The fate of zircon during UHT–UHP metamorphism: isotopic (U/Pb, δ18O,Hf) and trace element constraints

Garnet–clinopyroxene ultra‐high‐pressure (UHP) rocks from the northern Bohemian Massif contain zircon with micro‐diamond inclusions. Trace element concentrations, oxygen and hafnium isotopic composition and U–Pb age of distinct textural domains in zircon characterize their growth conditions and temporal evolution. Diamond‐bearing zircon mantle domains with relicts of oscillatory zoning have uniform Th/U ratios (~0.1–0.2), high‐Ti contents (110–190 ppm, corresponding to temperatures of at least 1100 °C), and some (two of 17 mantle analyses) preserve steep heavy rare earth element (HREE) patterns with Yb_N/Gd_N = 10–11, with a weak negative Eu anomaly. These signatures are consistent with crystallization from a melt under UHP/ultra‐high‐temperature (UHT) conditions. Some of the bright‐cathodoluminscence (CL) rims preserve Th/U and Ti values characteristic of the zircon mantles, but others show elevated Th/U ratios of ~0.3–0.4 and lower Ti contents (20–40 ppm; only 13 ppm in a rare low‐CL outer rim). As they feature flat HREE patterns and negative Eu anomalies and commonly make embayments and truncate the mantle zoning, we suggest that they have formed through recrystallization in the solid state during exhumation of the rock, when both garnet and plagioclase were stable. The three zircon domains, that is, cores, mantles and rims, yield U–Pb concordia ages of 340.9 ± 1.5, 340.3 ± 1.5 and 341.2 ± 3.4 Ma respectively. When linked to the previously reconstructed P–T path of the rock, the error limits of the zircon mantle and rim ages constrain the exhumation of the rocks from depth of ~140 km (UHP) to ~80 km (HP) to a minimum rate of 1.5 cm yr^?1. The zircon cores are heterogeneous in terms of Th/U ratio (below 0.1 but also above 0.2) and REE characteristics, and their εHf values scatter between ?15.7 and +4.8 with similar values for individual domains within a single zircon grain suggesting a very localized control on hafnium isotope composition on a grain scale. The non‐equilibrated εHf values as well as a large range of the Hf‐depleted mantle model ages possibly reflect the presence of a heterogeneous population of old zircon. Consequently, the uniform and young ²³⁸U/²⁰⁶Pb ages may represent (near‐)complete resetting of the U–Pb geochronometer during the UHP–UHT event at c. 340 Ma through dissolution–reprecipitation process. In contrast to Hf, the oxygen isotope composition of zircon is homogeneous, ranging between 7.8‰ and 9.6‰ VSMOW, reflecting a source containing upper crustal material and homogenization at UHP–UHT conditions. Our study documents that continental crust was subducted to mantle depths at c. 340 Ma during the Variscan orogeny and was subsequently very rapidly exhumed, implying that the sequence of events was faster than can be resolved by the secondary ion mass spectrometry technique.     

Behaviour of geochronometers and timing of metamorphic reactions during deformation at lower crustal conditions: phase equilibrium modelling and U–Pb dating of zircon,monazite, rutile and titanite from the Kalak Nappe Complex,northern Norway

This study investigates the behaviour of the geochronometers zircon, monazite, rutile and titanite in polyphase lower crustal rocks of the Kalak Nappe Complex, northern Norway. A pressure–temperature–time–deformation path is constructed by combining microstructural observations with P–T conditions derived from phase equilibrium modelling and U–Pb dating. The following tectonometamorphic evolution is deduced: A subvertical S1 fabric formed at ~730–775 °C and ~6.3–9.8 kbar, above the wet solidus in the sillimanite and kyanite stability fields. The event is dated at 702 ± 5 Ma by high‐U zircon in a leucosome. Monazite grains that grew in the S1 fabric show surprisingly little variation in chemical composition compared to a large spread in (concordant) U–Pb dates from c. 800 to 600 Ma. This age spread could either represent protracted growth of monazite during high‐grade metamorphism, or represent partially reset ages due to high‐T diffusion. Both cases imply that elevated temperatures of >600 °C persisted for over c. 200 Ma, indicating relatively static conditions at lower crustal levels for most of the Neoproterozoic. The S1 fabric was overprinted by a subhorizontal S2 fabric, which formed at ~600–660 °C and ~10–12 kbar. Rutile that originally grew during the S1‐forming event lost its Zr‐in‐rutile and U–Pb signatures during the S2‐forming event. It records Zr‐in‐rutile temperatures of 550–660 °C and Caledonian ages of 440–420 Ma. Titanite grew at the expense of rutile at slightly lower temperatures of ~550 °C during ongoing S2 deformation; U–Pb ages of c. 440–430 Ma date its crystallization, giving a minimum estimate for the age of Caledonian metamorphism and the duration of Caledonian shearing. This study shows that (i) monazite can have a large spread in U–Pb dates despite a homogeneous composition; (ii) rutile may lose its Zr‐in‐rutile and U–Pb signature during an amphibolite facies overprint; and (iii) titanite may record crystallization ages during retrograde shearing. Therefore, in order to correctly interpret U–Pb ages from different geochronometers in a polyphase deformation and reaction history, they are ideally combined with microstructural observations and phase equilibrium modelling to derive a complete P–T–t–d path.     

The settling dynamics of flocculating mud and sand mixtures: part 2—numerical modelling

Estuarine and coastal sediment transport is characterised by the transport of both sand-sized particles (of diameter greater than 63?μm) and muddy fine-grained sediments (silt, diameter less than 63?μm; clay, diameter less than 2?μm). These fractions are traditionally considered as non-cohesive and cohesive, respectively, because of the negligible physico-chemical attraction that occurs between sand grains. However, the flocculation of sediment particles is not only caused by physico-chemical attraction. Cohesivity of sediment is also caused by biology, in particular the sticky extra-cellular polymeric substances secreted by diatoms, and the effect of biology in binding sediment particles can be much larger than that of physico-chemical attraction. As demonstrated by Manning (2008) and further expanded in part 1 of this paper (Manning et al., submitted), the greater binding effect of biology allows sand particles to flocculate with mud. In many estuaries, both the sand and fine sediment fractions are transported in significant quantities. Many of the more common sediment transport modelling suites now have the capability to combine mud and sand transport. However, in all of these modelling approaches, the modelling of mixed sediment transport has still essentially separated the modelling of sand and mud fractions assuming that these different fractions do not interact except at the bed. However, the use of in situ video techniques has greatly enhanced the accuracy and reliability of settling velocity measurements and has led to a re-appraisal of this widely held assumption. Measurements of settling velocity in mixed sands presented by Manning et al. (2009) have shown strong evidence for the flocculation of mixed sediments, whilst the greater understanding of the role of biology in flocculation has identified mechanisms by which this mud-sand flocculation can occur. In the first part of this paper (Manning et al., submitted), the development of an empirical flocculation model is described which represents the interaction between sand and mud particles in the flocculation process. Measurements of the settling velocity of varying mud-sand mixtures are described, and empirical algorithms governing the variation of settling velocity with turbulence, suspended sediment concentration and mud-sand content are derived. The second part of this paper continues the theme of examination of the effects of mud-sand interaction on flocculation. A 1DV mixed transport model is developed and used to reproduce the vertical transport of mixed sediment fractions. The 1DV model is used to reproduce the measured settling velocities in the laboratory experiments described in the part 1 paper and also to reproduce measurements of concentration of mixed sediments in the Outer Thames. In both modelling exercises, the model is run using the algorithms developed in part 1 and repeated using an assumption of no interaction between mud and sand in the flocculation process. The results of the modelling show a significant improvement in the ability of the 1DV to reproduce the observed sediment behaviour when the empirical equations are used. This represents further strong evidence of the interaction between sand and mud in the flocculation process.     

Geochemistry and petrogenesis of the Ediacaran post-collisional Jabal Al-Hassir ring complex,Southern Arabian Shield,Saudi Arabia

The Jabal Al-Hassir ring complex is located between latitudes 19°21′ and 19°42′ N,  and longitudes 42°55′ and 4312′ E, Southern Arabian Shield. It is an alkaline to highly fractionated calc-alkaline granite complex consisting of an inner core of biotite granite followed outward by porphyritic sodic-calcic amphibole (ferrobarroisite) granite. U–Pb zircon geochronology indicates that the Jabal Al-Hassir ring complex was emplaced at ca. 620 Ma. The granites display highly fractionated geochemical features (i.e., Eu/Eu* = 0.05–0.35; enrichment of K, Rb, Th, U, Zr, Hf, Y and REE; depletion of Ta, Nb, Ba, Sr, P, Eu, and Ti). Jabal Al-Hassir granites are post-collisional plutonic rocks and contain abundant microcline perthite and sodic-calcic amphibole, sharing the petrological and chemical features of A₂-type granites. Sr_i values range from 0.70241 to 0.70424, are similar to those expected for magmas extracted from a Neoproterozoic depleted source and much lower than what would be expected, if there was minor involvement of pre-Neoproterozoic continental crust. The geochemical characteristics indicate that their magma was most plausibly represented by partial melting of juvenile lower crust following the collision between East and West Gondwana at the final stage of the Arabian Shield evolution. The data presented in this study are therefore consistent with an intraplate, post-collisional magmatism formed at the beginning of a transition from convergent to extensional tectonics.     

High resolution U‐Pb ages of Ca‐phosphates in Apollo 14 breccias: Implications for the age of the Imbrium impact

Previous age estimates of the Imbrium impact range from 3770 to 3920 Ma, with the latter being the most commonly accepted age of this basin‐forming event. The occurrence of Ca‐phosphates in Apollo 14 breccias, interpreted to represent ejecta formed by this impact, provides a new opportunity to date the Imbrium event as well as refining the impact history of the Moon. We present new precise U‐Pb analyses of Ca‐phosphates from impact breccia sample 14311 that are concordant and give a reliable weighted average age of 3938 ± 4 Ma (2σ). Comparison with previously published U‐Pb data on phosphate from Apollo 14 samples indicate that all ages are statistically similar and suggest phosphates could have been formed by the same impact at 3934 Ma ± 3 Ma (2σ). However, this age is older than the 3770 to 3920 Ma range determined for other samples and also interpreted as formed during the Imbrium impact. This suggests that several impacts occurred during a 20–30 Ma period around 3900 Ma and formed breccias sampled by the Apollo missions.     

Chironomid‐inferred late‐glacial summer air temperatures from Lough Nadourcan,Co. Donegal,Ireland

Western Ireland, located adjacent to the North Atlantic, and with a strongly oceanic climate, is potentially sensitive to rapid and extreme climate change. We present the first high‐resolution chironomid‐inferred mean July temperature reconstruction for Ireland, spanning the late‐glacial and early Holocene (LGIT, 15–10 ka BP). The reconstruction suggests an initial rapid warming followed by a short cool phase early in the interstadial. During the interstadial there are oscillations in the inferred temperatures which may relate to Greenland Interstadial events GI‐1a–e. The temperature decrease into the stadial occurs in two stages. This two‐stage drop can also be seen in other late‐glacial chironomid‐inferred temperature records from the British Isles. A stepped rise in temperatures into the Holocene, consistent with present‐day temperatures in Donegal, is inferred. The results show strong similarities with previously published LGIT chironomid‐inferred temperature reconstructions, and with the NGRIP oxygen‐isotope curve, which indicates that the oscillations observed in the NGRIP record are of hemispherical significance. The results also highlight the influence of the North Atlantic on the Irish climate throughout the LGIT. Copyright © 2010 John Wiley & Sons, Ltd.     

Middle Ordovician subduction of continental crust in the Scandinavian Caledonides: an example from Tjeliken,Seve Nappe Complex,Sweden

The Seve Nappe Complex of the Scandinavian Caledonides is thought to be derived from the distal passive margin of Baltica which collided with Laurentia in the Scandian Phase of the Caledonian Orogeny at 430–400 Ma. Parts of the Seve Nappe Complex were affected by pre-Scandian high- and ultrahigh-pressure metamorphism, in a tectonic framework that is still unclear, partly due to uncertainties about the exact timing. Previous age determinations yielded between ~ 505 and ~ 446 Ma, with a general trend of older ages in the North (Norrbotten) than in the South (Jämtland). New age determinations were performed on eclogite and garnet–phengite gneiss at Tjeliken in northern Jämtland. Thermodynamic modelling yielded peak metamorphic conditions of 25–27 kbar/680–760 °C for the garnet–phengite gneiss, similar to published peak metamorphic conditions of the eclogite (25–26 kbar/650–700 °C). Metamorphic rims of zircons from the garnet–phengite gneiss were dated using secondary ion mass spectrometry and yielded a concordia age of 458.9 ± 2.5 Ma. Lu–Hf garnet-whole rock dating yielded 458 ± 1.0 Ma for the eclogite. Garnet in the eclogite shows prograde major-element zoning and concentration of Lu in the cores, indicating that this age is related to garnet growth during pressure increase, i.e. subduction. The identical ages from both rock types, coinciding with published Sm–Nd ages from the eclogite, confirm subduction of the Seve Nappe Complex in Northern Jämtland during the Middle Ordovician in a fast subduction–exhumation cycle.     

The structure and timing of lateral escape during the Scandian Orogeny: A combined strain and geochronological investigation in Finnmark, Arctic Norwegian Caledonides

Determining the timing, duration and mechanism of tectonic events within an orogenic cycle, such as ocean subduction, continent–continent collision or gravitational collapse, is challenging, especially in ancient orogenic belts. Variations in the tectonic transport direction, however, can be used as a guide to these stages of orogeny. While thrust sheets within the Caledonian allochthon in north Norway were emplaced broadly eastwards perpendicular to the trend of the orogen, many features indicate material transport in other orientations. One dominant feature of the Magerøy Nappe, sitting above and infolded with the Kalak Nappe Complex, is the development of a strong N–S lineation orthogonal to the main transport direction. Strain measurements, in part determined by a new method, are used, in the context of the regional structural data to identify the critical stage in orogeny when compressional forces are balanced by orogen-parallel lateral escape. Quantitative 3-D strain estimation in the Magerøy Nappe indicates prolate deformation with c. 50% horizontal shortening parallel to the thrusting direction (E–W) and c. 200% extension along the orogenic strike (N–S) with c. 30% vertical shortening. Temporal constraint on this fabric is provided by Ar–Ar isotopic analysis of undeformed white mica in cross-cutting granitic pegmatites. These data show that prolate deformation occurred before the white mica cooling age of 416 ± 4 Ma, while the previously determined depositional age of the Hellefjord Schist indicates that it occurred after 438 ± 4 Ma. A granitic pegmatite that intruded the Hellefjord Schist after an initial deformation phase but during or prior to a later deformation, has been dated at 431 ± 2 Ma by U–Pb zircon. A previous lower age constraint on this deformation of 428 ± 5 Ma is given by metamorphic zircon overgrowths on fractured grains. These results constrain the continental collision between Baltica and Laurentia in Finnmark to the interval c. 431–428 Ma. Placed in a regional context, these results indicate that lateral escape was orthogonal to the thrusting direction and occurred during the continent–continent collision stage in the Scandian Orogeny before gravitationally driven collapse.     

A zircon U-Pb study of metaluminous (I-type) granites of the Lachlan Fold Belt,southeastern Australia: implications for the high/low temperature classification and magma differentiation processes

Following seminal studies in the Lachlan Fold Belt (southeastern Australia), it has become almost axiomatic that metaluminous granites derive from infracrustal precursors, whereas strongly peraluminous plutons have metasedimentary or supracrustal sources, as reflected in the I- and S-type designation. Recently, zircon saturation thermometry has been used to further subdivide I-type granites into high- and low-temperature categories. That low-temperature I-type granites evolved by restite separation from magmas generated in the zircon stability field is implicit in this classification. To explore this hypothesis, we report an ion microprobe U-Pb (zircon) study into three hallmark ‘low-temperature’ Lachlan Fold Belt I-type suites. The combined patterns of zircon age inheritance and bulk rock Zr trends suggest that each suite formed from magmas that were initially zircon-undersaturated, and that fractional crystallisation, not restite unmixing, was the dominant differentiation process. The low temperature status presently applied to these rocks cannot therefore be justified. The inherited zircons in these I-type granites reflect melting and assimilation of metasedimentary rock, and testify to a supracrustal source component. Electronic Supplementary Material Supplementary material is available for this article at