东南沿海地区降水与全球海温变化的关系

为了解近50年来东南沿海地区降水与海温变化的关系,对该地区降水与全球海表温度进行了奇异值分解（SVD）。结果表明：印度洋、南海及赤道东太平洋地区是对东南沿海地区降水有影响的关键区域。东南沿海地区秋冬季的降水总体上来说对前期海温变化的响应不敏感,而东南沿海地区夏季降水受前期海温的影响较为明显,尤其是上年夏季北印度洋、南海地区海温的变化对当年降水有明显影响。因此,在预测东南沿海地区夏季降水时应该重点考虑上年夏季北印度洋及南海地区海温的变化情况。     

Optimization of headspace single-drop microextraction technique for extraction of light hydrocarbons (C6-C12) and its potential applications

In this study, headspace single-drop microextraction (HS-SDME) coupled with gas chromatography-flame ionization detection (GC-FID) was tested to determine C₆-C₁₂ light hydrocarbons (LHs) in petroleum and aqueous samples. Several significant experimental parameters, such as drop solvent type, drop volume, sample solution ionic strength, agitation speed and extraction time were optimized. Under optimum extraction conditions, specifically, a 1.5 μl microdrop of n-hexadecane, 30 min extraction of a 5 ml aqueous sample placed in a 10 ml vial, and stirring at 1000 rpm at room temperature, the reproducibility and accuracy of this method were found to be satisfactory. Two examples using this method indicated that HS-SDME is a simple, efficient and promising technique for the determination of volatile C₆-C₁₂ LHs in complex matrices.     

广西苍梧县社洞钨钼矿床花岗岩类锆石LA-ICP-MS和辉钼矿Re-Os年龄及其地质意义

广西苍梧县社洞矿床是大瑶山隆起南侧正在勘查的一个与花岗岩类有关的斑岩-矽卡岩-石英脉型钨钼矿床,目前估算的资源量已达中型,并具有大型矿床的潜力.文章对矿区内的花岗岩类分别进行了单颗粒锆石LA-ICP-MS测年和辉钼矿Re-Os测年,获得社山复式岩体花岗斑岩的等时线年龄为(91.05±0.31) Ma,花岗闪长岩为(43...     

Organic species of lanthanum in natural environments: Implications to mobility of rare earth elements in low temperature environments

Naturally occurring organic ligands, such as acetate, citrate, malonate, oxalate, and succinate, play important roles in mobility and accumulation of La and other rare earth elements in low temperature systems under Earth surface conditions. However, a comprehensive and consistent thermodynamic database covering the complexes of rare earth elements with those naturally occurring organic ligands is lacking. In this study, thermodynamic data of organic species of rare earth elements (REE) represented by La, with an emphasis on their aqueous complexes with organic ligands, are critically reviewed. The organic ligands covered by this study include acetate, citrate, malonate, oxalate and succinate. In this critical review, the Specific Interaction Theory (SIT) model is adopted for extrapolation to infinite dilution. This model is a reliable activity coefficient model valid for a wide range of ionic strengths. These critically reviewed data, including complex formation constants, SIT interaction coefficients and solubility product constants, would enable accurate modeling of the speciation and solubility of REE in various environments including high ionic strength environments, providing insight into mobility and enrichment of REE in various environments.     

青藏高原拉萨地块西部雄巴盆地后碰撞钾质-超钾质火山岩年代学与地球化学

青藏高原拉萨地块后碰撞钾质和超钾质岩浆活动广泛分布且已有不少研究成果,但是它们的年龄主要是17~8Ma,而对于拉萨地块西部雄巴地区时代为24~23Ma的岩浆作用则研究较少。本文对雄巴盆地新识别出的三种类型火山岩的锆石LA-ICP-MS U-Pb定年和岩石地球化学研究表明,它们分别是超钾质安粗岩(23.9±0.6Ma)、粗面英安岩(23.3±0.4Ma)和钾质流纹岩(24.1±0.3Ma),这三种岩石近于同时产出。三类岩石的源区明显不同,其中钾质流纹岩是中、上地壳部分熔融产物;具有埃达克质特征的钾质粗面英安岩可能为加厚下地壳部分熔融;而超钾质安粗岩可能富集地幔部分熔融的产物。雄巴三种火山岩均含数量不等的继承锆石,钾质流纹岩具有~150Ma、~90Ma和~50Ma的继承锆石年龄群;钾质粗面英安岩突出显示了~90Ma左右岩浆活动记录和两个新元古代继承锆石年龄;幔源超钾质安粗岩的继承锆石则绝大多数继承锆石为晚白垩纪以来的岩浆活动记录,突出显示110~80Ma和62~30Ma两个峰值。     

页岩气测井地层评价的方法与进展

页岩气测井地层评价主要围绕3个方面展开：①页岩气地层的岩性和储集参数评价,包括孔隙度、饱和度、渗透率等;②页岩的生烃潜力评价,主要包括干酪根的识别与类型划分、有机质含量、热成熟度等一系列指标的定性或定量解释;③岩石力学参数和裂缝发育指标的评价。特别是在资源调查和勘探的初期,如何从烃源岩中寻找最有利的页岩气藏富集,是地球物理测井的首要任务。近几年,国外在页岩气测井评价方面的工作主要体现在对ECS测井和高分辨率成像测井的应用。另外有研究表明,感应测井与岩石介电常数有关的X分量负异常与干酪根的存在及其类型之间有一定的相关性。     

Prediction of non-cavitation propeller noise in time domain

The blade frequency noise of non-cavitation propeller in a uniform flow is analyzed in time domain. The unsteady loading (dipole source) on the blade surface is calculated by a potential-based surface panel method. Then the time- dependent pressure data is used as the input for Ffowcs Williams-Hawkings formulation to predict the acoustics pressure. The integration of noise source is performed over the true blade surface rather than the nothickness blade surface, and the effect of hub can be considered. The noise characteristics of the non-cavitation propeller and the numerical discretization forms are discussed.     

基于空间回归的B样条拟合在地面气温资料质量控制中的应用

将B样条拟合算法引入到地面气温资料的质量控制当中,在分析地面气温资料空间相关性的基础上,提出一种基于空间回归的B样条拟合地面气温资料质量控制方法(SRT_BSF方法)。为了检验SRT_BSF方法的有效性及适应性,利用SRT_BSF方法对多个场景地面气温资料进行质量控制,并与反距离加权方法(IDW方法)和空间回归方法(SRT方法)进行比较分析。试验结果表明,SRT_BSF方法相对于IDW方法和SRT方法更能有效地标记出地面气温资料中的存疑数据,同时多组独立案例的分析结果说明SRT_BSF方法具有更好的稳定性和适用性。