出相应的反演模型。结果显示:(1)现场测量端元光谱取得了较好的碱蓬和柽柳盖度反演结果,其中应用LSU方法的光谱解混结果与现场测量盖度的决定系数对于碱蓬和柽柳分别达到了0.88和0.95;(2)两种端元获取方式的光谱解混结果中,LSU和OSP方法均获得了较高的相关性,ACE解混方法的相关性都最低;(3)SAMCC方法提取端元光谱对柽柳的分解结果与现场测量盖度的相关性远高于碱蓬。     

Impact Compressive Creep Characteristics of Simulative Soil for Deep-Sea Sediment

The impact load (equivalent impact height) applied to deep-sea sediment by a walking mining machine was first deduced by the energy conservation principle, and the simulative soil was prepared based on the deep-sea sediment collected from the Pacific C-C mining area. The self-designed impact compressive creep tests of the simulative soil were conducted under different ground stresses and impact heights, in order to determine impact compressive creep parameters using a K-H rheological model. Test results show that the impact compressive creep curves have three similar creep stages (transient creep, unstable creep, and stable creep) to static compressive creep curves, where the transient creep deformation and total deformation at the unstable creep stage decrease with the impact load. Among the three impact compressive creep parameters (K₁, K₂, β) of the simulative soil, K₁ is first increased with impact height and finally fluctuated to a certain stable value, while K₂ and β are approximately linearly increased with impact height. The maximum subsidence of the mining machine under a specific designed ground stress and walking velocity predicted by the impact compressive creep constitutive equation can be used for safety assessment of the mining machine.     

Self-Weight Penetration Characteristics of the Suction Foundation with Different Diameters in Sand

During the self-weight penetration process of the suction foundation on the dense sand seabed, due to the shallow penetration depth, the excess seepage seawater from the outside to the inside of the foundation may cause the negative pressure penetration process failure. Increasing the self-weight penetration depth has become an important problem for the safe construction of the suction foundation. The new suction anchor foundation has been proposed, and the self-weight penetration characteristics of the traditional suction foundation and the new suction anchor foundation are studied and compared through laboratory experiments and analysis. For the above two foundation types, by considering five foundation diameters and two bottom shapes, 20 models are tested with the same penetration energy. The effects of different foundation diameters on the penetration depth, the soil plug characteristics, and the surrounding sand layer are studied. The results show that the penetration depth of the new suction foundation is smaller than that of the traditional suction foundation. With the same penetration energy, the penetration depth of the suction foundation becomes shallower as the diameter increases. The smaller the diameter of the suction foundation, the more likely it is to be fully plugged, and the smaller the height of the soil plug will be. In the stage of self-weight penetration, the impact cavity appears around the foundation, which may affect the stability of the suction foundation.

     

Distribution and invasion of Spartina alterniflora within the Jiaozhou Bay monitored by remote sensing image

Spartina alterniflora as an alien invasive plant, poses a serious threat to the ecological functions of the coastal wetland of the Jiaozhou Bay. As of 2019, the distribution area of S. alterniflora in the Jiaozhou Bay has reached more than 500 hm². For this reason, combined with field surveys, remote sensing monitoring of the invasion S.alterniflora in the Jiaozhou Bay has been carried out. To accurately identify S. alterniflora within the Jiaozhou Bay coastal wetland, we used a new m...     

On dynamic coupling effects between a spar and its mooring lines

The responses of a spar constrained by slack mooring lines to steep ocean waves and tensions in the mooring lines are simulated using two different numerical schemes: a quasi-static approach (SMACOS) and a coupled dynamic approach (COUPLE). The two approaches are the same in computing wave loads on the structure. Their difference is in modeling dynamic forces of mooring lines; that is the dynamic forces are included in the computation of COUPLE but neglected in SMACOS. The numerical simulation is examined against the laboratory measurements of the JIP Spar in a water depth of 318 m. The dynamic coupling effects between the JIP Spar and its mooring lines in different water depths (318, 618 and 1018 m) are investigated by the comparison of numerical simulations obtained using the quasi-static and coupled dynamic approaches. It is found that the damping of mooring lines reduces the slow-drift surge and pitch of the Spar, especially in deep water. The reduction in the amplitude of slow-drift surge can reach about 10% in a water depth of 1018 m. The tension in mooring lines may greatly increase in the wave frequency range when dynamic forces in mooring lines are considered. The mooring-line tension in the wave frequency range predicted by the coupled dynamic approach can be eight times as great as the corresponding prediction by the quasi-static approach in a water depth of 1018 m. This finding may have important implications for the estimation of the fatigue strength and life span of the mooring lines deployed in deep water oceans.     

中国对虾(Penaeus chinensis)幼体血液循环的活体观察

溞对中国对虾早期幼体的循环系统及血液流向进行了活体观察 ,描述了中国对虾早期幼体发育阶段中幼体循环系统血管的走向与分布、血液的流向及循环路径等 ,比较各期幼体循环系统的形态 ,并探讨对虾早期幼体循环系统的发育过程。     

基于遥感增强嵌套模型红树林带水沙环境对码头建设的响应研究

南海北部湾铁山港码头建设期间,邻近区域红树林带植株出现受损死亡现象。本研究构建基于遥感增强包含红树林潮间带的海湾水沙嵌套模型,评估码头建设对红树林带潮流、泥沙输移及冲淤的影响。结果表明：海湾水沙嵌套模型可充分利用南海海流模拟信息,且精细化模拟了工程建设附近海域泥沙输移规律。采用全球地表水覆盖几率遥感反演数据与当地潮位的信息融合技术,为红树林带水沙模拟提供了可靠地形信息。码头建设主要影响红树林带南部潮流,涨急时流速减小,落急时部分潮沟通道流速增大。当进港方案更改为过水钢栈桥,红树林带东南部流速略有增加。码头施工期,红树林带69%～72%范围的悬浮泥沙浓度增量介于20～50 mg/L之间。码头建设前,红树林带泥沙平均冲淤量为0.27 cm/a;进港方案分别为不过水通道和过水钢栈桥,码头建设后红树林带淤积量增加的面积占比分别为96.6%和89.3%,平均冲淤量分别为0.45 cm/a和0.36 cm/a。过水钢栈桥替换不过水通道,红树林带冲淤增量下降了50.0%。研究结论可为潮间带水沙环境模拟和红树林带保护决策提供科学依据。     

利用GPS拖体在万山区域测量平均海面技术研究

Wanshan area has been chosen to be the specified field to calibrate and validate(Cal/Val) the HY-2 altimeter and its follow-on satellites. In March 2018, an experiment has been conducted to determine the sea surface height(SSH) under the HY-2 A ground track(Pass No. 203). A GPS towing-body(GPS-TB) was designed to measure the SSH covering an area of about 6 km×28 km wide centered on the HY-2 A altimeter satellite ground track. Three GPS reference stations, one tide gauge and a GPS buoy were placed in the research area, in order to process and resolve the kinematic solution and check the precision of the GPS-TB respectively. All the GPS data were calculated by the GAMIT/GLOBK software and TRACK module. The sea surface was determined by the GPS-TB solution and the tide gauge placed on Zhiwan Island. Then the sea surface of this area was interpolated by Arc GIS10.2 with ordinary Kriging method. The results showed that the precision of the GPS-TB is about 1.10 cm compared with the tide gauge placed nearby, which has an equivalent precision with the GPS buoy. The interpolated sea surface has a bias of –1.5–4.0 cm with standard deviation of 0.2–2.4 cm compared with the checking line. The gradient of the measured sea surface is about 1.62 cm/km along the HY-2 orbit which shows a good agreement compared with the CLS11 mean sea surface(MSS). In the Cal/Val of satellites, the sea surface between the tide gauge/GPS buoy and the footprint of altimeter can be improved by this work.